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Volume 32
Main Index

Issue 1


Reactivity and acidity of Li in lithium aluminum oxide (LiAlO2) phases
Richard Dronskowski
pp 1 - 9; DOI:
10.1021/ic00053a001
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Importance of the interlayer Te...Te contacts on the electronic structure of the layered niobium germanium telluride Nb3Ge0.9Te6
E. Canadell, L. Monconduit, M. Evain, R. Brec, J. Rouxel, and M. H. Whangbo
pp 10 - 12; DOI:
10.1021/ic00053a002
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Syntheses and structures of vanadium(III) complexes containing 1,3-diaminopropane-N,N,N',N'-tetraacetate ([V(trdta)]-) and 1,3-diamino-2-propanol-N,N,N',N'-tetraacetate ([V2(dpot)2]2-)
Julita C. Robles, Yoko Matsuzaka, Shinji Inomata, Mamoru Shimoi, Wasuke Mori, and Hiroshi Ogino
pp 13 - 17; DOI:
10.1021/ic00053a003
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Heteronuclear trinuclear complex ions of the type [MII{Cr(A)4(OH)2}2]4+
Kathryn M. Corbin, Joergen Glerup, Derek J. Hodgson, Marc H. Lynn, Kirsten Michelsen, and Karen Margrethe Nielsen
pp 18 - 26; DOI:
10.1021/ic00053a004
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Crystal structure and magnetic properties of manganese-copper complex MnCu(obbz)(H2O)3.cntdot.DMF (obbz = N,N'-oxamidobis(benzoato) and DMF = dimethylformamide), a precursor of the molecular-based magnet MnCu(obbz).cntdot.H2O with Tc = 14 K
Francesc Lloret, Miguel Julve, Rafael Ruiz, Yves Journaux, Keitaro Nakatani, Olivier Kahn, and Jorunn Sletten
pp 27 - 31; DOI:
10.1021/ic00053a005
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Dinuclear copper(II) and mixed-valence copper(II)-copper(I) complexes of 34-membered macrocyclic ligands (H2M1, H2M2) capable of forming endogenous phenolate and pyridazino bridges. X-ray crystal structures of the dinuclear copper(II) complexes [Cu2M1][BF4]2.cntdot.H2O and [Cu2M2][BF4]2.cntdot.CH3OH, which exhibit a remarkable ligand twist
Santokh S. Tandon, Laurence K. Thompson, and John N. Bridson
pp 32 - 39; DOI:
10.1021/ic00053a006
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A new approach to the study of intramolecular electron-transfer reactions of metalloproteins: pulse radiolysis of nitrogen dioxide-modified tyrosine derivatives of plastocyanin
K. Govindaraju, Hans E. M. Christensen, Emma Lloyd, Marianne Olsen, G. Arthur Salmon, Nicholas P. Tomkinson, and A. Geoffrey Sykes
pp 40 - 46; DOI:
10.1021/ic00053a007
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Water-soluble organometallic compounds. 3. Kinetic investigations of dissociative phosphine substitution processes involving water-soluble Group 6 metal derivatives in miscible aqueous/organic media
Donald J. Darensbourg and Christopher J. Bischoff
pp 47 - 53; DOI:
10.1021/ic00053a008
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Ferromagnetic exchange coupling and magneto-structural correlations in mixed-bridged trinuclear copper(II) complexes. Magnetic data and theoretical investigations and crystal structures of two angled CuII3 complexes
Stefan Gehring, Peter Fleischhauer, Helmut Paulus, and Wolfgang Haase
pp 54 - 60; DOI:
10.1021/ic00053a009
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Lowest energy excited states of unsaturated cyclic M3(dppm)3CO2+ clusters (M = palladium, platinum)
Pierre D. Harvey and Rejean Provencher
pp 61 - 65; DOI:
10.1021/ic00053a010
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Solid-state cadmium-113 NMR of three structural isomers of hexadecakis(benzenethiolato)tetrasulfidodecacadmate(4-)
Garry S. H. Lee, Keith J. Fisher, Anthony M. Vassallo, John V. Hanna, and Ian G. Dance
pp 66 - 72; DOI:
10.1021/ic00053a011
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Inorganic hybrid analogs of Thiele's and Chichibabin's hydrocarbons. Spectroscopy, electrochemistry, and structure
Alexander Lichtblau, Hans Dieter Hausen, Wolfgang Schwarz, and Wolfgang Kaim
pp 73 - 78; DOI:
10.1021/ic00053a012
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Synthesis and interconversions of azagermatranes
Yanjian Wan and John G. Verkade
pp 79 - 81; DOI:
10.1021/ic00053a013
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Reaction of the manganese(II) Schiff-base complexes (X-SALPRN)MnII [X = H, 5-Cl, 5-CH3O; SALPRN = 1,3-bis(salicylideneamino)propane] with dioxygen and reactivity of the oxygenated products
Colin P. Horwitz, Patrick J. Winslow, Joseph T. Warden, and Carol A. Lisek
pp 82 - 88; DOI:
10.1021/ic00053a014
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Crystal structure and magnetic properties of K5.5Na1.5[PW10Cu2(H2O)2O38].13H2O. Substituted Keggin heteropolytungstates of the type PW10Cu2 containing exchange-coupled copper pairs
C. J. Gomez-Garcia, E. Coronado, P. Gomez-Romero, and N. Casan-Pastor
pp 89 - 93; DOI:
10.1021/ic00053a015
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Late transition metal .mu.-oxo and .mu.-imido complexes. 10. Rhodium arylimido/arylamido ring reactions: electrophilic additions
Yuan Wen Ge and Paul R. Sharp
pp 94 - 100; DOI:
10.1021/ic00053a016
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New strontium borate halides: Sr5(BO3)3X (X = F, Br)
Theodore Alekel and Douglas A. Keszler
pp 101 - 105; DOI:
10.1021/ic00053a017
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Pyridines with an appended metallocyclam subunit. Versatile building blocks to supramolecular multielectron redox systems
Andres De Blas, Giancarlo De Santis, Luigi Fabbrizzi, Maurizio Licchelli, Anna Maria Manotti Lanfredi, Piersandro Pallavicini, Antonio Poggi, and Franco Ugozzoli
pp 106 - 113; DOI:
10.1021/ic00053a018
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Switching the mechanism of spin-exchange coupling in a (.mu.-oxo)bis(.mu.-acetato)chromium(III)vanadium(III) complex by protonation of the oxo bridge
Rainer Hotzelmann and Karl Wieghardt
pp 114 - 116; DOI:
10.1021/ic00053a019
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Structure of dichlorobis{bis(diphenylphosphino)methane}nickel(II)
Ljubica Manojlovic-Muir, Hameed A. Mirza, Naheed Sadiq, and Richard J. Puddephatt
pp 117 - 119; DOI:
10.1021/ic00053a020
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Rhenium(V) oxo complexes relevant to technetium renal imaging agents derived from mercaptoacetylglycylglycylaminobenzoic acid isomers. Structural and molecular mechanics studies. [Erratum to document cited in CA117(4):39022t]
Lory Hansen, Renzo Cini, Andrew Taylor, and Luigi G. Marzilli
pp 120 - 120; DOI:
10.1021/ic00053a021
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Issue 2


The first observation of 1J(Ru,P) in phosphorus-31 CP/MAS NMR spectra of solid ruthenium compounds
Klaus Eichele, Roderick E. Wasylishen, John F. Corrigan, Simon Doherty, Arthur J. Carty, and Yan Sun
pp 121 - 123; DOI:
10.1021/ic00054a001
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(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): a model for the iron-sulfur center in nitrile hydratase from Brevibacterium, sp
Thomas Beissel, Kai Silke Buerger, Gottfried Voigt, Karl Wieghardt, Christian Butzlaff, and Alfred X. Trautwein
pp 124 - 126; DOI:
10.1021/ic00054a002
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A novel polyoxo molybdenum(V) organophosphonate anion having a sandwich structure: synthesis and crystal structure of [N(C2H5)4]2Na3(H3O)4{Na[Mo6O15(O3PC6H5)(HO3PC6H5)3]2}..apprx.14H2O
Guang Cao, Robert C. Haushalter, and Karl G. Strohmaier
pp 127 - 128; DOI:
10.1021/ic00054a003
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Inorganic synthesis in supercritical amines: synthesis of tetrakis(ethylenediamine)octasulfidotetratungsten sulfide containing an isolated sulfide ion
Paul T. Wood, William T. Pennington, Joseph W. Kolis, Biao Wu, and Charles J. O'Connor
pp 129 - 130; DOI:
10.1021/ic00054a004
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Methane vs benzene activation via transient tantalum amido-imido complex tert-Bu3SiNHTa(:NSiBu3-tert)2: structure of (py)2MeTa(:NSiBu3-tert)2
Christopher P. Schaller and Peter T. Wolczanski
pp 131 - 144; DOI:
10.1021/ic00054a005
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Technetium(VII) dioxotrifluoride, TcO2F3: synthesis, x-ray structure determination, and Raman spectrum
Helene P. A. Mercier and Gary J. Schrobilgen
pp 145 - 151; DOI:
10.1021/ic00054a006
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Synthesis of (.eta.6-Arene)tricarbonylchromium complexes: regioselective reaction of chromium hexacarbonyl with polycyclic aromatic hydrocarbons
Z. Y. Own, S. M. Wang, J. F. Chung, D. W. Miller, and P. P. Fu
pp 152 - 159; DOI:
10.1021/ic00054a007
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Oxidation of thioanisoles and methyl phenyl sulfoxides by oxo(phosphine)ruthenium(IV) complexes
John Henry Acquaye, James G. Muller, and Kenneth J. Takeuchi
pp 160 - 165; DOI:
10.1021/ic00054a008
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Electronic structure of the "molecular light switch" bis(bipyridine)dipyrido[3,2-a:2',3'-c]phenazineruthenium(2+). Cyclic voltammetric, UV/visible and EPR/ENDOR study of multiply reduced complexes and ligands
Joerg Fees, Wolfgang Kaim, Michael Moscherosch, Walter Matheis, Jiri Klima, Michael Krejcik, and Stanislav Zalis
pp 166 - 174; DOI:
10.1021/ic00054a009
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Kinetics and mechanism of the anation reaction of the aquapentaamminechromium(III) ion with the hexacyanocobaltate(III) ion
Dennis C. Gaswick and Steven M. Malinak
pp 175 - 177; DOI:
10.1021/ic00054a010
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Solid-state carbon-13 NMR chemical shift tensors in square-planar tetracyanometalates (M = nickel, palladium, platinum)
Ae Ja Kim and Leslie G. Butler
pp 178 - 181; DOI:
10.1021/ic00054a011
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Single-crystal studies of the zero-field splitting and magnetic exchange interactions in the magnetic susceptibility calibrant mercury cobalt-thiocyanate (HgCo(NCS)4)
David Nelson and Leonard W. Ter Haar
pp 182 - 188; DOI:
10.1021/ic00054a012
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Slow intramolecular electron transfer in a ruthenium(III)-titanium(III) redox intermediate having a dianion derived from a dihydroxyquinone as bridging ligand
Kejian Lu and Joseph E. Earley
pp 189 - 193; DOI:
10.1021/ic00054a013
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Monomeric and oligomeric complexes of ruthenium and osmium with tetra-2-pyridyl-1,4-pyrazine (TPPZ)
Claudia R. Arana and Hector D. Abruna
pp 194 - 203; DOI:
10.1021/ic00054a014
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Reactivity studies of mononuclear and dinuclear vanadium-sulfide-thiolate compounds
Shawn C. Sendlinger, John R. Nicholson, Emil B. Lobkovsky, John C. Huffman, Dieter Rehder, and George Christou
pp 204 - 210; DOI:
10.1021/ic00054a015
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Preparation and characterization of iron complexes of the penta-p-tolylcyclopentadienyl and o-tolyltetraphenylcyclopentadienyl ligands
Leslie D. Field, Anthony F. Masters, Michelle Gibson, Devin R. Latimer, Trevor W. Hambley, and Irmi E. Buys
pp 211 - 217; DOI:
10.1021/ic00054a016
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Synthesis, x-ray crystal structure, and phosphine-exchange reactions of the hafnium(III)-hafnium(III) dimer Hf2Cl6(PEt3)4
Matthew E. Riehl, Scott R. Wilson, and Gregory S. Girolami
pp 218 - 222; DOI:
10.1021/ic00054a017
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Synthesis and decomposition of benzenediazonium tris((trifluoromethyl)sulfonyl)methanide, C6H5N2+(CF3SO2)3C- and benzenediazonium bis((trifluoromethyl)sulfonyl)amide C6H5N2+(CF3SO2)2N- and the cyclic analog, C6H5N2+ cyclo-SO2(CF2)3SO2N-
Shi Zheng Zhu and D. D. DesMarteau
pp 223 - 226; DOI:
10.1021/ic00054a018
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Photochemistry of iodocuprate(I) complexes
Otto Horvath, Janos H. Fendler, and Kenneth L. Stevenson
pp 227 - 230; DOI:
10.1021/ic00054a019
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Synthesis and structural characterization of tetrakis(tetraethylammonium) hexatelluridodistannate(4-)
Mohammad A. Ansari, John C. Bollinger, and James A. Ibers
pp 231 - 232; DOI:
10.1021/ic00054a020
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A new water-soluble phosphine for use in aqueous organometallic systems. Products from the reactions of 2,3-bis(diphenylphosphino)maleic anhydride with water and oxygen
Alfred Avey, David M. Schut, Timothy J. R. Weakley, and David R. Tyler
pp 233 - 236; DOI:
10.1021/ic00054a021
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Spectroscopic and crystallographic characterization of tricarbonylchloro(.sigma.2-terpyridyl)rhenium. 2D-NMR evidence for a linkage isomerization reaction
Edgar R. Civitello, Peter S. Dragovich, Timothy B. Karpishin, Sabrina G. Novick, Geoffrey Bierach, John F. O'Connell, and T. David Westmoreland
pp 237 - 241; DOI:
10.1021/ic00054a022
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A convenient synthesis of carboranyl aldehydes from (hydroxymethyl)carboranes
Xiaoguang Yang and M. Frederick Hawthorne
pp 242 - 243; DOI:
10.1021/ic00054a023
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Unusually high redox potentials of two copper(II) compounds of 1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane. [Erratum to document cited in CA117(4):35422a]
Willem G. Haanstra, M. Fernanda Cabral, Joao de O. Caabral, Willem L. Driessen, and Jan Reedijk
pp 244 - 244; DOI:
10.1021/ic00054a024
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Issue 3


Isolation and crystal structure of a six coordinate yttrium trichloride complex of .epsilon.-caprolactone, YCl3(C6H10O2)3
William J. Evans, Julie L. Shreeve, and Robert J. Doedens
pp 245 - 246; DOI:
10.1021/ic00055a001
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Structure and solution properties of a dimeric tetrahedral vanadium(V) chloride alkoxide complex
Debbie C. Crans, Robert A. Felty, Oren P. Anderson, and Mary M. Miller
pp 247 - 248; DOI:
10.1021/ic00055a002
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New precursors for barium MOCVD. .beta.-Ketoiminate complexes containing appended polyether "lariats"
Douglas L. Schulz, Bruce J. Hinds, Charlotte L. Stern, and Tobin J. Marks
pp 249 - 250; DOI:
10.1021/ic00055a003
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Applicability of the Marcus relationship to copper(II/I) electron transfer. Comparison of NMR self-exchange relaxation and reduction and oxidation cross-reaction kinetics for a macrocyclic amino tetrathiaether-copper(II/I) complex in aqueous solution
Ana M. Q. Vande Linde, Bryan C. Westerby, L. A. Ochrymowycz, and D. B. Rorabacher
pp 251 - 257; DOI:
10.1021/ic00055a004
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Substituent effects and bonding characteristics in (o-benzoquinone diimine)bis(bipyridine)ruthenium(II) complexes
Hitoshi Masui, A. B. P. Lever, and Elaine S. Dodsworth
pp 258 - 267; DOI:
10.1021/ic00055a005
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Studies on transition-metal oxo and nitrido complexes. 13. Perruthenate and ruthenate anions as catalytic organic oxidants
Alan J. Bailey, William P. Griffith, Sahar I. Mostafa, and Paul A. Sherwood
pp 268 - 271; DOI:
10.1021/ic00055a006
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Mixed valency in binuclear cyano-bridged manganese bis(carbonyl) complexes and stereochemical control of their oxidation. A molecular orbital study
Gabino A. Carriedo, Neil G. Connelly, Santiago Alvarez, Enrique Perez-Carreno, and Santiago Garcia-Granda
pp 272 - 276; DOI:
10.1021/ic00055a007
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Interpretation of the second hyperpolarizability of bis(ethylene-1,2-dithiolato)nickel and some of its derivatives. A comparative study
M. G. Papadopoulos, J. Waite, C. S. Winter, and S. N. Oliver
pp 277 - 280; DOI:
10.1021/ic00055a008
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Resonance Raman investigation of nitric oxide bonding in iron porphyrins: detection of the Fe-NO stretching vibration
Leigh Ann Lipscomb, Bao Shiang Lee, and Nai Teng Yu
pp 281 - 286; DOI:
10.1021/ic00055a009
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Perfluoroalkyl(N-pentafluorosulfanyl)azidoazomethines and perfluoroalkyl(N-pentafluorosulfanyl)carbodiimides
Earnest O. John, Hans Georg Mack, Heinz Oberhammer, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 287 - 290; DOI:
10.1021/ic00055a010
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(Octaethylazaporphyrinato)iron(III) chloride: its structure in the solid state and in solution
Alan L. Balch, Marilyn M. Olmstead, and Nasser Safari
pp 291 - 296; DOI:
10.1021/ic00055a011
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Synthesis and properties of the iron(II) complex of a pentadentate ligand derived from diazaoxacyclononane
Witold S. Szulbinski, P. Richard Warburton, Daryle H. Busch, and Nathaniel W. Alcock
pp 297 - 302; DOI:
10.1021/ic00055a012
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(Hydrosilyl)tungsten complexes of the type (C5Me5)(OC)2(Me3P)W-SiR3 (SiR3 = SiH3, SiH2Me, SiHMe2, SiHClMe, SiHCl2): synthesis, crystal structure, and detailed vibrational analysis
Siegfried Schmitzer, Udo Weis, Harald Kaeb, Wolfgang Buchner, Wolfgang Malisch, Thomas Polzer, Uwe Posset, and Wolfgang Kiefer
pp 303 - 309; DOI:
10.1021/ic00055a013
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Synthesis and properties of new DNA cleavage agents based on oxoruthenium(IV)
Nishi Gupta, Neena Grover, Gregory A. Neyhart, Phirtu Singh, and H. Holden Thorp
pp 310 - 316; DOI:
10.1021/ic00055a014
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Mechanism of associatively controlled ligand substitution in square-planar bis(N-alkylsalicylaldiminato)nickel(II) complexes: kinetic, spectroscopic, and thermodynamic characterization of adducts and intermediates
Harald Hoss and Horst Elias
pp 317 - 323; DOI:
10.1021/ic00055a015
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Correlation of CrOCr .pi.-bonding strength with .pi.-donor effectiveness of bridging and nonbridging ligands in (tris(2-pyridylmethyl)amine)chromium(III) dimers
Thomas F. Tekut, Charles J. O'Connor, and Robert A. Holwerda
pp 324 - 328; DOI:
10.1021/ic00055a016
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Preparation, characterization, and reaction of novel dioxoruthenium(VI) porphyrin cation radical complexes
Yuichi Tokita, Kazuya Yamaguchi, Yoshihito Watanabe, and Isao Morishima
pp 329 - 333; DOI:
10.1021/ic00055a017
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Reactions of two-coordinate phosphines with acetylenes: synthesis of new allenic and acetylenic phosphines
Christo M. Angelov and Robert H. Neilson
pp 334 - 336; DOI:
10.1021/ic00055a018
PDF
NMR spectroscopic evidence for the existence of tellurium-containing chalcogen rings and polymers in sulfur-tellurium and sulfur-selenium-tellurium melts
Tristram Chivers, Risto S. Laitinen, Kenneth J. Schmidt, and Jari Taavitsainen
pp 337 - 340; DOI:
10.1021/ic00055a019
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Synthesis of (dialkylamino)disilanes
Yanjian Wan and John G. Verkade
pp 341 - 344; DOI:
10.1021/ic00055a020
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Potassium complexes containing both crown ether and tertiary phosphine oxide ligands
Vladimir V. Grushin, Corinne Bensimon, and Howard Alper
pp 345 - 346; DOI:
10.1021/ic00055a021
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Synthesis, structure, and reactivity of Lewis acidic cyclopentadienyltitanium dithiolate complexes
T. Timothy Nadasdi, Yujin Huang, and Douglas W. Stephan
pp 347 - 356; DOI:
10.1021/ic00055a022
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Studies on the electronic structure of titanium, zirconium and hafnium tetrachloride type molecules by the MS-X.alpha. method
V. Subramanian, M. Vijayakumar, and T. Ramasami
pp 357 - 359; DOI:
10.1021/ic00055a023
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Syntheses and characterization of dichlorozirconium porphyrin complexes and their novel organometallic derivatives. X-ray structure of Zr(TPP)Cl2(THF)
Hee Joon Kim, Dongmok Whang, Kimoon Kim, and Youngkyu Do
pp 360 - 362; DOI:
10.1021/ic00055a024
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Bromination of dibromobis(diamine)nickel complexes. Crystal structure of trans-dibromobis(ethylenediamine)nickel(III) bromide, [Ni(en)2br2]Br
Masahiro Yamashita, Emiko Tsuruta, Kazuo Inoue, Munetaka Oyama, and Koshiro Toriumi
pp 363 - 365; DOI:
10.1021/ic00055a025
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Effect of ring configuration on axial ligand binding to nickel(II) octaethylisobacteriochlorins
Alexander D. Procyk and David F. Bocian
pp 366 - 367; DOI:
10.1021/ic00055a026
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Amido complexes of (cyclopentadienyl)dichlorotitanium(IV): titanium-nitrogen multiple-bond character. [Erratum to document cited in CA117(13):131316q]
Dean M. Giolando, Kristin Kirschbaum, Lisa J. Graves, and Urs Bolle
pp 368 - 368; DOI:
10.1021/ic00055a027
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Issue 4


Spectroscopic and structural properties of binuclear platinum-terpyridine complexes
James A. Bailey, Vincent M. Miskowski, and Harry B. Gray
pp 369 - 370; DOI:
10.1021/ic00056a001
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Carbynes and carbenes in coordination chemistry: a new class of pentaammine and tetraammine complexes of osmium(II)
L. Mark Hodges, Michal Sabat, and W. Dean Harman
pp 371 - 372; DOI:
10.1021/ic00056a002
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Bis(carbonyl)silver tetrakis(pentafluorooxotellurato)borate: the first structurally characterized M(CO)2 complex
Paul K. Hurlburt, Jeffrey J. Rack, Steve F. Dec, Oren P. Anderson, and Steven H. Strauss
pp 373 - 374; DOI:
10.1021/ic00056a003
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Oxidized nickel-substituted rubredoxin as a model for the Ni-C EPR signal of NiFe hydrogenases
Yun Hua Huang, Jae Bum Park, Michael W. W. Adams, and Michael K. Johnson
pp 375 - 376; DOI:
10.1021/ic00056a004
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Molecular and crystal structure of .mu.2-[TCNE]2- complex: [(Ph3P)2(OC)Ir]2-[TCNE]
Gordon T. Yee, Joseph C. Calabrese, Carlos Vazquez, and Joel S. Miller
pp 377 - 378; DOI:
10.1021/ic00056a005
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Swinging of the bent nitrosyl ligand in (nitrosyl- 15N)(meso-tetraphenylporphinato)cobalt: a solid-state motion detected by nitrogen-15 CPMAS NMR spectroscopy
Christopher J. Groombridge, Leslie F. Larkworthy, and Joan Mason
pp 379 - 380; DOI:
10.1021/ic00056a006
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Nickel(II) chelation by three bicyclic tetrathioethers: solution and solid-state data
John M. Desper, James R. Vyvyan, Michael J. Mayer, Leo A. Ochrymowycz, and Samuel H. Gellman
pp 381 - 382; DOI:
10.1021/ic00056a007
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Strontium barium copper oxide carbonate (Sr2-xBaxCuO2(CO3)): a series of antiferromagnetic layered oxide carbonates
Alexandros Lappas, Kosmas Prassides, A. Robert Armstrong, and Peter P. Edwards
pp 383 - 385; DOI:
10.1021/ic00056a008
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The oxotrifluoroxenon(VI) cation: x-ray crystal structure of XeOF3+SbF6- and a solution oxygen-17 and xenon-129 nuclear magnetic resonance study of the 17,18O-enriched XeOF3+ cation
Helene P. A. Mercier, Jeremy C. P. Sanders, Gary J. Schrobilgen, and Scott S. Tsai
pp 386 - 393; DOI:
10.1021/ic00056a009
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Picosecond excited-state dynamics in octahedral cobalt(III) complexes: intersystem crossing versus internal conversion
James K. McCusker, Kevin N. Walda, Douglas Magde, and David N. Hendrickson
pp 394 - 399; DOI:
10.1021/ic00056a010
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5d Orbital and electronic localization in rare earth diiodides and praseodymium halides, Pr2X5 (X = Br, I)
Yunchao Tian and Timothy Hughbanks
pp 400 - 405; DOI:
10.1021/ic00056a011
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Resonance Raman studies of nickel tetrathiolates and nickel-substituted rubredoxins and desulforedoxin
Yun Hua Huang, Isabel Moura, Jose J. G. Moura, Jean LeGall, Jae Bum Park, Michael W. W. Adams, and Michael K. Johnson
pp 406 - 412; DOI:
10.1021/ic00056a012
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Amidate ligands for the oxovanadium(IV) cation: design, synthesis, structure, and spectroscopic and electrochemical properties
A. S. Borovik, Torin M. Dewey, and Kenneth N. Raymond
pp 413 - 421; DOI:
10.1021/ic00056a013
PDF
Spectrophotometric evidence for involvement of aromatic residues in the interaction of ferreascidin with the ferric ion
Steven W. Taylor, Clifford J. Hawkins, and Donald J. Winzor
pp 422 - 427; DOI:
10.1021/ic00056a014
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Metal ion-tetracycline interactions in biological fluids. 10. Structural investigations on copper(II) complexes of tetracycline, oxytetracycline, chlortetracycline, 4-(dedimethylamino)tetracycline, and 6-desoxy-6-demethyltetracycline and discussion of their binding modes
Malgorzata Jezowska-Bojczuk, Luc Lambs, Henryk Kozlowski, and Guy Berthon
pp 428 - 437; DOI:
10.1021/ic00056a015
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Electrochemical and spectroelectrochemical characterization of (5,10,15,20-tetrakis(1-methyl-4-pyridyl)porphinato)manganese(III) chloride, [(TMpyP)MnIIICl]4+(Cl-)4, in N,N-dimethylformamide
Eric Van Caemelbecke, Wlodzimierz Kutner, and Karl M. Kadish
pp 438 - 444; DOI:
10.1021/ic00056a016
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Linkage isomerization, acid and base hydrolysis, and oxidation reactions of coordinated methanesulfinate: oxygen- and sulfur-bonded isomers of pentaammine(methanesulfinato)cobalt(2+)
W. Gregory Jackson, Silvia S. Jurisson, and Margaret A. O'Leary
pp 445 - 449; DOI:
10.1021/ic00056a017
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Synthesis, solution structure, and reactivity of oxygen-bound amides on cobalt(III)
Patricia M. Angus, David P. Fairlie, and W. Gregory Jackson
pp 450 - 459; DOI:
10.1021/ic00056a018
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Molybdenum-95 T1 measurements of molybdenum hexacarbonyl encapsulated in NaY zeolite
Peter A. Cybulski, Daniel J. Gillis, and Michael C. Baird
pp 460 - 462; DOI:
10.1021/ic00056a019
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Structure and nonrigidity of undecahydrodecaborate(1-). An ab initio/IGLO/NMR study
A. M. Mebel, O. P. Charkin, Michael Buehl, and Paul v. R. Schleyer
pp 463 - 468; DOI:
10.1021/ic00056a020
PDF
Theoretical prediction of the structure and nonrigidity of octahydroheptaborate(1-). Application of the ab initio/IGLO/NMR method
A. M. Mebel, O. P. Charkin, and Paul v. R. Schleyer
pp 469 - 473; DOI:
10.1021/ic00056a021
PDF
Sodium borohydride reduction of cobalt ions in nonaqueous media. Formation of ultrafine particles (nanoscale) of cobalt metal
G. N. Glavee, K. J. Klabunde, C. M. Sorensen, and G. C. Hadjipanayis
pp 474 - 477; DOI:
10.1021/ic00056a022
PDF
Preparative and structural chemistry of chiral P,N-bidentate complexes of palladium(II) and platinum(II)
Alberto Albinati, Francesca Lianza, Heinrich Berger, Paul S. Pregosin, Heinz Ruegger, and Roland W. Kunz
pp 478 - 486; DOI:
10.1021/ic00056a023
PDF
Application of the ab initio/IGLO/NMR method to the structure confirmation of the [.mu.5,6-BHNR2-nido-2,4-C2B4H6]- ion intermediate observed during the interaction of closo-2,4-C2B5H7 with LiNR2
Thomas Onak, James Tseng, Martin Diaz, Dan Tran, Joachin Arias, Sergio Herrera, and Dwayne Brown
pp 487 - 489; DOI:
10.1021/ic00056a024
PDF
The phosphorus-31 resonance of hexafluorophosphate(1-) and related subspecies intercalated in graphite as a function of temperature
Henry Selig and Amos J. Leffler
pp 490 - 490; DOI:
10.1021/ic00056a025
PDF
Ferromagnetism in decamethylchromocenium tetracyanoethylenide: support for the spin-polarization mechanism of spin coupling in metallocenium charge-transfer salts
David M. Eichhorn, David C. Skee, William E. Broderick, and Brian M. Hoffman
pp 491 - 492; DOI:
10.1021/ic00056a026
PDF

Issue 5


Complexes of quinone-functionalized chelating ligands for multiple electron/proton transfer reduction reactions
William S. Durfee and Cortlandt G. Pierpont
pp 493 - 494; DOI:
10.1021/ic00057a001
PDF
Factors influencing the thermodynamics of molecular hydrogen oxidation addition to Vaska-type complexes (trans-Ir(PR3)2(CO)X): predictions from ab initio calculations and experimental verification
Faraj Abu-Hasanayn, Karsten Krogh-Jespersen, and Alan S. Goldman
pp 495 - 496; DOI:
10.1021/ic00057a002
PDF
Anhydrous yttrium acetylacetonate and the course of thermal "dehydration" of Y(acac)3.3H2O
Eyal H. Barash, Paul S. Coan, Emil B. Lobkovsky, William E. Streib, and Kenneth G. Caulton
pp 497 - 501; DOI:
10.1021/ic00057a003
PDF
Synthesis and characterization of novel yttrium-copper alkoxide clusters
Wolfgang Bidell, Joachim Doering, H. William Bosch, Hans Ulrich Hund, Elisabeth Plappert, and Heinz Berke
pp 502 - 507; DOI:
10.1021/ic00057a004
PDF
First-row transition metal complexes of the hexadentate macrocycle 1,4,7-tris(5-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (LH3). Crystal structures of [LTiIV]BPh4, [LCrIII], [LFeIII], and [(LH)2FeIII2](ClO4)2.2H2O
Ulf Auerbach, Thomas Weyhermueller, Karl Wieghardt, Bernhard Nuber, Eckhard Bill, Christian Butzlaff, and Alfred X. Trautwein
pp 508 - 519; DOI:
10.1021/ic00057a005
PDF
The (.mu.-oxo)bis[trichloroferrate(III)] dianion revisited
Gabriele Haselhorst, Karl Wieghardt, Stefan Keller, and Bernhard Schrader
pp 520 - 525; DOI:
10.1021/ic00057a006
PDF
Solution structures of copper coordination compounds containing ligands with ether or thioether donors
Huikang Wu and C. Robert Lucas
pp 526 - 531; DOI:
10.1021/ic00057a007
PDF
Three-coordinate thiolato complexes of zinc: solution and solid-state structures and EHMO analysis of the bonding pattern of [Zn(S-tert-Bu3C6H2-2,4,6)2]2
Manfred Bochmann, Gabriel Bwembya, Roger Grinter, Jianjun Lu, Kevin J. Webb, David J. Williamson, Michael B. Hursthouse, and Muhammed Mazid
pp 532 - 537; DOI:
10.1021/ic00057a008
PDF
Transition-metal complexes with sulfur ligands. 94. Synthesis and reactivity of nickel, palladium, and platinum complexes with the thiolate carbene ligand 'S2C'2-. X-ray structure determinations of [Ni(PMe3)('S2C')], [Ni(PPh3)('S2C')], [Ni('SC')2], [Pt(PMe3)('S2C')], and ('S2CO')2
Dieter Sellmann, Werner Prechtel, Falk Knoch, and Matthias Moll
pp 538 - 546; DOI:
10.1021/ic00057a009
PDF
Oxidative addition of methyl iodide to monosubstituted and disubstituted derivatives of osmium pentacarbonyl
Gianfranco Bellachioma, Giuseppe Cardaci, Alceo Macchioni, and Pierfrancesco Zanazzi
pp 547 - 553; DOI:
10.1021/ic00057a010
PDF
Oxidative addition of methyl iodide to monosubstituted and disubstituted derivatives of ruthenium pentacarbonyl: preparation of neutral and ionic complexes of ruthenium
Gianfranco Bellachioma, Giuseppe Cardaci, Alceo Macchioni, and Andrea Madami
pp 554 - 560; DOI:
10.1021/ic00057a011
PDF
A molecular orbital comparison of molybdenum-sulfur dimers with sulfido ligands bridged by CH2 and FeCp fragments
D. L. DuBois, F. Kvietok, and M. Rakowski DuBois
pp 561 - 564; DOI:
10.1021/ic00057a012
PDF
Kinetics and mechanism of the oxidation of bisulfite by peroxymonosulfate
Robert E. Connick, Shaoyung Lee, and Raymond Adamic
pp 565 - 571; DOI:
10.1021/ic00057a013
PDF
Formation of cryptatium species in solution: electrochemistry of bipyridyl-, bipyrimidyl-, and bithiazole-based cryptates
Luis Echegoyen, Eduardo Perez-Cordero, Jean Bernard Regnouf de Vains, Christine Roth, and Jean Marie Lehn
pp 572 - 577; DOI:
10.1021/ic00057a014
PDF
EPR and proton ENDOR study of the solution equilibria of bis(2-ethyl-2-hydroxybutanoato(2-))oxochromate(V) and bis(2-hydroxy-2-methylbutanoato(2-))oxochromate(V)
Mario Branca, Alessandro Dessi, Giovanni Micera, and Daniele Sanna
pp 578 - 581; DOI:
10.1021/ic00057a015
PDF
Thermodynamics, proton NMR, and fluorescence studies for the complexation of trivalent lanthanides, calcium(2+), copper(2+), and zinc(2+) by diethylenetriaminepentaacetic acid bis(methylamide)
Emil N. Rizkalla, Gregory R. Choppin, and William Cacheris
pp 582 - 586; DOI:
10.1021/ic00057a016
PDF
Equilibrium and kinetic studies of lanthanide complexes of macrocyclic polyamino carboxylates
Krishan Kumar, C. Allen Chang, and M. F. Tweedle
pp 587 - 593; DOI:
10.1021/ic00057a017
PDF
Coordination compounds of pentaaminerhenium(III/II)
Stephen D. Orth, Joseph Barrera, Michal Sabat, and W. Dean Harman
pp 594 - 601; DOI:
10.1021/ic00057a018
PDF
[Tris(trimethylsilyl)silyl]lead(IV) derivatives
S. P. Mallela and R. A. Geanangel
pp 602 - 605; DOI:
10.1021/ic00057a019
PDF
Unusual tridentate N3 capping coordination behavior of hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene, N3P3(3,5-Me2Pz)6: synthesis, spectroscopy, and electrochemistry of mono- and dinuclear copper(II) complexes and the x-ray structure of N3P3(3,5-Me2Pz)6.cntdot.CuCl2
K. R. Justin Thomas, V. Chandrasekhar, Parthasarathy Pal, Syrona R. Scott, Randal Hallford, and A. W. Cordes
pp 606 - 611; DOI:
10.1021/ic00057a020
PDF
Chemistry of [Cp*Rh(.mu.-Cl)]2 and its dioxygen and nitrosobenzene insertion products
David W. Hoard and Paul R. Sharp
pp 612 - 620; DOI:
10.1021/ic00057a021
PDF
Structure and properties of a tetranuclear iron(III) cage complex. A model for hemerythrin
Jonathan L. Sessler, John W. Sibert, Vincent Lynch, John T. Markert, and Chris L. Wooten
pp 621 - 626; DOI:
10.1021/ic00057a022
PDF
Effects of metal and ring reduction on metallo(octaethylisobacteriochlorins). Resonance Raman spectra of the nickel(I), copper(I), and zinc(II) radical anion complexes
Alexander D. Procyk, Alan M. Stolzenberg, and David F. Bocian
pp 627 - 633; DOI:
10.1021/ic00057a023
PDF
Saturation magnetization of ureases from Klebsiella aerogenes and jack bean: no evidence for exchange coupling between the two active site nickel ions in the native enzymes
Edmund P. Day, Jim Peterson, Mariana S. Sendova, Matthew J. Todd, and Robert P. Hausinger
pp 634 - 638; DOI:
10.1021/ic00057a024
PDF
Pressure-induced luminescence quenching of terbium-doped oxide sulfides
John K. Gleason, Henry W. Offen, and W. Dale Turley
pp 639 - 641; DOI:
10.1021/ic00057a025
PDF
Cryogenic reactions of gallium with molecular hydrogen and methane
Z. L. Xiao, R. H. Hauge, and J. L. Margrave
pp 642 - 646; DOI:
10.1021/ic00057a026
PDF
Ion pairing and solvation effects in the intra-5f2 absorption spectra of dimeric uranium(IV) alkoxide complexes
John M. Berg, Alfred P. Sattelberger, David E. Morris, William G. Van der Sluys, and Patrick Fleig
pp 647 - 653; DOI:
10.1021/ic00057a027
PDF
From isolated complex units to one-dimensional molecular chains: optical investigations of ternary alkali-metal thioferrates(III)
Rolf Packroff and Hans Herbert Schmidtke
pp 654 - 663; DOI:
10.1021/ic00057a028
PDF
Synthesis, crystallographic and spectroscopic characterization, and magnetic properties of mixed-ligand oxovanadium(IV) hydrotris(3,5-dimethylpyrazolyl)borate complexes
David Collison, David R. Eardley, Frank E. Mabbs, Anne K. Powell, and Scott S. Turner
pp 664 - 671; DOI:
10.1021/ic00057a029
PDF
Polyoxo alkoxide clusters of vanadium: structural characterization of the decavanadate core in the "fully reduced" vanadium(IV) species [V10O16{(OCH2)3CCH2CH3}4]4- and [V10O14(OH)2{(OCH2)3CCH2OH}4]2- and in the mixed-valence clusters [VIV8VV2O16{(OCH2)3CR}4]2- (R = -CH2CH3, -CH3)
M. Ishaque Khan, Qin Chen, D. P. Goshorn, and Jon Zubieta
pp 672 - 680; DOI:
10.1021/ic00057a030
PDF
A new synthetic route to quadruply bonded tungsten-tungsten and molybdenum-tungsten compounds of the type MM'X4(PR3)4, X = Cl or Br. Structural characterization of quadruply bonded WWBr4(.mu.-dppm)2 and MoWBr4(PMe2Ph)4 and phosphorus-31{proton} NMR spectra of these and related compounds
F. A. Cotton, Judith L. Eglin, and Chris A. James
pp 681 - 686; DOI:
10.1021/ic00057a031
PDF
Unusual isomers of edge-sharing bioctahedral complexes
F. A. Cotton, Judith L. Eglin, and Chris A. James
pp 687 - 694; DOI:
10.1021/ic00057a032
PDF
The first ferromagnetic tetranuclear nickel(II) complex with a .mu.-azido bridge. Structure and magnetic properties of [Ni4(.mu.-N3)4(2-oxo-1,3-diaminopropane)2(2-hydroxo-1,3-diaminopropane)2](ClO4)2
Joan Ribas, Montserrat Monfort, Ramon Costa, and Xavier Solans
pp 695 - 699; DOI:
10.1021/ic00057a033
PDF
Strong metal-metal bonds between trans-bis(amine)platinum(II) and -palladium(II) in heteronuclear complexes of cytosine nucleobases: preparation, x-ray structures, and NMR spectroscopy
Michael Krumm, Ennio Zangrando, Lucio Randaccio, Stephan Menzer, and Bernhard Lippert
pp 700 - 712; DOI:
10.1021/ic00057a034
PDF
Bridging bis-bidentate coordination of the usually tetradentate 5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine macrocyclic ligand: experimental and theoretical study of [Mo2(O2CR)2(C22H22N4)]. Comparative electrochemical behavior of the [Mo-Mo] core with quadruple bond
J. M. Kerbaol, E. Furet, J. E. Guerchais, Y. Le Mest, J. Y. Saillard, J. Sala-Pala, and L. Toupet
pp 713 - 721; DOI:
10.1021/ic00057a035
PDF
Supramolecular assemblies of porphyrins and phthalocyanines bearing oppositely charged substituents. First evidence of heterotrimer formation
J. F. Lipskier and T. H. Tran-Thi
pp 722 - 731; DOI:
10.1021/ic00057a036
PDF
Metal oligo-yne polymers: electronic structures of [-(L)nMC.tplbond.CRC.tplbond.C-]x polymers
Gilles Frapper and Miklos Kertesz
pp 732 - 740; DOI:
10.1021/ic00057a037
PDF
Spin population analysis and local spin Hamiltonian parameters in exchange-coupled system
P. Bertrand
pp 741 - 745; DOI:
10.1021/ic00057a038
PDF
Electronic structure of elemental calcium and zinc
Theodore D. Brennan and Jeremy K. Burdett
pp 746 - 749; DOI:
10.1021/ic00057a039
PDF
Oxygen-oxygen pair potentials and the origin of nonstoichiometry in yttrium barium copper oxide YBa2Cu3O7-.delta.
Jeremy K. Burdett and John T. Chung
pp 750 - 755; DOI:
10.1021/ic00057a040
PDF
Laser-induced luminescence studies of europium hexaazamacrocycle Eu(HAM)3+. An evaluation of complex stability and the use of the gadolinium analog as a relaxation agent in yttrium-89 NMR
JoAnne Bruno, Brian R. Herr, and William D. Horrocks
pp 756 - 762; DOI:
10.1021/ic00057a041
PDF
Ligand configuration on weakly paramagnetic (.beta.-imino carbonyl enolato)nickel complexes: a combined solid-state carbon-13 NMR and infrared study
Marino Basato, Giancarlo Favero, Augusto C. Veronese, and Alfonso Grassi
pp 763 - 768; DOI:
10.1021/ic00057a042
PDF
Variable valence MnO3S3 species. The case of tris(1-hydroxy-2-pyridinethionato)manganese(II,III,IV) and its structural correlation with the cobalt(III) analog
Vadivelu Manivannan, Somnath Dutta, Partha Basu, and Animesh Chakravorty
pp 769 - 771; DOI:
10.1021/ic00057a043
PDF
Synthesis, characterization, and x-ray structure of the uranium thiolate complex U(S-2,6-Me2C6H3)[N(SiMe3)2]3
David L. Clark, Mary M. Miller, and John G. Watkin
pp 772 - 774; DOI:
10.1021/ic00057a044
PDF
Observation of a novel cyclic tetrametavanadate anion isolated from aqueous solution
Pascual Roman, Ana San Jose, Antonio Luque, and Juan M. Gutierrez-Zorrilla
pp 775 - 776; DOI:
10.1021/ic00057a045
PDF

Issue 6


Synthesis and characterization of the cubane-type molybdenum-indium mixed-metal cluster [Mo3InS4(pts)2(H2O)10]3+
Genta Sakane and Takashi Shibahara
pp 777 - 778; DOI:
10.1021/ic00058a001
PDF
Synthesis and crystal structure of zinc-vanadium complex [ZnII(LH3)(L)VIV][PF6]3 [LH3 = N,N',N''-tris(2S)-2-hydroxypropyl-1,4,7-triazacyclononane]: a chiral mixed-metal pendant-arm macrocyclic dimer containing nonvanadyl vanadium(IV)
Ian Fallis, Louis J. Farrugia, Norman M. Macdonald, and Robert D. Peacock
pp 779 - 780; DOI:
10.1021/ic00058a002
PDF
Synthesis and oxidation potential of 3-ferrocenylpyrrole
Timothy L. Rose and Allan B. Kon
pp 781 - 782; DOI:
10.1021/ic00058a003
PDF
Spectroelectrochemical characterization of tetrakis(1,8-diisocyanomenthane)diiridium(1+) and (0)
Michael G. Hill, Andrew G. Sykes, and Kent R. Mann
pp 783 - 784; DOI:
10.1021/ic00058a004
PDF
Nitrogen-nitrogen bond cleavage reactions. Generation of ammonia and amines from substituted hydrazido(2-) complexes of tungsten
Jeffery R. D. DeBord, T. Adrian George, Yuanda Chang, Qin Chen, and Jon Zubieta
pp 785 - 786; DOI:
10.1021/ic00058a005
PDF
Chemistry of sulfur halides. 58. Monofluorosulfonium hexafluoroantimonate, H2SF+SbF6-
R. Minkwitz, G. Nowicki, B. Baeck, and W. Sawodny
pp 787 - 790; DOI:
10.1021/ic00058a006
PDF
Synthesis, structure, and nuclear magnetic resonance spectra cadmium-111, sodium-23 of tetramethylammonium hexakis(thiobenzoato)(dicadmium sodium)ate. A trinuclear anion with cadmium in nearly trigonal planar coordination and sodium in octahedral coordination
Jagadese J. Vittal and Philip A. W. Dean
pp 791 - 794; DOI:
10.1021/ic00058a007
PDF
Synthesis, crystal structure, and magnetic properties of (.mu.-bipyrimidine)(cyanato)copper(II) and -(thiocyanato)copper(II) complexes
Miguel Julve, Michel Verdaguer, Giovanni De Munno, Jose Antonio Real, and Giuseppe Bruno
pp 795 - 802; DOI:
10.1021/ic00058a008
PDF
Addition reactions of the unsaturated rhenium cluster anion [Re4(.mu.-H)3(.mu.3-H)2(CO)12]- with carbon monoxide, triphenylphosphine and acetonitrile and characterization of an unstable adduct with water. X-ray crystal structure of the tetraethylammonium salt of the derivative [Re4(.mu.-H)4(.mu.3-H)(CO)12(PPh3)]-
T. Beringhelli, G. D'Alfonso, A. Minoja, G. Ciani, and D. M. Proserpio
pp 803 - 810; DOI:
10.1021/ic00058a009
PDF
Pyridine-2-thiolate binding of osmium(III). Geometrical isomers of [Os(C5H4NS)2(PPh3)2]PF6.nH2O (n = 1, 0)
Amitava Pramanik, Nilkamal Bag, and Animesh Chakravorty
pp 811 - 815; DOI:
10.1021/ic00058a010
PDF
Synthesis and structural characterization of the alkaline earth aryloxide aggregates H2Ba8(.mu.5-O)2(OPh)14(HMPA)6 and H2Sr6Ba2(.mu.5-O)2(OPh)14(HMPA)6. A new structural type displaying metal ion site selectivity
Kenneth G. Caulton, Malcolm H. Chisholm, Simon R. Drake, Kirsten Folting, and John C. Huffman
pp 816 - 820; DOI:
10.1021/ic00058a011
PDF
Application of the hydro(solvento)thermal technique to the synthesis of metal carbonyl chalcogenide clusters. 2. Synthesis and x-ray structures of [[Fe4Te4(CO)10]2(Te2)]2- and [[Fe2Se(CO)6]2(Se2)]2-
Song Ping Huang and Mercouri G. Kanatzidis
pp 821 - 825; DOI:
10.1021/ic00058a012
PDF
Synthesis, structures, and properties of the molecular assemblies of copper(I) and silver(I) complexes with phenazine. Novel donor-acceptor and huge polynuclear complexes
Megumu Munakata, Susumu Kitagawa, Naohiko Ujimaru, Masaki Nakamura, Masahiko Maekawa, and Hajime Matsuda
pp 826 - 832; DOI:
10.1021/ic00058a013
PDF
Molecular copper-barium compounds. Syntheses, crystal structures, and magnetic properties of two sandwich copper-barium complexes: BaCu4(bdmap)4(PyO)4(O2CCF3)2.0.5THF and BaCu4(deae)4(PyO)4(O2CCF3)2 (bdmap = 1,3-bis(dimethylamino)-2-propanolato, PyO = deprotonated 2-hydroxypyridine, deae = 2-(diethylamino)ethanolato)
Suning Wang, Steven J. Trepanier, and Michael J. Wagner
pp 833 - 840; DOI:
10.1021/ic00058a014
PDF
X-ray structure, EPR, and magnetic susceptibility of gallium(III) tris(3,5-di-tert-butyl-1,2-semibenzoquinonate), a main group triradical complex
Andrzej Ozarowski, Bruce R. McGarvey, Ahmed El-Hadad, Zhigang Tian, Dennis G. Tuck, Daniel J. Krovich, and Gary C. DeFotis
pp 841 - 847; DOI:
10.1021/ic00058a015
PDF
Steric and electronic effects of mono- and tridentate phosphine ligands on the basicities of the metal in tungsten tris(phosphine) tricarbonyl complexes
John R. Sowa, Valerio Zanotti, and Robert J. Angelici
pp 848 - 853; DOI:
10.1021/ic00058a016
PDF
Ferrocene-metallocyclam conjugates: new redox systems whose two-electron activity can be modulated through the medium
Giancarlo De Santis, Luigi Fabbrizzi, Maurizio Licchelli, Carlo Mangano, Piersandro Pallavicini, and Antonio Poggi
pp 854 - 860; DOI:
10.1021/ic00058a017
PDF
Arylxenon tetrafluoroborates: compounds of unexpected stability
D. Naumann, H. Butler, R. Gnann, and W. Tyrra
pp 861 - 863; DOI:
10.1021/ic00058a018
PDF
Electron transfer. 116. Reductions by trinuclear aquamolybdenum(III)
Sanchita Purohit Ghosh and E. S. Gould
pp 864 - 868; DOI:
10.1021/ic00058a019
PDF
Photoluminescence properties of the structurally analogous tetranuclear copper(I) clusters Cu4X4(dpmp)4 (X = I, Br, Cl; dpmp = 2-(diphenylmethyl)pyridine)
Chong Kul Ryu, Marcello Vitale, and Peter C. Ford
pp 869 - 874; DOI:
10.1021/ic00058a020
PDF
Characterization and intramolecular spin coupling of a monomeric a1u copper(II) porphyrin .pi.-cation radical
Hiroshi Fujii
pp 875 - 879; DOI:
10.1021/ic00058a021
PDF
Electronic structure of octahedral copper(I) cluster complexes: hexahydridohexakis(phosphine)hexacopper and carbidohexakis(phosphine)hexacopper(2+)
G. A. Bowmaker, M. Pabst, N. Roesch, and H. Schmidbaur
pp 880 - 887; DOI:
10.1021/ic00058a022
PDF
An imidazolate-bridged tetranuclear copper(II) complex: synthesis, magnetic and EPR studies, and crystal structure of [L4Cu4(Im)4](ClO4)4.2H2O (L = 1,4,7-triazacyclononane, Im = imidazolate anion)
Phalguni Chaudhuri, Ina Karpenstein, Manuela Winter, Marek Lengen, Christian Butzlaff, Eckhard Bill, Alfred X. Trautwein, Ulrich Floerke, and Hans Juergen Haupt
pp 888 - 894; DOI:
10.1021/ic00058a023
PDF
Kinetics of water proton exchange of pentaqua(cyanomethyl)chromium(2+) in aqueous acid
Kefei Wang and R. B. Jordan
pp 895 - 897; DOI:
10.1021/ic00058a024
PDF
Investigation of the photochemical, electrochemical, and spectroelectrochemical properties of an iridium(III)/ruthenium(II) mixed-metal complex bridged by 2,3,5,6-tetrakis(2-pyridyl)pyrazine
Lisa M. Vogler, Brian Scott, and Karen J. Brewer
pp 898 - 903; DOI:
10.1021/ic00058a025
PDF
The first [14]cyclidene complexes: relationships between macrocyclic ring size, lacunar cavity shape, and dioxygen affinity of the cobalt-cyclidene dioxygen carriers
Jihong Chen, Naidong Ye, Nathaniel W. Alcock, and Daryle H. Busch
pp 904 - 910; DOI:
10.1021/ic00058a026
PDF
Insight into the g .apprxeq. 16 EPR signals of reduced diiron-oxo proteins. Structure and properties of [FeII2BPMP{O2P(OC6H5)2}2]Cl
Ho G. Jang, Michael P. Hendrich, and Lawrence Que
pp 911 - 918; DOI:
10.1021/ic00058a027
PDF
Mercury binding to metallothioneins: formation of the Hg18-MT species
Wuhua Lu, Andrzej J. Zelazowski, and Martin J. Stillman
pp 919 - 926; DOI:
10.1021/ic00058a028
PDF
Moessbauer study of zinc-iron-sulfur ZnFe3S4 and nickel-iron-sulfur NiFe3S4 clusters in Pyrococcus furiosus ferredoxin
K. K. P. Srivastava, K. K. Surerus, R. C. Conover, M. K. Johnson, J. B. Park, M. W. W. Adams, and E. Munck
pp 927 - 936; DOI:
10.1021/ic00058a029
PDF
Ligand variation and metal ion binding specificity in zinc finger peptides
Beth Allyn Krizek, Denise L. Merkle, and Jeremy M. Berg
pp 937 - 940; DOI:
10.1021/ic00058a030
PDF
Reactions of (meso-.alpha.,.alpha.,.alpha.,.alpha.-tetrakis[o-(N-methylisonicotinamido)phenyl]porphyrin)iron(5+) and (meso-tetrakis[N-methylpyridinium-4-yl]porphyrin)iron(5+) with CN-, CO2- and O2-
Vicki Barnitz McLaughlin, M. Faraggi, and Daniel L. Leussing
pp 941 - 947; DOI:
10.1021/ic00058a031
PDF
A matrix photochemistry study on (fluorocarbonyl)sulfenyl bromide: the precursor of sulfur bromide fluoride
C. O. Della Vedova and H. G. Mack
pp 948 - 950; DOI:
10.1021/ic00058a032
PDF
Ab initio study of the coordination modes of tetrahydroborato ligands: what is the actual structure of the tris(tetrahydroborato)bis(trimethylphosphine) titanium complex
Francois Volatron, Miquel Duran, Agusti Lledos, and Yves Jean
pp 951 - 954; DOI:
10.1021/ic00058a033
PDF
Solid-state multinuclear NMR studies of ferroelectric, piezoelectric, and related materials
Steven F. Dec, Mark F. Davis, Gary E. Maciel, Charles E. Bronnimann, John J. Fitzgerald, and Sang Sub Han
pp 955 - 959; DOI:
10.1021/ic00058a034
PDF
Transition metal complexes with sulfur ligands. 95. Diazene, hydrazine, ammine and azido complexes with sulfur dominated [Ru(PPh3)('buS4')] fragments ('buS4'2- = 1,2-bis(2-mercapto-3,5-di-tert-butylphenylthio)ethanato(2-))
Dieter Sellmann, Joachim Kaeppler, Matthias Moll, and Falk Knoch
pp 960 - 964; DOI:
10.1021/ic00058a035
PDF
Preparation, structure, and magnetic properties of a tetrakis(carboxylato)diosmium(III) dichloride. Comparison with Os2(hp)4Cl2
F. Albert Cotton, Tong Ren, and Michael J. Wagner
pp 965 - 968; DOI:
10.1021/ic00058a036
PDF
Metal-metal-bonded compounds of lower-valent niobium and tantalum. Compounds containing the [Nb2Cl7(PR3)2]- and [Nb3Cl10(PR3)3]- ions and some clues as to how higher-nuclearity clusters are formed
F. Albert Cotton and Maoyu Shang
pp 969 - 976; DOI:
10.1021/ic00058a037
PDF
Oxidation of nickel thiolate ligands by dioxygen
Shaukat A. Mirza, Michelle A. Pressler, Manoj Kumar, Roberta O. Day, and Michael J. Maroney
pp 977 - 987; DOI:
10.1021/ic00058a038
PDF
Rhenium(V)-oxo complexes of neutral and monoanionic tetraazamacrocycles. X-ray structures of trans-oxohydroxo(1,4,8,11-tetraazacyclotetradecan-2-one)rhenium(V) perrhenate and trans-oxohydroxo(1,4,8,11-tetraazacyclotetradecane)rhenium(V) bis(perchlorate)
Brenda Winckler Tsang, Joseph Reibenspies, and Arthur E. Martell
pp 988 - 994; DOI:
10.1021/ic00058a039
PDF
Clusters as ligands. Comparison of the reactivity of (CO)9Co3(.mu.3-CR) (R = COOH, p-C6H4(CH2)2COOH) leading to the formation of Zn[p-C6H4(CH2)2CO2]2 vs MII4O[(CO)9Co3CCO2]6 (M = Zn, Co)
Wei Cen, Kenneth J. Haller, and Thomas P. Fehlner
pp 995 - 1000; DOI:
10.1021/ic00058a040
PDF
Ditopic crown thioethers. Synthesis and structures of anti-[Cu2(L)(PPh2Me)2][ClO4]2, syn-[Cu2(L)(.mu.-PPh2CH2CH2PPh2)][PF6]2, and anti-[Ag2(L)(PPh3)2][BF4]2 (L = 2,5,8,17,20,23-hexathia[9](1,2)[9](4,5)cyclophane)
Stephen J. Loeb and George K. H. Shimizu
pp 1001 - 1006; DOI:
10.1021/ic00058a041
PDF
Effects of cyclodextrin inclusion on the kinetics of the outer-sphere oxidation of 4-tert-butylpyrocatechol by transition metal complexes in acidic aqueous media
Jerome A. Imonigie and Donal H. Macartney
pp 1007 - 1012; DOI:
10.1021/ic00058a042
PDF
Characterization of calcium aluminate phases in cements by aluminum-27 MAS NMR spectroscopy
Joergen Skibsted, Eric Henderson, and Hans J. Jakobsen
pp 1013 - 1027; DOI:
10.1021/ic00058a043
PDF
One-step synthesis of the degradation-resistant diamine ligands H2NCR2CR2NH2 (R = Me, Et)
Paul Krajnik and Robert H. Crabtree
pp 1028 - 1029; DOI:
10.1021/ic00058a044
PDF
Carbon-13 NMR spectra of carboxylate-bridged paramagnetic dinuclear and tetranuclear iron oxo complexes
Robert H. Beer and Stephen J. Lippard
pp 1030 - 1032; DOI:
10.1021/ic00058a045
PDF
The first 1D nickel(II) complex with a single azido bridge: structure and magnetic behavior of catena-(.mu.-N3)[Ni(1,4,8,11-tetraazacyclotetradecane)](ClO4).H2O
Albert Escuer, Ramon Vicente, Joan Ribas, M. Salah El Fallah, and Xavier Solans
pp 1033 - 1035; DOI:
10.1021/ic00058a046
PDF
Photophysical and photochemical behavior of nitro complexes of ruthenium(II)
Carlo A. Bignozzi, Claudio Chiorboli, Zakir Murtaza, Wayne E. Jones, and Thomas J. Meyer
pp 1036 - 1038; DOI:
10.1021/ic00058a047
PDF
Crystal structure and study of the volatility of di-.mu.-chloro-tetrakis(trifluorophosphine)dirhodium(I)
Pascal Doppelt, Louis Ricard, and Valerie Weigel
pp 1039 - 1040; DOI:
10.1021/ic00058a048
PDF
Intensive hydrogen bonding in a monomeric magnesium salicylate tetrahydrate
Simon R. Drake, Kevin D. Sanderson, Michael B. Hursthouse, and K. M. Abdul Malik
pp 1041 - 1044; DOI:
10.1021/ic00058a049
PDF
Vibrational study of the trifluoromethanesulfonate anion: unambiguous assignment of the asymmetric stretching modes
Dean H. Johnston and Duward F. Shriver
pp 1045 - 1047; DOI:
10.1021/ic00058a050
PDF
Comparisons of solid-state and solution structures of rhodium carbonyl (R3P)2Rh(CO)Cl complexes with monodentate phosphole and phosphine ligands
Janet M. Kessler, John H. Nelson, James S. Frye, Andre DeCian, and Jean Fischer
pp 1048 - 1052; DOI:
10.1021/ic00058a051
PDF
Linkage isomerization in potassium cadmium hexacyanoferrate induced by ultrasound
J. E. House and Nicholas E. Kob
pp 1053 - 1054; DOI:
10.1021/ic00058a052
PDF
Moessbauer effect study of the influence of ligand steric interactions on the lattice dynamics and electronic structure of bis[tetra-3-isopropylpyrazol-1-ylborato]iron
Gary J. Long, Fernande Grandjean, and Swiatoslaw Trofimenko
pp 1055 - 1058; DOI:
10.1021/ic00058a053
PDF
Transition metal chemistry of Main Group hydrazides. 1. Synthesis and characterization of cyclometallaphosphohydrazides of cobalt(I), copper(I), and palladium(II). X-ray structures of cobalt(I) and palladium(II) representatives. [Erratum to document cited in CA117(24):244530y]
Kattesh V. Katti, Prahlad R. Singh, and Charles L. Barnes
pp 1058 - 1058; DOI:
10.1021/ic00058a054
PDF
pH-dependent coordination mode of new bleomycin synthetic analogs with copper(II), iron(II), and zinc(II). [Erratum to document cited in CA118(6):51167x]
Eiichi Kimura, Hiromasa Kurosaki, Yasuhisa Kurogi, Mitsuhiko Shionoya, and Motoo Shiro
pp 1058 - 1058; DOI:
10.1021/ic00058a055
PDF

Issue 7


Potassium indium zinc compound K8In10Zn: interstitially-stabilized analogs of early-transition-metal halide clusters
Slavi C. Sevov and John D. Corbett
pp 1059 - 1061; DOI:
10.1021/ic00059a001
PDF
Synthesis, structure, and alcoholysis of .eta.5-1,3-bis(trimethylsilyl)cyclopentadienyltitanium cis-1,3,5-cyclohexanetrialkoxide, an adamantane-framework complex of a polydentate alkoxide ligand
Deborah M. Choquette, Wayne E. Buschmann, Marilyn M. Olmstead, and Roy P. Planalp
pp 1062 - 1063; DOI:
10.1021/ic00059a002
PDF
Controlling the number of bridging ligands in binuclear iron thiolate complexes by modulation of ligand nucleophilicities: [Fe2(SC4H9)5]-, the first complex containing FeS4 tetrahedra connected via common faces, and [Fe2(SC3H7)]6]2-, a complex with a bitetrahedral M2S6 framework of conventional design
Gerald Henkel and Changneng Chen
pp 1064 - 1065; DOI:
10.1021/ic00059a003
PDF
A highly symmetrical octapalladium(I) compound: crystal structure of {[Pd(.mu.-SC6F5)(.mu.-dppm)Pd](.mu.-SC6F5)}4.cntdot.2O(C2H5)2
Rafael Uson, Juan Fornies, Larry R. Falvello, Miguel A. Uson, Isabel Uson, and Santiago Herrero
pp 1066 - 1067; DOI:
10.1021/ic00059a004
PDF
Oxidation resistant inorganic-porphyrin analog polyoxometalates. 3. Synthesis and x-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog KLi15[O{RuIVCl(.alpha.2-P2W17O61)}2].2KCl.60H2O
William J. Randall, Timothy J. R. Weakley, and Richard G. Finke
pp 1068 - 1071; DOI:
10.1021/ic00059a005
PDF
Photoluminescence of tellurium(IV) chloride complexes in solution
Hans Nikol and Arnd Vogler
pp 1072 - 1073; DOI:
10.1021/ic00059a006
PDF
Reaction of platinum-gold cluster compounds with dihydrogen
T. G. M. M. Kappen, J. J. Bour, P. P. J. Schlebos, A. M. Roelofsen, J. G. M. Van der Linden, J. J. Steggerda, Mark A. Aubart, Donald A. Krogstad, Marcel F. J. Schoondergang, and Louis H. Pignolet
pp 1074 - 1075; DOI:
10.1021/ic00059a007
PDF
Recognition of organotin compounds by macrocyclic polyethers: a novel pentacoordinate tin-coronand complex
Anjana Mitra, Carolyn B. Knobler, and Stephen E. Johnson
pp 1076 - 1077; DOI:
10.1021/ic00059a008
PDF
Ion pairing effects in the photochemistry of the cyclopentadienyl(.eta.6-benzene)osmium(II) cation. Synthesis and reactions of a synthetically useful intermediate: the cyclopentadienyltris(acetonitrile)osmium(II) cation
Daniel A. Freedman, John R. Matachek, and Kent R. Mann
pp 1078 - 1080; DOI:
10.1021/ic00059a009
PDF
Resonance Raman spectroscopic studies of the nitric oxide adducts of cobaltous-reconstituted myoglobin and hemoglobin
Songzhou Hu
pp 1081 - 1085; DOI:
10.1021/ic00059a010
PDF
Kinetics and intermediates in the autoxidation of synthetic, non-porphyrin iron(II) dioxygen carriers
Alexandra Sauer-Masarwa, Norman Herron, Carol M. Fendrick, and Daryle H. Busch
pp 1086 - 1094; DOI:
10.1021/ic00059a011
PDF
An electronic influence of a distant aromatic ring in reduced rubredoxin models. Iron(II) complexes with Z-Cys-Pro-Leu-Cys-Gly-X (X = NHCH2C6H4-p-F, NHCH2CH2C6H4-p-F, and Phe-OMe)
Wei Yin Sun, Norikazu Ueyama, and Akira Nakamura
pp 1095 - 1100; DOI:
10.1021/ic00059a012
PDF
Temperature-dependent proton NMR investigation of the electronic structure of the trinuclear iron cluster of the oxidized Desulfovibrio gigas ferredoxin II
Anjos L. Macedo, Isabel Moura, Jose J. G. Moura, Jean Le Gall, and Huynh Boi Hanh
pp 1101 - 1105; DOI:
10.1021/ic00059a013
PDF
Electron transfer between copper and zinc superoxide dismutase and hexacyanoferrate(II)
I. Bertini, K. Hiromi, J. Hirose, M. Sola, and M. S. Viezzoli
pp 1106 - 1110; DOI:
10.1021/ic00059a014
PDF
Structures and stabilities of ternary copper(II) complexes containing an acidic and a basic amino acid. Evidence for arginine side chain involvement in intermolecular interactions and its biological implication
Hideki Masuda, Akira Odani, Takayasu Yamazaki, Tatsuo Yajima, and Osamu Yamauchi
pp 1111 - 1118; DOI:
10.1021/ic00059a015
PDF
Synthesis, structural characterization, and metalation of N-o-tolyl-5,10,15,20-tetraphenylporphine: deformation effect due to a bulky N-substituent group
Senichi Aizawa, Yasuyuki Tsuda, Yoshio Ito, Keiichiro Hatano, and Shigenobu Funahashi
pp 1119 - 1123; DOI:
10.1021/ic00059a016
PDF
Acetylide complexes of diamagnetic gallium(III) and paramagnetic iron(III) porphyrins
Alan L. Balch, Lechoslaw Latos-Grazynski, Bruce C. Noll, and Shane L. Phillips
pp 1124 - 1129; DOI:
10.1021/ic00059a017
PDF
CP/MAS yttrium-89 NMR spectroscopy: a facile method for characterizing yttrium-containing solids
Jiejun Wu, Timothy J. Boyle, Julie L. Shreeve, Joseph W. Ziller, and William J. Evans
pp 1130 - 1134; DOI:
10.1021/ic00059a018
PDF
Synthesis and characterization of the monomeric aluminum monoamides (tert-Bu) 2AlN(R)R' (R and R' = bulky aryl, alkyl, or silyl groups)
Mark A. Petrie, Karin Ruhlandt-Senge, and Philip P. Power
pp 1135 - 1141; DOI:
10.1021/ic00059a019
PDF
Preparation, characterization, and crystal structure of the tungsten hexafluoride and tetrafluoride oxide adducts WF6.F-py and WOF4.F-py (F-py = 2-fluoropyridine)
Lucile Arnaudet, Roland Bougon, Buu Ban, Monique Lance, Martine Nierlich, and Julien Vigner
pp 1142 - 1146; DOI:
10.1021/ic00059a020
PDF
Synthesis and properties of rhodium(I) chloranilate and 2,5-dihydroxy-1,4-benzoquinonate complexes. Crystal structures of the binuclear [Rh2(.mu.-CA)(cod)2] and tetranuclear [Rh4(.mu.-CA)2(cod)4] complexes (CA = chloranilate anion)
Miguel A. Calvo, Anna Maria Manotti Lanfredi, Luis A. Oro, M. Teresa Pinillos, Cristina Tejel, Antonio Tiripicchio, and Franco Ugozzoli
pp 1147 - 1152; DOI:
10.1021/ic00059a021
PDF
Redox behavior of the black roussinate heptanitrosyltrisulfotetraferrate(1-) monoanion. Synthesis and spectroscopic characterization of the [Fe4S3(NO)7]n- (n = 2, 3) anions and crystal structures of the mono- and dianions in their [NEt4]+ salts
Sabatino D'Addario, Francesco Demartin, Loris Grossi, Maria Carmela Iapalucci, Franco Laschi, Giuliano Longoni, and Piero Zanello
pp 1153 - 1160; DOI:
10.1021/ic00059a022
PDF
Alkoxymagnesium halide supports for heterogeneous Ziegler-Natta polymerization catalysts
Gregory M. Smith, Charles F. Tirendi, Richard J. Amata, and Elliot I. Band
pp 1161 - 1166; DOI:
10.1021/ic00059a023
PDF
Photochemical electron transfer in chromophore-quencher complexes of ruthenium(II) based on tris(1-pyrazolyl)methane
Wayne E. Jones, Carlo A. Bignozzi, Pingyun Chen, and Thomas J. Meyer
pp 1167 - 1178; DOI:
10.1021/ic00059a024
PDF
Mono- and dinuclear complexes of ruthenium(II) and osmium(II) with a 3,5-bis(2-pyridyl)-1,2,4-triazole cyclohexyl-bridged spacer. Absorption spectra, luminescence properties, and electrochemical behavior
Gaetano Giuffrida, Giuseppe Calogero, Giovanni Guglielmo, Vittorio Ricevuto, Mauro Ciano, and Sebastiano Campagna
pp 1179 - 1183; DOI:
10.1021/ic00059a025
PDF
Kinetics of ternary complex formation with the (nitrilotriacetato)copper(II) complex
Istvan Fabian
pp 1184 - 1190; DOI:
10.1021/ic00059a026
PDF
Effects of hydrogen bonding in electron-transfer reactions of tris(ethylenediamine)cobalt(2+)
Robert M. L. Warren, Akira Tatehata, and A. Graham Lappin
pp 1191 - 1196; DOI:
10.1021/ic00059a027
PDF
Ferrocene-containing chelating ligands. 1. Solution study, synthesis, crystal structure, and electronic properties of bis{N,N'-ethylenebis((ferrocenylmethyl)amine)}copper(II) nitrate
Angel Benito, Juan Cano, Ramon Martinez-Manez, Juan Soto, Jorge Paya, Francesc Lloret, Miguel Julve, Juan Faus, and M. Dolores Marcos
pp 1197 - 1203; DOI:
10.1021/ic00059a028
PDF
Thermodynamic and structural properties of palladium(II) polynuclear complexes of azamacrocycles. Crystal structure of the [Pd2([24]aneN8)] (ClO4)4 complex
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Enrique Garcia-Espana, Piero Paoletti, Paola Paoli, Jose Antonio Ramirez, and Agustin Rodriguez
pp 1204 - 1208; DOI:
10.1021/ic00059a029
PDF
Anion-exchange reactions of hydroxy double salts
Martina Meyn, Klaus Beneke, and Gerhard Lagaly
pp 1209 - 1215; DOI:
10.1021/ic00059a030
PDF
ESR characterization of trans-diacidatotetrakis(pyridine)vanadium and -manganese trans-VII(py)4X2 and trans-MnII(py)4X2 (X = NCS, Cl, Br, I; py = pyridine)
Claus J. H. Jacobsen, Erik Pedersen, Joergen Villadsen, and Hoegni Weihe
pp 1216 - 1221; DOI:
10.1021/ic00059a031
PDF
Fast atom bombardment mass spectrometry of multiply charged polynuclear rhenium(I)-ruthenium(II) complexes
R. Argazzi, C. A. Bignozzi, O. Bortolini, and P. Traldi
pp 1222 - 1225; DOI:
10.1021/ic00059a032
PDF
Optical activity in tris bidentate cobalt(III) complexes. An ab initio study
M. C. Ernst and D. J. Royer
pp 1226 - 1232; DOI:
10.1021/ic00059a033
PDF
Correlation of x-ray crystallographic data and spectroscopic properties of divalent metal complexes of octaethylporphyrin
K. D. Stanley, L. Luo, R. Lopez de la Vega, and J. M. E. Quirke
pp 1233 - 1236; DOI:
10.1021/ic00059a034
PDF
Dinuclear europium(3+), terbium(3+) and gadolinium(3+) complexes of a branched hexaazacyclooctadecane ligand containing six 2,2'-bipyridine pendant units
Raymond Ziessel, Mauro Maestri, Luca Prodi, Vincenzo Balzani, and Alain Van Dorsselaer
pp 1237 - 1241; DOI:
10.1021/ic00059a035
PDF
Organization of water around a beryllium cation
Charles W. Bock and Jenny P. Glusker
pp 1242 - 1250; DOI:
10.1021/ic00059a036
PDF
Electronic structure and spectroscopy of nickel(II), palladium(II), and platinum(II) acetylacetonate complexes
Frederick D. Lewis, Gwen D. Salvi, David R. Kanis, and Mark A. Ratner
pp 1251 - 1258; DOI:
10.1021/ic00059a037
PDF
Structure and conformation of photosynthetic pigments and related compounds. 5. Structural investigation of nickel(II) bacteriopetroporphyrins related to the bacteriochlorophylls c and d: evidence for localized conformational distortion in the c-series
Mathias O. Senge, Norman W. Smith, and Kevin M. Smith
pp 1259 - 1265; DOI:
10.1021/ic00059a038
PDF
Synthesis, structure, and fluxional behavior of octahedral ruthenium(II) complexes with mixed oxygen-phosphine ligands. Phosphorus-31 DNMR spectroscopic studies, line shape analysis, and determination of rearrangement barriers
Ekkehard Lindner, Andrea Moeckel, Hermann August Mayer, Hartwig Kuehbauch, Riad Fawzi, and Manfred Steimann
pp 1266 - 1271; DOI:
10.1021/ic00059a039
PDF
Primary steps in the hydrolyses of two heterometallic alkoxides. Characterization of lithium-titanium and barium-zirconium isopropoxides [LiTiO(O-iso-Pr)3]4 and BaZr4(OH)(O-iso-Pr)17
Roger Kuhlman, Brian A. Vaartstra, William E. Streib, John C. Huffman, and Kenneth G. Caulton
pp 1272 - 1278; DOI:
10.1021/ic00059a040
PDF
Carbon dioxide coordination chemistry. 3. Vibrational, NMR, theoretical studies of (carbon dioxide)bis(tricyclohexylphosphine)nickel
Corine Jegat, Monique Fouassier, Michel Tranquille, Joelle Mascetti, Immacolata Tommasi, Michele Aresta, Florent Ingold, and Alain Dedieu
pp 1279 - 1289; DOI:
10.1021/ic00059a041
PDF
New titanatranes and an unexpected reactivity trend in (dialkylamido)titanatranes
A. A. Naiini, S. L. Ringrose, Y. Su, R. A. Jacobson, and J. G. Verkade
pp 1290 - 1296; DOI:
10.1021/ic00059a042
PDF
Coordination chemistry of the tetrathiacyclophane ligand 2,5,14,17-tetrathia[6.6]-o-cyclophane, TT[6.6]OC. Synthesis and structures of TT[6.6]OC and [Pt(TT[6.6]OC)] [BF4]2
Stephen J. Loeb and Karen D. L. Smith
pp 1297 - 1300; DOI:
10.1021/ic00059a043
PDF
Isolation and x-ray crystal structure of a dimeric molybdenum(V) oxo complex containing a bis(3,5-dimethylpyrazolyl)methane ligand: an unusual case of dioxygen activation
Vijaya S. Joshi, Malay Nandi, Hongming Zhang, Brian S. Haggerty, and Amitabha Sarkar
pp 1301 - 1303; DOI:
10.1021/ic00059a044
PDF
Magnetic resonance spectral characterization of tetrathiotungstate adducts with iron(III) porphyrins
Yunghee Oh Kim, Byungho Song, and Harold M. Goff
pp 1304 - 1305; DOI:
10.1021/ic00059a045
PDF
Reversible complexation of dioxygen to (meso-tetraphenylporphyrinato)cobalt(II) plasma polymer and sublimed films at room temperature
J. M. Skelly, N. C. Morosoff, V. T. Stannett, and A. L. Crumbliss
pp 1306 - 1308; DOI:
10.1021/ic00059a046
PDF

Issue 8


Synthesis and characterization of the monomeric digallylphosphine and digallylarsine derivatives MesP{Ga(Trip)2}2.cntdot.Et2O and PhAs{Ga(Trip)2}2
Mark A. Petrie and Philip P. Power
pp 1309 - 1312; DOI:
10.1021/ic00060a001
PDF
The ortho effect in ligation of iron tetraphenylporphyrins
Carmita F. Portela, Douglas Magde, and Teddy G. Traylor
pp 1313 - 1320; DOI:
10.1021/ic00060a002
PDF
A compound with a new type of butterfly metal atom cluster: bis(tetrabutylammonium) dodecabromooxotetramolybdate(2-)
F. Albert Cotton, Xuejun Feng, Maoyu Shang, and Zhong Sheng Sun
pp 1321 - 1326; DOI:
10.1021/ic00060a003
PDF
A new route to binuclear and trinuclear ruthenium carbonyl derivatives; structures of [Ru3(CO)6(.mu.-Ph2PCH2PPh2)3] and its proton adduct
Hameed A. Mirza, Jagadese J. Vittal, and Richard J. Puddephatt
pp 1327 - 1332; DOI:
10.1021/ic00060a004
PDF
Ring-opening reactions of the anticancer drug carboplatin: NMR characterization of cis-[Pt(NH3)2(CBDCA-O)(5'-GMP-N7)] in solution
Urban Frey, John D. Ranford, and Peter J. Sadler
pp 1333 - 1340; DOI:
10.1021/ic00060a005
PDF
Reactions of the electron-rich triply bonded dirhenium(II) complexes Re2X4(.mu.-dppm)2 (X = Cl, Br) with dioxygen. 1. Multielectron redox chemistry with preservation of the Re2X4(dppm)2 unit
Stuart L. Bartley, Kim R. Dunbar, Keng Yu Shih, Phillip E. Fanwick, and Richard A. Walton
pp 1341 - 1349; DOI:
10.1021/ic00060a006
PDF
Polyselenide chemistry of indium and thallium in dimethylformamide, acetonitrile, and water. Syntheses, structures, and properties of the new complexes [In2(Se4)2(Se5)]4-, [In2Se2(Se4)2]2-, and [In3Se3(Se4)3]3-
Sandeep S. Dhingra and Mercouri G. Kanatzidis
pp 1350 - 1362; DOI:
10.1021/ic00060a007
PDF
Framework expansion versus edge opening in a 50-electron phosphido-bridged triruthenium cluster. A case study
Noel Lugan, Paul Louis Fabre, Dominique de Montauzon, Guy Lavigne, Jean Jacques Bonnet, Jean Yves Saillard, and Jean Francois Halet
pp 1363 - 1369; DOI:
10.1021/ic00060a008
PDF
Tungsten(VI) hexahydride complexes supported by chelating triphosphine ligands: protonation to give .eta.2-dihydrogen complexes and catalytic dehydrogenation of cyclooctane to cyclooctene
Demetrius Michos, Xiao Liang Luo, J. W. Faller, and Robert H. Crabtree
pp 1370 - 1375; DOI:
10.1021/ic00060a009
PDF
Control of intramolecular electron transfer by protonation: oligomers of ruthenium porphyrins bridged by 4,4'-azopyridine
Valerie Marvaud and Jean Pierre Launay
pp 1376 - 1382; DOI:
10.1021/ic00060a010
PDF
Experimental investigation of the electronic structures of enneacarbonylbis(.mu.3-X-methylidyne)triiron complexes (X = H, F, Cl, Br) by means of He I/He II gas-phase UV photoelectron spectroscopy
M. Casarin, A. Gulino, D. Lentz, H. Michael-Schulz, and A. Vittadini
pp 1383 - 1388; DOI:
10.1021/ic00060a011
PDF
Synthesis, characterization, and reactivity of catecholato adducts of iron(III) triaza- and tetraazamacrocyclic complexes: chemical evidence of the role of the metal ion in the oxidative cleavage
Andrea Dei, Dante Gatteschi, and Luca Pardi
pp 1389 - 1395; DOI:
10.1021/ic00060a012
PDF
Comparison of copper(II) complexes containing various saturated 12-membered macrocycles
Robin L. Webb, Marion L. Mino, Elliott L. Blinn, and A. Alan Pinkerton
pp 1396 - 1402; DOI:
10.1021/ic00060a013
PDF
pH-dependent properties of SOD studied through mutants on Lys-136
Lucia Banci, Ivano Bertini, Claudio Luchinat, and Maria Silvia Viezzoli
pp 1403 - 1406; DOI:
10.1021/ic00060a014
PDF
Artificial allosteric ionophore: regulation of ion recognition of polyethers bearing bipyridine moieties by copper(I)
Tatsuya Nabeshima, Tadashi Inaba, Naomichi Furukawa, Toshiyuki Hosoya, and Yumihiko Yano
pp 1407 - 1416; DOI:
10.1021/ic00060a015
PDF
Synthesis and electrochemistry of (.mu.-oxo)technetium complexes with bipyridine and halide ligands. Crystal structures of (.mu.-O)[X(bpy)2Tc]2X2.cntdot.bpy ( X = Cl, Br) and (.mu.-O)[Cl(phen)2Tc]2Cl2
Jun Lu, M. J. Clarke, and C. D. Hiller
pp 1417 - 1423; DOI:
10.1021/ic00060a016
PDF
Syntheses of chromium and copper complexes of hexaazamacrocycles. Crystal structures of chromium(III) complexes of 1,4,7,10,13,16-hexaazacyclooctadecane and 1,4,7,11,14,17-hexaazacycloeicosane
S. Chandrasekhar, D. G. Fortier, and A. McAuley
pp 1424 - 1429; DOI:
10.1021/ic00060a017
PDF
Synthesis, characterization, and molecular structure of (.eta.5-cyclopentadienyl)(.eta.4-2,4-cyclopentadien-1-one)ruthenium(II) complexes
Karl Kirchner, Henry Taube, Brian Scot, and Roger D. Willett
pp 1430 - 1434; DOI:
10.1021/ic00060a018
PDF
Reactions of unsaturated nickel-tungsten and nickel-molybdenum complexes with organic disulfides. Synthetic and structural studies
Aaron F. Bartlone, Michael J. Chetcuti, Phillip E. Fanwick, and Kenneth J. Haller
pp 1435 - 1441; DOI:
10.1021/ic00060a019
PDF
Lanthanide tetramethoxyborate complexes isolated from reductive amination of 2,6-diformyl-p-cresol
Karen D. Matthews, Ishenkumba A. Kahwa, Marie P. Johnson, Joel T. Mague, and Gary L. McPherson
pp 1442 - 1444; DOI:
10.1021/ic00060a020
PDF
Crystal structure and magnetic properties of two nitronyl nitroxide biradicals and of their copper(II) complexes
A. Caneschi, P. Chiesi, L. David, F. Ferraro, D. Gatteschi, and R. Sessoli
pp 1445 - 1453; DOI:
10.1021/ic00060a021
PDF
Chemical gating of a molecular bilayer rectifier at clay-modified electrodes
Daiting Rong and Thomas E. Mallouk
pp 1454 - 1459; DOI:
10.1021/ic00060a022
PDF
Imidazole- and alkylamine-ligated iron(II,III) chlorin complexes as models for histidine and lysine coordination to iron in dihydroporphyrin-containing proteins: characterization with magnetic circular dichroism spectroscopy
Ann M. Huff, Chi K. Chang, David K. Cooper, Kevin M. Smith, and John H. Dawson
pp 1460 - 1466; DOI:
10.1021/ic00060a023
PDF
Chiral siderophore analogs: ferrichrome
Izac Dayan, Jacqueline Libman, Yael Agi, and Abraham Shanzer
pp 1467 - 1475; DOI:
10.1021/ic00060a024
PDF
Dimensional diversity in transition metal trihalides
Jianhua Lin and Gordon J. Miller
pp 1476 - 1487; DOI:
10.1021/ic00060a025
PDF
Oxidation of a macrocyclic nickel(II) complex by alkyl hydroperoxides
Qin Yao, Andreja Bakac, and James H. Espenson
pp 1488 - 1492; DOI:
10.1021/ic00060a026
PDF
Multiple-state emission and excited-state dynamics of CpRe(CO)2L (L = 3-benzoylpyridine and 4-benzoylpyridine) complexes in fluid and glassy solutions
Zhikai Wang and Alistair J. Lees
pp 1493 - 1501; DOI:
10.1021/ic00060a027
PDF
Crystal structure and vibrational spectra of guanidinium hexakis(propionato)trifluoro(.mu.3-oxo)trichromate(2-)
Christopher E. Anson, Nittayaporn Chai-Sa'ard, John P. Bourke, Roderick D. Cannon, Upali A. Jayasooriya, and Anne K. Powell
pp 1502 - 1507; DOI:
10.1021/ic00060a028
PDF
Comparative study on crystal structures of ruthenium bipyridine carbonyl complexes [Ru(bpy)2(CO)2](PF6)2, [Ru(bpy)2(CO)(C(O)OCH3)]B(C6H5)4.cntdot.CH3CN, and [Ru(bpy)2(CO)(.eta.1-CO2)].cntdot.3H2O (bpy = 2,2'-bipyridyl)
Hiroaki Tanaka, Biing Chiau Tzeng, Hirotaka Nagao, Shie Ming Peng, and Koji Tanaka
pp 1508 - 1512; DOI:
10.1021/ic00060a029
PDF
(Fluoroalkyl)phosphine complexes of rhodium and iridium. Synthesis and reactivity properties of [(dfepe)Ir(.mu.-Cl)]2
R. Chris Schnabel and Dean M. Roddick
pp 1513 - 1518; DOI:
10.1021/ic00060a030
PDF
A simple, efficient synthesis of tetraselenium tetranitride
Jari Siivari, Tristram Chivers, and Risto S. Laitinen
pp 1519 - 1520; DOI:
10.1021/ic00060a031
PDF
MO explanation of the "unexpected" structure of (.eta.5-C5Me5)2Ta(:NC6H5)H
Karl Anker Joergensen
pp 1521 - 1522; DOI:
10.1021/ic00060a032
PDF
Preparation of 1-fluoro-2,4,6-trihalogeno-s-triazinium hexafluoroarsenates: structure of [C3N3Cl3F][AsF6] as deduced by experimental and ab initio methods
Paul v. R. Schleyer, Peter Buzek, Thomas M. Klapoetke, Inis C. Tornieporth-Oetting, Matthias Broschag, and Joachim Pickardt
pp 1523 - 1524; DOI:
10.1021/ic00060a033
PDF
Valence photoelectron spectrum of osmium tetroxide: evidence for 5p semicore effects?
Pekka Pyykko, Jian Li, T. Bastug, B. Fricke, and D. Kolb
pp 1525 - 1526; DOI:
10.1021/ic00060a034
PDF
A diphosphaferrocene as a chelating ligand for silver(I)
David A. Atwood, Alan H. Cowley, and Sean M. Dennis
pp 1527 - 1528; DOI:
10.1021/ic00060a035
PDF
Synthesis and structure of the unligated carbene of chromium
W. E. Billups, Sou Chan Chang, Robert H. Hauge, and John L. Margrave
pp 1529 - 1531; DOI:
10.1021/ic00060a036
PDF
Kinetics of coordinated-base-catalyzed and free-base-catalyzed configurational conversions of a tetraamine macrocyclic ligand complex of copper(II). [Erratum to document cited in CA100(14):109750d]
Chung Shin Lee and Chung Sun Chung
pp 1532 - 1532; DOI:
10.1021/ic00060a037
PDF
Kinetics of the formation and dissociation of nickel(II) complexes of diamino diamides. [Erratum to document cited in CA103(6):43426f]
Si Han Liu and Chung Sun Chung
pp 1532 - 1532; DOI:
10.1021/ic00060a038
PDF
Steric, inductive, and ring-strain effects in chelation thermodynamics and kinetics: reactions of copper(II) ion with N-alkyl-substituted diamino diamides. [Erratum to document cited in CA110(10):82967x]
Min Shiun Chao and Chung Sun Chung
pp 1532 - 1532; DOI:
10.1021/ic00060a039
PDF
Complexation kinetics of diamino diamides with copper(II) in aqueous solution. [Erratum to document cited in CA105(20):179135j]
Si Han Liu and Chung Sun Chung
pp 1532 - 1532; DOI:
10.1021/ic00060a040
PDF

Issue 9


Oxidative decoupling of the molybdenum-iron-sulfur MoFe3S4 clusters and possible relevance to the oxidative degradation of the nitrogenase cofactor. Isolation and structural characterization of the [(Cl4cat)Mo(O)(.mu.-S)2FeCl2]2- anion
D. Coucouvanis, Saleem Al-Ahmad, C. G. Kim, P. E. Mosier, and J. W. Kampf
pp 1533 - 1535; DOI:
10.1021/ic00061a001
PDF
fac-Bis(triphenylphosphine)nitrogen(+) tricarbonyltris(benzenetellurolato)ferrate: oxidative addition of (PhTe)2 to [PPN][PhTeFe(CO)4]
Wen Feng Liaw, Ming Hsi Chiang, Chen Ju Liu, Piin Jye Harn, and Lin Kang Liu
pp 1536 - 1538; DOI:
10.1021/ic00061a002
PDF
Synthesis of heterobimetallic allene complexes
Iuan Yuan Wu, Tian Wen Tseng, Chun Ting Chen, Ming Chu Cheng, Ying Chih Lin, and Yu Wang
pp 1539 - 1540; DOI:
10.1021/ic00061a003
PDF
A carbene germanium diiodide adduct: model of the non-least-motion pathway for dimerization of singlet carbenes
Anthony J. Arduengo, H. V. Rasika Dias, Joseph C. Calabrese, and Fredric Davidson
pp 1541 - 1542; DOI:
10.1021/ic00061a004
PDF
Magnetochemistry of tetrahaloferrate(III) ions. 5. Specific heats of and magnetic ordering in [4-Cl(py)H]3Fe2Br9, [4-Br(py)H]3Fe2Br9, and [4-Cl(py)H]1.1[4-Br(py)H]1.9Fe2Br9
Roey Shaviv, Carol B. Lowe, and Richard L. Carlin
pp 1543 - 1547; DOI:
10.1021/ic00061a005
PDF
A molecular mechanics model of ligand effects. 4. Binding of amines to chromium pentacarbonyl: ER values for amines
Moon Gun Choi and Theodore L. Brown
pp 1548 - 1553; DOI:
10.1021/ic00061a006
PDF
Preparation and solid state-structure of a 1,3,5-triazine-bridged tris(1,2,3,5-dithiadiazolyl) complex [N3C3(CN2S2)3]
A. W. Cordes, R. C. Haddon, R. G. Hicks, D. K. Kennepohl, R. T. Oakley, L. F. Schneemeyer, and J. V. Waszczak
pp 1554 - 1558; DOI:
10.1021/ic00061a007
PDF
Complex formation of pyrosulfate melts. 4. Density, potentiometry, calorimetry, and conductivity of the systems cesium pyrosulfate-vanadium pentoxide, Cs2S2O7-cesium sulfate and Cs2S2O7-Cs2SO4-V2O5 in the temperature range 340-550.degree.C
G. E. Folkmann, G. Hatem, R. Fehrmann, M. Gaune-Escard, and N. J. Bjerrum
pp 1559 - 1565; DOI:
10.1021/ic00061a008
PDF
Two families of centered zirconium cluster phases with M1,2M'Cl6.Zr6Cl12Z compositions
Jie Zhang and John D. Corbett
pp 1566 - 1572; DOI:
10.1021/ic00061a009
PDF
Rigid nonlabile polyoxometalate cryptates [ZP5W30O110](15-n)- that exhibit unprecedented selectivity for certain lanthanide and other multivalent cations
Inge Creaser, Mark C. Heckel, R. Jeffrey Neitz, and Michael T. Pope
pp 1573 - 1578; DOI:
10.1021/ic00061a010
PDF
Hydrothermal synthesis, structure, and sorption properties of the new microporous ferric molybdenum phosphates [(CH3)4N]2(NH4)2[Fe2Mo12O30(H2PO4)6(HPO4)2].nH2O and [(CH3)4N]2Na4[Fe3Mo12O30(HxPO4)8].nH2O
Linda A. Meyer and Robert C. Haushalter
pp 1579 - 1586; DOI:
10.1021/ic00061a011
PDF
Bis(2,2'-bipyridine)ruthenium(2+) and -osmium(2+) complexes of large polyaza cavity-shaped ligands
Randolph P. Thummel, Darwin Williamson, and Christophe Hery
pp 1587 - 1596; DOI:
10.1021/ic00061a012
PDF
Synthetic and structural studies of a new nickel-antimony alkoxide: Ni6Sb4O4(OEt)16(HOEt)4
U. Bemm, R. Norrestam, M. Nygren, and G. Westin
pp 1597 - 1600; DOI:
10.1021/ic00061a013
PDF
Intramolecular redox and methyl for chloride exchange processes at platinum(II) metal centers bridged by the short bite ligand 2-(diphenylphosphino)pyridine
Carmela Grazia Arena, Giuseppe Bruno, Giovanni De Munno, Enrico Rotondo, Dario Drommi, and Felice Faraone
pp 1601 - 1606; DOI:
10.1021/ic00061a014
PDF
Complex polymeric cations of copper(I) with graphite- and diamond-related lattices; crystal structures of poly-tris(.mu.-2,5-dimethylpyrazine)dicopper(I) hexafluorophosphate and poly-bis(.mu.-2,5-dimethylpyrazine)copper(I) hexafluorophosphate
Tom Otieno, Steven J. Rettig, Robert C. Thompson, and James Trotter
pp 1607 - 1611; DOI:
10.1021/ic00061a015
PDF
Synthesis, characterization, and bonding of indium clusters: A3Na26In48 (A = K, Rb, Cs) with a novel cubic network of arachno- and closo-In12 clusters
Slavi C. Sevov and John D. Corbett
pp 1612 - 1615; DOI:
10.1021/ic00061a016
PDF
Structure, spectroscopic and magnetic properties of rare earth metal(III) derivatives with the 2-formyl-4-methyl-6-(N-(2-pyridylethyl)formimidoyl)phenol ligand
Marius Andruh, Evangelos Bakalbassis, Olivier Kahn, Jean Christian Trombe, and Pierre Porcher
pp 1616 - 1622; DOI:
10.1021/ic00061a017
PDF
Oxophily of gadolinium(III), and synthesis of dissymmetric di(Schiff bases) and dissymmetric dinuclear compounds. Crystal structure of [Cu2L'(OH)](ClO4)2.cntdot.H2O with L' = 2-[N-(2-pyridylethyl)formimidoyl]-6-[N-((dimethylamino)propyl)formimidoyl]phenolato
Marius Andruh, Olivier Kahn, Joelle Sainton, Yves Dromzee, and Suzanne Jeannin
pp 1623 - 1628; DOI:
10.1021/ic00061a018
PDF
Synthesis and characterization of ruthenium complexes containing tridentate P3O93-, Nb2W4O194-, and Cp*TiW5O183- ligands
V. W. Day, T. A. Eberspacher, W. G. Klemperer, R. P. Planalp, P. W. Schiller, A. Yagasaki, and B. Zhong
pp 1629 - 1637; DOI:
10.1021/ic00061a019
PDF
dppm-Assisted synthesis and reactivity of bimetallic M-molybdenum, M-tungsten, M-cobalt, and M-manganese (M = platinum, palladium) complexes. Crystal structure of [cyclic] [(.eta.2-dppm)Pt(.mu.-dppm)W(CO)2CpPt,W][PF6].cntdot.CH2Cl2 (dppm = bis(diphenylphosphino)methane)
Pierre Braunstein, Claude de Meric de Bellefon, Benoit Oswald, Michel Ries, Maurizio Lanfranchi, and Antonio Tiripicchio
pp 1638 - 1648; DOI:
10.1021/ic00061a020
PDF
Carbonylmetalate-induced phosphorus migration and bis(diphenylphosphino)methane (dppm-) assisted synthesis of bimetallic complexes and clusters of palladium and platinum with molybdenum, tungsten, manganese and cobalt
Pierre Braunstein, Claude de Meric de Bellefon, and Benoit Oswald
pp 1649 - 1655; DOI:
10.1021/ic00061a021
PDF
Transition-metal silyl complexes. 46. Reaction of anionic silyl complexes [Fe(CO)3(SiR3)(PR'3)]- with CdX2 (X = Cl, Br) to probe the influence of the phosphines PR'3, and X on nuclearity and geometry of the resulting polynuclear complexes
Georg Reinhard, Brigitte Hirle, Ulrich Schubert, Michael Knorr, Pierre Braunstein, Andre DeCian, and Jean Fischer
pp 1656 - 1661; DOI:
10.1021/ic00061a022
PDF
Mixed transition metal-main group atom clusters as potential models for M2X (010) and M4 (100) surfaces. Synthesis and spectroscopic and structural characterization of M4(CO)13(.mu.3-PPh) (M = ruthenium, osmium). Pyramidal clusters with M3P square faces
Andrew A. Cherkas, John F. Corrigan, Simon Doherty, Shane A. MacLaughlin, Francoise van Gastel, Nicholas J. Taylor, and Arthur J. Carty
pp 1662 - 1670; DOI:
10.1021/ic00061a023
PDF
Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM'(CO)3(Ph2PCH2PPh2)2] (M, M' = rhodium, iridium)
Robert McDonald and Martin Cowie
pp 1671 - 1680; DOI:
10.1021/ic00061a024
PDF
Oxidative addition of oxygen-hydrogen bonds to iridium(I): synthesis and characterization of (phenolato)- and (carboxylato)iridium(III) hydride complexes
Folami T. Ladipo, Mahimid Kooti, and Joseph S. Merola
pp 1681 - 1688; DOI:
10.1021/ic00061a025
PDF
Synthesis and reactivity of binaphtholate complexes of a d3-d3 ditungsten template
Steven D. Dietz, Nancy W. Eilerts, Joseph A. Heppert, and David Vander Velde
pp 1689 - 1697; DOI:
10.1021/ic00061a026
PDF
Binaphtholate and binaphtholate chloride complexes of tungsten(VI)
Steven D. Dietz, Nancy W. Eilerts, Joseph A. Heppert, and Martha D. Morton
pp 1698 - 1705; DOI:
10.1021/ic00061a027
PDF
Reactions of hydrazido(2-) and dinitrogen complexes of molybdenum with reducing agents. Crystal structure of a molybdenum(V) hydrazido(2-) complex: [MoBr3(NNH2)(Ph2PCH2CH2PPh2)].cntdot.THF
T. Adrian George, Bharat B. Kaul, Qin Chen, and Jon Zubieta
pp 1706 - 1711; DOI:
10.1021/ic00061a028
PDF
A combined NMR/IGLO/Ab initio study of the carborane anion C2B10H13(=) isomers
Michael L. McKee, Michael Buehl, and Paul v. R. Schleyer
pp 1712 - 1715; DOI:
10.1021/ic00061a029
PDF
A planar dodecasubstituted porphyrin
Mathias O. Senge, Craig J. Medforth, Laurie D. Sparks, John A. Shelnutt, and Kevin M. Smith
pp 1716 - 1723; DOI:
10.1021/ic00061a030
PDF
Synthesis and structural characterization of the beryllium compounds [Be(2,4,6-Me3C6H2)2(OEt2)], [Be{O(2,4,6-tert-Bu3C6H2)}2(OEt2)], and [Be{S(2,4,6-tert-Bu3C6H2)}2(THF)].cntdot.PhMe and determination of the structure of [BeCl2(OEt2)2]
Karin Ruhlandt-Senge, Ruth A. Bartlett, Marilyn M. Olmstead, and Philip P. Power
pp 1724 - 1728; DOI:
10.1021/ic00061a031
PDF
Ligands for oxovanadium(IV): bis(catecholamide) coordination and intermolecular hydrogen bonding to the oxo atom
Torin M. Dewey, Justin Du Bois, and Kenneth N. Raymond
pp 1729 - 1738; DOI:
10.1021/ic00061a032
PDF
Reactions of copper(I) aryloxides with phenyl isothiocyanate: steric and ligand control in the oligomerization of [N-phenylimino(aryloxy)methanethiolato]copper(I) complexes
Santosh P. Abraham, N. Narasimhamurthy, M. Nethaji, and Ashoka G. Samuelson
pp 1739 - 1745; DOI:
10.1021/ic00061a033
PDF
Coinage-metal tellurides: synthesis and structural characterization of the [(Te4)M(.mu.-Te4)M(Te4)]4- anions (M = copper, silver)
Mohammad A. Ansari, John C. Bollinger, and James A. Ibers
pp 1746 - 1748; DOI:
10.1021/ic00061a034
PDF
Synthesis and characterization of dinuclear gold(I) ring and open-ring complexes containing saturated and unsaturated dithiol bridging ligands and phosphine or bis(diphosphine) donor ligands. Crystal structures of [Au2(.mu.-S(CH2)3S) (.mu.-dppm)], [Au2(.mu.-MNT)(PPh3)2], [Au2(.mu.-S2C6H4) (PPh3)2], and [Au4(.mu.-S2C6H3CH3)2(PEt3)2]
Rosa M. Davila, Anabel Elduque, Tiffany Grant, Richard J. Staples, and John P. Fackler
pp 1749 - 1755; DOI:
10.1021/ic00061a035
PDF
Highly flexible chelating ligands for Group 13 metals: design and synthesis of hexadentate (N3O3) tripodal amine phenol ligand complexes of aluminum, gallium, and indium
Shuang Liu, Ernest Wong, Veranja Karunaratne, Steven J. Rettig, and Chris Orvig
pp 1756 - 1765; DOI:
10.1021/ic00061a036
PDF
Synthesis and characterization of thorium tert-butoxide complexes: x-ray crystal structures of Th(O-tert-Bu)4(py)2 and NaTh2(O-tert-Bu)9
David L. Clark and John G. Watkin
pp 1766 - 1772; DOI:
10.1021/ic00061a037
PDF
Diiron and dicobalt complexes of a phenolate-bridged binucleating ligand with mixed phenolate and pyridine podands
V. D. Campbell, E. J. Parsons, and W. T. Pennington
pp 1773 - 1778; DOI:
10.1021/ic00061a038
PDF
Chiral siderophore analogs: ferrioxamines and their iron(III) coordination properties
Pnina Yakirevitch, Natacha Rochel, Anne Marie Albrecht-Gary, Jacqueline Libman, and Abraham Shanzer
pp 1779 - 1787; DOI:
10.1021/ic00061a039
PDF
Chemistry of a cofacial dirhodium diporphyrin: synthesis and reactivity of Rh2DPB
James P. Collman, Yunkyoung Ha, Roger Guilard, and Michel Angel Lopez
pp 1788 - 1794; DOI:
10.1021/ic00061a040
PDF
Characterization of platinum(II)-phosphato complexes of uridine nucleotides
Rathindra N. Bose, Lori L. Slavin, Jeff W. Cameron, Donna L. Luellen, and Ronald E. Viola
pp 1795 - 1802; DOI:
10.1021/ic00061a041
PDF
Synthesis and spectroscopic properties of symmetrically tetrasubstituted phthalocyanines with four alkyl or aryl chains or porphyrin, adamantane, crown, or quinone units attached
Nagao Kobayashi, Toshie Ohya, Mitsuo Sato, and Shinichiro Nakajima
pp 1803 - 1808; DOI:
10.1021/ic00061a042
PDF
Vibrational and electronic contributions to entropy changes for oxidation-reduction reactions of metal complexes
David E. Richardson and Paul Sharpe
pp 1809 - 1812; DOI:
10.1021/ic00061a043
PDF
ENDOR and ESEEM investigation of AgI2CuII2 bovine superoxide dismutase
Ryszard J. Gurbiel, Risa Peoples, Peter E. Doan, John F. Cline, John McCracken, Jack Peisach, Brian M. Hoffman, and Joan Selverstone Valentine
pp 1813 - 1819; DOI:
10.1021/ic00061a044
PDF
Kinetics of the complexation of dioxouranium(VI) with selected diphosphonic acids in acidic solutions
Margaret A. Hines, James C. Sullivan, and K. L. Nash
pp 1820 - 1823; DOI:
10.1021/ic00061a045
PDF
Inclusion of (N-adamantan-1'-ylpyrazinium)pentacyanoferrate(II) ion in .alpha.- and .beta.-cyclodextrins. Effects of inclusion on the spectroscopic properties and ligand substitution kinetics
Megan E. Shortreed, R. Stephen Wylie, and Donal H. Macartney
pp 1824 - 1829; DOI:
10.1021/ic00061a046
PDF
Effects of cyclodextrin inclusion on the kinetics of the ligand substitution reactions of aquapentacyanoferrate(II) and pentacyano(N-heterocycle)ferrate(II) complexes in aqueous media
R. Stephen Wylie and Donal H. Macartney
pp 1830 - 1837; DOI:
10.1021/ic00061a047
PDF
New insights into the electrochemistry of molybdenum(VI) dioxo complexes containing a tetradentate S2(NH)2-type ligand
Ulrich Kuesthardt, Rolf W. Albach, and Paul Kiprof
pp 1838 - 1843; DOI:
10.1021/ic00061a048
PDF
Binding of L-histidine to vanadium. Structure of exo-[VO2{N-(2-oxidonaphthal)-His}]
Vassilios Vergopoulos, Wolfgang Priebsch, Martina Fritzsche, and Dieter Rehder
pp 1844 - 1849; DOI:
10.1021/ic00061a049
PDF
Relative energies and strain energies of proposed structures for octaphosphorus
Benjamin M. Gimarc and D. Scott Warren
pp 1850 - 1856; DOI:
10.1021/ic00061a050
PDF
Ab initio comparison of the bonding modes of nitrate and bicarbonate in model carbonic anhydrase systems
P. N. V. Pavan Kumar and Dennis S. Marynick
pp 1857 - 1859; DOI:
10.1021/ic00061a051
PDF
Nickel-promoted reductive carbon-sulfur bond cleavage: a model for the first step in the reaction promoted by methyl coenzyme M reductase
Mikyung Cha, Steven C. Shoner, and Julie A. Kovacs
pp 1860 - 1863; DOI:
10.1021/ic00061a052
PDF
Amine ligand effects in hydroxoaquatetraaminecobalt(III) ion promoted hydrolysis of adenosine 5'-triphosphate
Fikru Tafesse, Salah S. Massoud, and Ronald M. Milburn
pp 1864 - 1865; DOI:
10.1021/ic00061a053
PDF
A high-yield conversion of trans-carbonylchlorobis(triphenylphosphine)rhodium to chlorotris(triphenylphosphine) rhodium
Joseph M. O'Connor and Junning Ma
pp 1866 - 1867; DOI:
10.1021/ic00061a054
PDF
Another bogus isomer: sic transit "green tetrachlorotetrakis(methyldiphenylphosphine)dimolybdenum". The x-ray crystal structure determination of trichlorobis(methyldiphenylphosphine oxide)oxomolybdenum.benzene
F. Albert Cotton, Manu Kohli, Rudy L. Luck, and J. V. Silverton
pp 1868 - 1870; DOI:
10.1021/ic00061a055
PDF
Reactions of 2-benzo[b]thienyl (2-BTyl) complexes with acid to give Cp(PMe3)2Ru(.eta.1(S)-BT)+ and Cp(CO)(PPh3)Ru(.eta.1(S)-BT)+: a model for benzo[b]thiophene (BT) deuterium exchange on hydrodesulfurization catalysts
John William Benson and Robert J. Angelici
pp 1871 - 1874; DOI:
10.1021/ic00061a056
PDF
Di-.mu.-sulfidotetrakis(triphenylphosphine) as a metalloligand toward main-group Lewis acids. A "Mexican-hat-like" structure for [Pt2Tl(.mu.3-S)2(PPh3)4]X (X = NO3, PF6) with a two-coordinate angular thallium(I)
Meisheng Zhou, Yan Xu, Lip Lin Koh, K. F. Mok, Pak Hing Leung, and T. S. Andy Hor
pp 1875 - 1876; DOI:
10.1021/ic00061a057
PDF
Photosubstitution of diazidobis(bipyridine)ruthenium(II) through a radical mechanism
Kyu Wang Lee and Patrick E. Hoggard
pp 1877 - 1878; DOI:
10.1021/ic00061a058
PDF

Issue 10


Monomeric (benzoato)manganese(II) complexes as manganese superoxide dismutase mimics
Nobumasa Kitajima, Masahisa Osawa, Nobuchika Tamura, Yoshihiko Morooka, Tomohisa Hirano, Masaaki Hirobe, and Tetsuo Nagano
pp 1879 - 1880; DOI:
10.1021/ic00062a001
PDF
Reactions of the molybdenum-sulfur double bond in the [(Cp)Mo(O)(.mu.-S)2Mo(O)(S)]- complex with sulfur dioxide. An proton NMR study and the synthesis and structural characterization of [(Cp)Mo(O)(.mu.-S)2Mo(O)(L)]- complexes containing SO2-derived sulfite, thiosulfate, and sulfate bidentate chelating ligands
Chang G. Kim and Dimitri Coucouvanis
pp 1881 - 1882; DOI:
10.1021/ic00062a002
PDF
Synthesis and characterization of a series of tripodal transition metal complexes with the Schiff base of 2,2',2''-triaminoethylamine and 2-pyridinecarboxaldehyde N-oxide. Crystal structures of heptacoordinate manganese(II) and cobalt(II) complexes of a seven-coordinate ligand
Shaohua Gou, Xiaozeng You, Kaibei Yu, and Jianping Lu
pp 1883 - 1887; DOI:
10.1021/ic00062a003
PDF
Photochemical synthesis and structure of a 3-dimensional anionic polymeric network of an iron(II) oxalato complex with tris(2,2'-bipyridine)iron(II) cations
Silvio Decurtins, Helmut W. Schmalle, Philippe Schneuwly, and Hans Rudolf Oswald
pp 1888 - 1892; DOI:
10.1021/ic00062a004
PDF
Synthesis and properties of crown ether-alkali metal cation intercalation compounds of transition metal phosphorus sulfides, MPS3 (M = manganese, cadmium, zinc)
David S. Glueck, Adrian R. Brough, Philip Mountford, and Malcolm L. H. Green
pp 1893 - 1902; DOI:
10.1021/ic00062a005
PDF
Relationships between metal-metal force constants and metal-metal separations for disilver and dipalladium systems. Crystal and molecular structures of Ag2(dmb)2X2 (X = Cl, Br, I; dmb = 1,8-diisocyano-p-menthane) and cis-Pd(CNC(CH3)3)2Cl2 complexes
Daniel Perreault, Marc Drouin, Andre Michel, and Pierre D. Harvey
pp 1903 - 1912; DOI:
10.1021/ic00062a006
PDF
Coordination of ortho chlorines in nickel and zinc 4-substituted 2,6-dichlorophenolates. Crystal and molecular structures of (N,N,N',N'-tetramethyl-1,2-ethanediamine)bis(2,4,6-trichlorophenolato-O,Cl)nickel(II) and tris(pyridine)bis(2,4,6-trichlorophenolato-O)nickel(II)
Mary Frances Richardson, Gary Wulfsberg, Richard Marlow, Suliemann Zaghonni, David McCorkle, Khalid Shadid, John Gagliardi, and Barry Farris
pp 1913 - 1919; DOI:
10.1021/ic00062a007
PDF
New dinuclear penta- and hexacoordinated nickel(II) complexes with .mu.-azido bridges. Crystal structures of ferromagnetically coupled (.mu.-N3)2[Ni(Me3[12]N3)]2(ClO4)2.cntdot.2H2O and (.mu.-N3)2[Ni(232-N4)]2(ClO4)2
Ramon Vicente, Albert Escuer, Joan Ribas, M. Salah el Fallah, Xavier Solans, and Merce Font-Bardia
pp 1920 - 1924; DOI:
10.1021/ic00062a008
PDF
Study of manganese phosphate or arsenate hydrates, MnXO4.nH2O (X = P, As), phases and synthesis and structure of the simple, novel salt MnAsO4
Miguel A. G. Aranda, J. Paul Attfield, and Sebastian Bruque
pp 1925 - 1930; DOI:
10.1021/ic00062a009
PDF
Gas phase metal chalcogenide cluster ions: a new cobalt-sulfur [CoxSy]- series up to [Co38S24]- and two iron-sulfur [FexSy]- series
John El Nakat, Keith J. Fisher, Ian G. Dance, and Gary D. Willett
pp 1931 - 1940; DOI:
10.1021/ic00062a010
PDF
Novel volatile barium .beta.-diketone chelates for chemical vapor deposition of barium fluoride thin films
H. Sato and S. Sugawara
pp 1941 - 1945; DOI:
10.1021/ic00062a011
PDF
Late transition metal oxo and imido complexes. 11. Gold(I) oxo complexes
Yi Yang, Visalakshi Ramamoorthy, and Paul R. Sharp
pp 1946 - 1950; DOI:
10.1021/ic00062a012
PDF
Organoplatinum(II) and -(IV) and organopalladium(II) and -(IV) complexes of a macrocyclic thioether: x-ray crystal structure of Pt(C6H5)2(9S3), an example of exodentate 1,4,7-trithiacyclononane (9S3)
Martin A. Bennett, Allan J. Canty, Josef K. Felixberger, Louis M. Rendina, Christopher Sunderland, and Anthony C. Willis
pp 1951 - 1958; DOI:
10.1021/ic00062a013
PDF
Novel bis((trimethylsilyl)benzamidinato)titanium(III) complexes. Preparation and crystal structures of {PhC[(Me3Si)N]2}2Ti(.mu.-Cl)2Li(TMEDA), {PhC[(Me3Si)N]2}2Ti(BH4), and {PhC[(Me3Si)N]2}2Ti(.eta.3-allyl)
David G. Dick, Jilles J. H. Edema, Robbert Duchateau, and Sandro Gambarotta
pp 1959 - 1962; DOI:
10.1021/ic00062a014
PDF
Transition metal promoted reactions of boron hydrides. 13. Platinum catalyzed synthesis of 6,9-dialkyldecaboranes
Khaled Mazighi, Patrick J. Carroll, and Larry G. Sneddon
pp 1963 - 1969; DOI:
10.1021/ic00062a015
PDF
Triangular phenoxide aggregates of calcium, strontium, and barium: a comparison
Kenneth G. Caulton, Malcolm H. Chisholm, Simon R. Drake, Kirsten Folting, John C. Huffman, and William E. Streib
pp 1970 - 1976; DOI:
10.1021/ic00062a016
PDF
Unexpected coordination of aminoiminophosphoranate ligands with alkali metals
Alexander Steiner and Dietmar Stalke
pp 1977 - 1981; DOI:
10.1021/ic00062a017
PDF
New weakly coordinating anions. 2. Derivatization of the carborane anion CB11H12-
Tomas Jelinek, Patricia Baldwin, W. Robert Scheidt, and Christopher A. Reed
pp 1982 - 1990; DOI:
10.1021/ic00062a018
PDF
Rhenium-carbon bonding in erbium rhenium carbide (Er2ReC2), an organometallic polymer in the solid state
Haibin Deng and Roald Hoffmann
pp 1991 - 1996; DOI:
10.1021/ic00062a019
PDF
Anion-catalyzed heterolysis of chromium-carbon .sigma. bonds. Effect of different anions, temperature, and pressure
Wolfgang Gaede, Rudi van Eldik, Haim Cohen, and Dan Meyerstein
pp 1997 - 2000; DOI:
10.1021/ic00062a020
PDF
Ruthenium ammine/crown ether interactions in solution: effects of modification of both guest and host on the strength of second-sphere complexation
Matthew D. Todd, Yuhua Dong, Jennifer Horney, Dong I. Yoon, and Joseph T. Hupp
pp 2001 - 2004; DOI:
10.1021/ic00062a021
PDF
A Fenton mechanism and an oxochromium(IV) intermediate in reactions of the hydroperoxochromium(III) ion
Wei Dong Wang, Andreja Bakac, and James H. Espenson
pp 2005 - 2009; DOI:
10.1021/ic00062a022
PDF
Kinetics of the heterolysis and homolysis of pentaaqua(benzyl)chromium(III) in acetate buffers
Zhongsheng Zhang and R. B. Jordan
pp 2010 - 2012; DOI:
10.1021/ic00062a023
PDF
Bis(dimethylviolurato)(phenanthroline)cobalt(II), a low-spin octahedral cobalt(II) complex. Crystal structure of [Co(dmvi)2phen].2CHCl3
Juan Faus, Miguel Julve, Francisco Lloret, and M. Carmen Munoz
pp 2013 - 2017; DOI:
10.1021/ic00062a024
PDF
Splitting dioxygen with mesitylcopper(I). An arylcopper(I) intermediate, formed in a coupling reaction, containing two trapped trigonal pyramidally coordinated oxides
Mikael Haakansson, Mikael Oertendahl, Susan Jagner, Michael P. Sigalas, and Odile Eisenstein
pp 2018 - 2024; DOI:
10.1021/ic00062a025
PDF
Distorted manganese cubane [Mn4O3Cl]6+ complexes with arenecarboxylate ligation: crystallographic, magnetochemical, and spectroscopic characterization
Michael W. Wemple, Hui Lien Tsai, Kirsten Folting, David N. Hendrickson, and George Christou
pp 2025 - 2031; DOI:
10.1021/ic00062a026
PDF
1,3,5-Triamino-1,3,5-trideoxy-cis-inositol, a new ligand with a remarkable versatility for metal ions. 3. Preparation and characterization of the aluminum(III), gallium(III), and thallium(III) complexes
Kaspar Hegetschweiler, Michele Ghisletta, Thomas F. Faessler, Reinhard Nesper, Helmut W. Schmalle, and Greti Rihs
pp 2032 - 2041; DOI:
10.1021/ic00062a027
PDF
Synthesis of sulfido and oxo complexes of technetium(V) and rhenium(V) containing dithiolato and hydrotris(1-pyrazolyl)borato ligands. Crystal structures of dimeric bis(.mu.-ethane-1,2-dithiolato)bis(ethene-1,2-dithiolato)technetium(IV) and [hydrotris(1-pyrazolyl)borato](ethane-1,2-dithiolato)oxorhenium(V)
Francesco Tisato, Cristina Bolzati, Adriano Duatti, Giuliano Bandoli, and Fiorenzo Refosco
pp 2042 - 2048; DOI:
10.1021/ic00062a028
PDF
Nuclear magnetic resonance investigation of the hydrogen peroxide oxidation of platinum(II) complexes. Crystal and molecular structures of sodium trans-dihydroxobis(malonato)platinate(IV) hexahydrate and sodium trans-dihydroxobis(oxalato)platinate(IV) hexahydrate
S. O. Dunham, R. D. Larsen, and E. H. Abbott
pp 2049 - 2055; DOI:
10.1021/ic00062a029
PDF
Hemocyanin and tyrosinase models. Synthesis, azide binding, and electrochemistry of dinuclear copper(II) complexes with poly(benzimidazole) ligands modeling the met forms of the proteins
Luigi Casella, Oliviero Carugo, Michele Gullotti, Stefano Garofani, and Piero Zanello
pp 2056 - 2067; DOI:
10.1021/ic00062a030
PDF
Synthesis and characterization of a novel DTPA-like gadolinium(III) complex: a potential reagent for the determination of glycated proteins by water proton NMR relaxation measurements
Silvio Aime, Mauro Botta, Walter Dastru, Mauro Fasano, Maurizio Panero, and Aldo Arnelli
pp 2068 - 2071; DOI:
10.1021/ic00062a031
PDF
Recognition of α-amino acid esters by zinc porphyrin derivatives via coordination and hydrogen bonding interactions. Evidence for two-point fixation from thermodynamic and induced circular dichroism spectroscopic studies
Tadashi Mizutani, Tadashi Ema, Takashi Yoshida, Yasuhisa Kuroda, and Hisanobu Ogoshi
pp 2072 - 2077; DOI:
10.1021/ic00062a032
PDF
Exchange interaction between copper(II) ions through glutamic acid molecules
C. D. Brondino, N. M. C. Casado, M. C. G. Passeggi, and R. Calvo
pp 2078 - 2084; DOI:
10.1021/ic00062a033
PDF
Molybdenum binding site models for the molybdenum cofactor. Synthesis, spectroscopic characterization, and EHMO analysis of (NBun4)Na[Mo(O2CC(S)Ph2)3]
Antonio Cervilla, Jose A. Ramirez, Elisa Llopis, and Pedro Palanca
pp 2085 - 2091; DOI:
10.1021/ic00062a034
PDF
Density functional studies of iron(III) porphines and their one-electron-oxidized derivatives
David H. Jones, A. Scott Hinman, and Tom Ziegler
pp 2092 - 2095; DOI:
10.1021/ic00062a035
PDF
Temperature and magnetic field effects on the luminescence of thallium(1+) tetracyanoplatinate(1-)
B. Weissbart, A. L. Balch, and D. S. Tinti
pp 2096 - 2103; DOI:
10.1021/ic00062a036
PDF
Singlet-triplet separations measured by phosphorus-31{proton} NMR; applications to quadruply-bonded dimolybdenum and ditungsten complexes
F. Albert Cotton, Judith L. Eglin, Bo Hong, and Chris A. James
pp 2104 - 2106; DOI:
10.1021/ic00062a037
PDF
Electrocatalysis of the reduction of dioxygen by adsorbed cobalt 5,10,15,20-tetraarylporphyrins to which one, two, or three pentaammineruthenium(2+) centers are coordinated
Beat Steiger, Chunnian Shi, and Fred C. Anson
pp 2107 - 2113; DOI:
10.1021/ic00062a038
PDF
Magnetic properties of isostructural dodecanuclear polyoxovanadates with six and eight vanadium(IV) ions
Dante Gatteschi, Boris Tsukerblatt, Anne Laure Barra, Louis Claude Brunel, Achim Mueller, and Joachim Doering
pp 2114 - 2117; DOI:
10.1021/ic00062a039
PDF
Synthesis and solution structure of heterobimetallic rhenium-iridium polyhydride complexes
Demetrius Michos, Xiao Liang Luo, and Robert H. Crabtree
pp 2118 - 2122; DOI:
10.1021/ic00062a040
PDF
Stability of pentaammineosmium(II) in aqueous solution
Jason T. Call, Karin A. Hughes, W. Dean Harman, and M. G. Finn
pp 2123 - 2127; DOI:
10.1021/ic00062a041
PDF
Synthesis and structural characterization of the trinuclear mixed-valence complex [{(tiptacn)MoVO(.mu.-O)2}2MoIV(bpy)](PF6)2.cntdot.0.25CH3NO2 (tiptacn = 1,4,7-tris(2-propyl)-1,4,7-triazacyclononane)
Stefan Stoetzel, Karl Wieghardt, and Bernhard Nuber
pp 2128 - 2131; DOI:
10.1021/ic00062a042
PDF
Structure of the lithium thiocyanate-tetramethylpropylenediamine complex dimer, [LiNCS-Me2N(CH2)3NMe2]2, with asymmetric NCS-bridge bonding: a new bonding mode for the thiocyanate ligand
David R. Armstrong, Amit H. Khandelwal, Paul R. Raithby, Ronald Snaith, Dietmar Stalke, and Dominic S. Wright
pp 2132 - 2136; DOI:
10.1021/ic00062a043
PDF
Effects of temperature on the crystal and molecular structure of the mixed-valence linear chain bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = chloro, bromo)
Sara C. Huckett, Brian Scott, Steven P. Love, Robert J. Donohoe, Carol J. Burns, Ed Garcia, Tracey Frankcom, and Basil I. Swanson
pp 2137 - 2144; DOI:
10.1021/ic00062a044
PDF
Mono- and binuclear molybdenum and tungsten complexes containing asymmetric bridging ligands: effects of ligand conjugation and conformation on metal-metal interactions
Amitava Das, John C. Jeffery, John P. Maher, Jon A. McCleverty, Erik Schatz, Michael D. Ward, and Gerd Wollermann
pp 2145 - 2155; DOI:
10.1021/ic00062a045
PDF
Carbon-rich metallacarboranes. 15. Novel metal-promoted cluster fusion reactions
Kent W. Piepgrass, Michael A. Curtis, Xiaotai Wang, Xiangsheng Meng, Michal Sabat, and Russell N. Grimes
pp 2156 - 2163; DOI:
10.1021/ic00062a046
PDF
Chelating properties of 2-((diphenylphosphino)methyl)pyridine N,P-dioxide and 2,6-bis((diphenylphosphino)methyl)pyridine N,P,P'-trioxide toward f-element ions
B. M. Rapko, E. N. Duesler, P. H. Smith, R. T. Paine, and R. R. Ryan
pp 2164 - 2174; DOI:
10.1021/ic00062a047
PDF
Nucleophile promoted degradation of catecholborane: consequences for transition metal-catalyzed hydroborations
Stephen A. Westcott, Henk P. Blom, Todd B. Marder, R. Thomas Baker, and Joseph C. Calabrese
pp 2175 - 2182; DOI:
10.1021/ic00062a048
PDF
Mixed platinum(II)-mercury(II) cytosine nucleobase complexes with metal-metal bonds
Michael Krumm, Ennio Zangrando, Lucio Randaccio, Stephan Menzer, Annette Danzmann, Dagmar Holthenrich, and Bernhard Lippert
pp 2183 - 2189; DOI:
10.1021/ic00062a049
PDF
Oxygen versus nitrogen coordination of a urea to (diethylenetriamine)platinum(II)
Tai Chin Woon, Wasantha A. Wickramasinghe, and David P. Fairlie
pp 2190 - 2194; DOI:
10.1021/ic00062a050
PDF
Complexation of alkali metal ions by the pendant arm macrocyclic ligand 1,4,7,10-tetrakis(2-hydroxyethyl)-1,4,7,10-tetraazacyclododecane. A potentiometric titration and nuclear magnetic resonance study
Mary L. Turonek, Philip Clarke, Gerald S. Laurence, Stephen F. Lincoln, Pierre Andre Pittet, Steve Politis, and Kevin P. Wainwright
pp 2195 - 2198; DOI:
10.1021/ic00062a051
PDF
Correlations between the ligand electrochemical parameter, EL(L), and the Hammett substituent parameter, .sigma.
Hitoshi Masui and A. B. P. Lever
pp 2199 - 2201; DOI:
10.1021/ic00062a052
PDF
Insight into formation and reactivity of molybdenum(0) bent nitrenes. Crystal structure of a phosphine-phosphoranimine chelate
A. Saravanamuthu, D. M. Ho, M. E. Kerr, C. Fitzgerald, M. R. M. Bruce, and A. E. Bruce
pp 2202 - 2206; DOI:
10.1021/ic00062a053
PDF
A molecular dynamics study of carboxypeptidase A: effect of protonation of Glu 270
Lucia Banci, Ivano Bertini, and Giovanni La Penna
pp 2207 - 2211; DOI:
10.1021/ic00062a054
PDF
Reaction of tetraethylammonium tetrakis(tetracarbonyliron)bismuthate(3-) with isobutyl bromide. Isolation of the tetrahedral anionic complex [Et4N]2[iso-BuBi{Fe(CO)4}3] and the ring complex (iso-Bu)2Bi2Fe2(CO)8
Minghuey Shieh, Yeantarn Liou, Shie Ming Peng, and Gene Hsiang Lee
pp 2212 - 2214; DOI:
10.1021/ic00062a055
PDF
Bonding flexibility of 2,2'-bipyrimidine (bpm): symmetry and magnetism of three copper(II) complexes with different Cu:bpm ratios
Giovanni De Munno, Miguel Julve, Michel Verdaguer, and Giuseppe Bruno
pp 2215 - 2220; DOI:
10.1021/ic00062a056
PDF
(Phosphinoalkyl)silanes. 2. Synthesis and spectroscopic properties of the poly(phosphinoalkyl)silanes SiHR[(CH2)nPR'2]2 (R = Me or Ph; n = 2 or 3; R' = Ph or cyclohexyl) and SiH[(CH2)nPR'2]3 (R = Me or Ph; n = 2, R' = Ph or cyclohexyl; n = 3, R' = Ph)
Frederick L. Joslin and Stephen R. Stobart
pp 2221 - 2223; DOI:
10.1021/ic00062a057
PDF
Additions and Corrections - Structural and Spectroscopic Correlations in Cadmium(II) Halide Complexes of 2,2-Dimethylpropane- 1,3-diamine.
N. Masciocchi, M. Moret, A. Sironi, S. Bruni, F. Cariati, A. Pozzi, T. Manfredini, L. Menabue, and G. C. Pellacani
pp 2224 - 2224; DOI:
10.1021/ic00062a600
PDF

Issue 11


Excited-state interaction of dicyanocuprate(1-) with halide ions. Does the emission originate from a simple inorganic exciplex?
A. Horvath and K. L. Stevenson
pp 2225 - 2227; DOI:
10.1021/ic00063a001
PDF
Intermetal oxygen, sulfur, and selenium atom transfer reactions involving titanium porphyrin complexes
L. Keith Woo and J. Alan Hays
pp 2228 - 2229; DOI:
10.1021/ic00063a002
PDF
Near doubling of hydrogen-hydrogen bond length in the "stretched" osmium molecular hydrogen complex [Os(NH3)4OAc(.eta.2-H2)]+: a theoretical study
J. Simon Craw, George B. Bacskay, and Noel S. Hush
pp 2230 - 2231; DOI:
10.1021/ic00063a003
PDF
Dimerization of the molybdenum complex [(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)]2- dianions stabilized by a quadruply bridging sulfate ligand and intramolecular hydrogen bonding by the [(CH3)2NH2]+ cations. Structures of the [(CH3)2NH2]6-x(Et4N)x[{(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)}2(SO4)] aggregates (x = 1, 2, 2.5)
Chang G. Kim and Dimitri Coucouvanis
pp 2232 - 2233; DOI:
10.1021/ic00063a004
PDF
Relative importance of oligomerized structures and donor-acceptor interactions in electrophilic cyclopentadienyl compounds
Pamela S. Tanner, R. Allen Williams, and Timothy P. Hanusa
pp 2234 - 2235; DOI:
10.1021/ic00063a005
PDF
Hydrogen/deuterium exchange reactions of an iridium dithiol complex
Philip G. Jessop and Robert H. Morris
pp 2236 - 2237; DOI:
10.1021/ic00063a006
PDF
Preparation and spectroscopic characterization of 1,5- and 1,3-diphosphadiselenatetrazocines: x-ray structure of [N(PMe2NH2)2]2Se
Tristram Chivers, Daniel D. Doxsee, and Masood Parvez
pp 2238 - 2242; DOI:
10.1021/ic00063a007
PDF
Preparation and solid-state isomerization of Se,Se'-dialkyltetraphenyldiphosphadiselenatetrazocines: x-ray structures of 1,5-Ph4P2N4Se2Me2 and [Ph2P(NH2)2]2Se
Tristram Chivers, Daniel D. Doxsee, James F. Fait, and Masood Parvez
pp 2243 - 2248; DOI:
10.1021/ic00063a008
PDF
Cis-trans isomerization of [bis(L-methioninato)platinum]: metabolite of the anticancer drug cisplatin
Socorro del Piedad Murdoch, John D. Ranford, Peter J. Sadler, and Susan J. Berners-Price
pp 2249 - 2255; DOI:
10.1021/ic00063a009
PDF
Platinum hydride cluster complexes
Ravindranath Ramachandran and Richard J. Puddephatt
pp 2256 - 2260; DOI:
10.1021/ic00063a010
PDF
Electron transfer. 117. Copper catalysis in thiol reduction of bound superoxide. A second mechanistic variation
Sanchita Purohit Ghosh, S. K. Saha, R. N. Bose, J. W. Reed, Manik C. Ghosh, and E. S. Gould
pp 2261 - 2264; DOI:
10.1021/ic00063a011
PDF
Indium-115 NMR studies of reactions of indium trihalides with halides and pseudohalides in acetonitrile solution. Complexes with different coordination numbers
M. A. Malyarick and S. P. Petrosyants
pp 2265 - 2268; DOI:
10.1021/ic00063a012
PDF
Mechanism of associative photoinduced ligand substitution in tetracarbonyl(phenanthroline)tungsten under metal-to-ligand charge-transfer excitation: subnanosecond transient spectra and solvent and wavelength dependence evidence for rapid primary processes
Elspeth Lindsay, Antonin Vlcek, and Cooper H. Langford
pp 2269 - 2275; DOI:
10.1021/ic00063a013
PDF
Synthesis of S-alkyl and S-acyl derivatives of mercaptoundecahydrododecaborate, a possible boron carrier for neutron capture therapy
Detlef Gabel, Detlef Moller, Sven Harfst, Jens Roesler, and Hartmut Ketz
pp 2276 - 2278; DOI:
10.1021/ic00063a014
PDF
Reactions of two- and three-coordinate (silylamino)phosphines with propargyl halides
Christo M. Angelov and Robert H. Neilson
pp 2279 - 2281; DOI:
10.1021/ic00063a015
PDF
Chromium(II) and molybdenum(II) N,N-diethylcarbamato complexes from metal halides/carbon dioxide/diethylamine: crystal and molecular structure of the quadruply metal-metal-bonded Mo2(O2CNEt2)4
Antonio Belforte, Daniela Belli Dell'Amico, Fausto Calderazzo, Michel Devillers, and Ulli Englert
pp 2282 - 2286; DOI:
10.1021/ic00063a016
PDF
Triphenylsiloxy complexes. A novel compound containing a molybdenum(VI)-phosphorus bond: dioxo(triphenylphosphine)bis(triphenylsiloxo)molybdenum
Mingdong Huang and Carroll W. DeKock
pp 2287 - 2291; DOI:
10.1021/ic00063a017
PDF
Redox behavior of ferrocene derivatives. 2. Bis(.eta.5-tricyclo[5.2.1.02,6]deca-2,5,8-trien-6-yl)iron and related molecules
Judith C. Gallucci, Giuliana Opromolla, Leo A. Paquette, Luca Pardi, Paulo F. T. Schirch, Mark R. Sivik, and Piero Zanello
pp 2292 - 2297; DOI:
10.1021/ic00063a018
PDF
Syntheses and characterization of the first thallium polysulfide anions
Sandeep S. Dhingra and Mercouri G. Kanatzidis
pp 2298 - 2307; DOI:
10.1021/ic00063a019
PDF
Trisilylmethane as a structural backbone in multifunctional lithium amides: syntheses and structures of HC{(CH3)2SiN(Li)-tert-Bu}3 and its solvate HC{(CH3)2SiN(Li)-tert-Bu}3.cntdot.2THF
Lutz H. Gade, Christian Becker, and Joseph W. Lauher
pp 2308 - 2314; DOI:
10.1021/ic00063a020
PDF
Cyanophosphazene small molecules and high polymers: synthesis and structure
H. R. Allcock, J. Steven Rutt, Mark F. Welker, and Masood Parvez
pp 2315 - 2321; DOI:
10.1021/ic00063a021
PDF
Interconverting edge-sharing and face-sharing bioctahedral dinuclear tungsten(III) phosphine complexes. Preparations, properties, and structures of W2Cl6L4, where L = PMe3, PEt3, and P(n-Bu)3, W2Cl6L3, where L = PEt3 and P(n-Bu)3, and [HPEt3]+[W2Cl7(PEt3)2]-
Jane T. Barry, Stephanie T. Chacon, Malcolm H. Chisholm, Vince F. DiStasi, John C. Huffman, William E. Streib, and William G. Van Der Sluys
pp 2322 - 2331; DOI:
10.1021/ic00063a022
PDF
Stereo- and regiospecific conversions of rhodium halo phosphines Rh2X6(PR3)3 molecules to Rh2X6(PR3)4 and RhX3(PR3)3 molecules
F. Albert Cotton, Judith L. Eglin, and Seong Joo Kang
pp 2332 - 2335; DOI:
10.1021/ic00063a023
PDF
Preparation and structure of rhodium phosphine compounds containing the [Rh2X7(PR3)2]- anion and their stereospecific reactions with phosphines to produce [Rh2X7(PR3)3]- species
F. Albert Cotton and Seong Joo Kang
pp 2336 - 2342; DOI:
10.1021/ic00063a024
PDF
Quadruply bonded dimolybdenum compounds with polydentate phosphines. 1. Mo2X4(tetraphos-1) (tetraphos-1 = Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2, X = Cl, Br), the first examples of enantiomeric 1,2,5,8/1,2,6,7 and 1,2,5,7/1,2,6,8 types
Jhy Der Chen, F. Albert Cotton, and Bo Hong
pp 2343 - 2353; DOI:
10.1021/ic00063a025
PDF
Quadruply bonded dimolybdenum compounds with polydentate phosphines. 2. Structural and spectroscopic properties of quadruply bonded rac-Mo2Cl4(PEt3)(.eta.3-tetraphos-2) (tetraphos-2 = tris(diphenylphosphinoethyl)phosphine)
F. Albert Cotton and Bo Hong
pp 2354 - 2359; DOI:
10.1021/ic00063a026
PDF
Rhodium(I) and rhodium(III) phosphine complexes with nonbridging benzenethiolato ligands: preparation, structures, and chemical properties
Kohtaro Osakada, Kouji Hataya, and Takakazu Yamamoto
pp 2360 - 2365; DOI:
10.1021/ic00063a027
PDF
Classical, nonclassical, and mixed-metal osmium(II) polyhydrides stabilized by the tetraphosphine P(CH2CH2PPh2)3. Hydrogen/deuterium isotope exchange reactions promoted by a strongly bound dihydrogen ligand
Claudio Bianchini, Klaus Linn, Dante Masi, Maurizio Peruzzini, Alfonso Polo, Alberto Vacca, and Fabrizio Zanobini
pp 2366 - 2376; DOI:
10.1021/ic00063a028
PDF
Theoretical and spectroscopic studies of tetrahedral gold clusters of the type (L3M(.mu.-H)x{AuL'}3]2+ (M = rhodium iridium, x = 2; M = ruthenium, x = 3)
Alberto Albinati, Juergen Eckert, Peter Hofmann, Heinz Ruegger, and Luigi M. Venanzi
pp 2377 - 2390; DOI:
10.1021/ic00063a029
PDF
Activation volume (.DELTA. V.dbldag.q) for energy- and electron-transfer quenching of [Cu(dpp)2+]* (dpp = 2,9-diphenyl-1,10-phenanthroline)
Daniel R. Crane and Peter C. Ford
pp 2391 - 2393; DOI:
10.1021/ic00063a030
PDF
Nitrogen-15 NMR studies of tetrazole complexes of pentaamminecobalt(III). Implications concerning the transition state for linkage isomerization
S. Hubinger, J. H. Hall, and W. L. Purcell
pp 2394 - 2398; DOI:
10.1021/ic00063a031
PDF
Iron(II)-catalyzed autoxidation of a macrocyclic cobalt(II) complex
Adam Marchaj, Andreja Bakac, and James H. Espenson
pp 2399 - 2403; DOI:
10.1021/ic00063a032
PDF
Thermodynamic and kinetic studies of migratory carbon monoxide insertion in alkyl complexes of iron(II)
Gianfranco Bellachioma, Giuseppe Cardaci, Chet Jablonski, Alceo Macchioni, and Gustavo Reichenbach
pp 2404 - 2409; DOI:
10.1021/ic00063a033
PDF
Enthalpies of reaction of (diene)- and (enone)iron tricarbonyl complexes with monodentate and bidentate ligands. Solution thermochemical study of ligand substitution in the L2Fe(CO)3 complexes
Lubin Luo and Steven P. Nolan
pp 2410 - 2415; DOI:
10.1021/ic00063a034
PDF
A green heteropoly blue: isolation of a stable, odd oxidation level in a Dawson molybdate anion, [S2Mo18O62]5-
John B. Cooper, David M. Way, Alan M. Bond, and Anthony G. Wedd
pp 2416 - 2420; DOI:
10.1021/ic00063a035
PDF
Calorimetric studies of the heats of protonation of the dangling phosphorus in .eta.-bis(diphenylphosphino)methane complexes of chromium, molybdenum, and tungsten
Mary K. Rottink and Robert J. Angelici
pp 2421 - 2425; DOI:
10.1021/ic00063a036
PDF
Multinuclear magnetic resonance study of the structure and dynamics of lanthanide(III) complexes of the bis(propylamide) of diethylenetriaminepentaacetic acid in aqueous solution
Carlos F. G. C. Geraldes, Ana M. Urbano, Mattheus A. Hoefnagel, and Joop A. Peters
pp 2426 - 2432; DOI:
10.1021/ic00063a037
PDF
Solvent effects in the reductions of (ethylenediamine)bis(oxalato)cobaltate(1-) and (glycinato)bis(oxalato)cobaltate(2-) by tris(ethylenediamine)cobalt(2+)
Akira Tatehata, Hiroshi Oota, Tsuyoshi Fukagawa, Robert M. L. Warren, and A. Graham Lappin
pp 2433 - 2436; DOI:
10.1021/ic00063a038
PDF
Tetrahedral-atom 3-ring groupings in 1-dimensional inorganic chains: beryllium arsenate hydroxide hydrate (Be2AsO4OH.cntdot.4H2O) and sodium zinc hydroxide phosphate hydrate (Na2ZnPO4OH.cntdot.7H2O)
William T. A. Harrison, Tina M. Nenoff, Thurman E. Gier, and Galen D. Stucky
pp 2437 - 2441; DOI:
10.1021/ic00063a039
PDF
Molecular structure of 1-aza-closo-dodecaborane(12). Experimental and theoretical refinement
Drahomir Hnyk, Michael Buehl, Paul v. R. Schleyer, Hans V. Volden, Snefrid Gundersen, Jens Mueller, and Peter Paetzold
pp 2442 - 2445; DOI:
10.1021/ic00063a040
PDF
Triplet exciton activation in moderately coupled (0.21 eV), discrete tetrakis(methylthio)-TTF.bul.+ dimers: a manifestation of the weakening of the intradimer interaction upon binding of the outer methylthio and thiocyanate functionalities in [(MeS)4TTF.bul.+]2[Mo6Cl8(NCS)62-], completed by the synthesis and structure of the tetrabutylammonium salt of the cluster dianion, (Bu4N)2[Mo6Cl8(NCS)6]
Aude Guirauden, Ib Johannsen, Patrick Batail, and Claude Coulon
pp 2446 - 2452; DOI:
10.1021/ic00063a041
PDF
Syntheses, structures, and properties of six novel alkali metal tin sulfides: K2Sn2S8, .alpha.-Rb2Sn2S8, .beta.-Rb2Sn2S8, K2Sn2S5, Cs2Sn2S6, and Cs2SnS14
Ju Hsiou Liao, Constantinos Varotsis, and Mercouri G. Kanatzidis
pp 2453 - 2462; DOI:
10.1021/ic00063a042
PDF
Ferromagnetism in triangular cobalt(II) layers: comparison of cobalt dihydroxide and cobalt nitrate hydroxide (Co2(NO3)(OH)3)
P. Rabu, S. Angelov, P. Legoll, M. Belaiche, and M. Drillon
pp 2463 - 2468; DOI:
10.1021/ic00063a043
PDF
Photoperturbation of the 1A .dblharw. 5T spin equilibrium in an iron(II) complex in solution via ligand field excitation
John J. McGarvey, Hans Toftlund, Ala H. R. Al-Obaidi, K. Paul Taylor, and Steven E. J. Bell
pp 2469 - 2472; DOI:
10.1021/ic00063a044
PDF
Addition of new donors to the E and C model
Russell S. Drago, Andrew P. Dadmun, and Glenn C. Vogel
pp 2473 - 2479; DOI:
10.1021/ic00063a045
PDF
Effect of isotopic substitution on association with the sodium counterion
Cheryl D. Stevenson, Eugene P. Wagner, and Richard C. Reiter
pp 2480 - 2482; DOI:
10.1021/ic00063a046
PDF
Structure and the electronic properties of a Jahn-Teller distorted tetrahedral nickel(II) complex with sulfur ligands
Andreas Wilk, Michael A. Hitchman, Werner Massa, and Dirk Reinen
pp 2483 - 2490; DOI:
10.1021/ic00063a047
PDF
Matrix infrared spectra of aluminum, gallium, and indium complexes with acetylene
Thomas R. Burkholder and Lester Andrews
pp 2491 - 2496; DOI:
10.1021/ic00063a048
PDF
An EXAFS spectroscopic study of solvates of copper(I) and copper(II) in acetonitrile, dimethyl sulfoxide, pyridine, and tetrahydrothiophene solutions and a large-angle x-ray scattering study of the copper(II) acetonitrile solvate in solution
Ingmar Persson, James E. Penner-Hahn, and Keith O. Hodgson
pp 2497 - 2501; DOI:
10.1021/ic00063a049
PDF
Syntheses and characterization of gold(I) and platinum(II) complexes containing tris(2-cyanoethyl)phosphine. X-ray crystal structures of [(CEP)2Au]Cl, cis-(CEP)(Et2S)PtCl2, and trans-(CEP)2PtCl2
M. Nazrul I. Khan, Christopher King, John P. Fackler, and Richard E. P. Winpenny
pp 2502 - 2505; DOI:
10.1021/ic00063a050
PDF
Synthesis, structure, and electronic spectroscopy of neutral, dinuclear gold(I) complexes. Gold(I)-gold(I) interactions in solution and in the solid state
Ratnavathany Narayanaswamy, Michelle A. Young, Erica Parkhurst, Michelle Ouellette, Margaret E. Kerr, Douglas M. Ho, Richard C. Elder, Alice E. Bruce, and Mitchell R. M. Bruce
pp 2506 - 2517; DOI:
10.1021/ic00063a051
PDF
Electronic spectra and photophysics of platinum(II) complexes with .alpha.-diimine ligands. Mixed complexes with halide ligands
Vincent M. Miskowski, Virginia H. Houlding, Chi Ming Che, and Yu Wang
pp 2518 - 2524; DOI:
10.1021/ic00063a052
PDF
Metalloprotein-cobalt cage electron transfer and the stereoselective reduction of spinach plastocyanin by .LAMBDA.- and .DELTA.-[Co((N(CH3)3)2-sar)]4+
Jack R. Pladziewicz, Molly A. Accola, Peter Osvath, and Alan M. Sargeson
pp 2525 - 2533; DOI:
10.1021/ic00063a053
PDF
Transition metal complexes with sulfur ligands. 97. Coordinatively and electronically unsaturated and saturated chromium, molybdenum, and tungsten dithiolate complexes of the type [M(CO)3('S2')]2- and [M2(CO)7('S2')]2- {'S2'2- = S2C6R42- (R = H, Cl, Me); S2C2H42-}
Dieter Sellmann, Monika Wille, and Falk Knoch
pp 2534 - 2543; DOI:
10.1021/ic00063a054
PDF
Heteronuclear NMR studies of cobalt corrinoids. 14. Amide proton and nitrogen-15 NMR studies of base-on cobalamins
Kenneth L. Brown and Daniel R. Evans
pp 2544 - 2548; DOI:
10.1021/ic00063a055
PDF
Controlled aggregation and deaggregation of a polynuclear oxido-bridged manganese complex: utility to synthesis of the Jahn-Teller effect in high-spin manganese(III)
Eduardo Libby, Kirsten Folting, Carolyn J. Huffman, John C. Huffman, and George Christou
pp 2549 - 2556; DOI:
10.1021/ic00063a056
PDF
Synthesis and characterization of the monomeric gallium monoamides tert-Bu2GaN(R)SiPh3 (R = tert-Bu, 1-adamantyl), Trip2MN(H)Dipp (M = Al, Ga; Trip = 2,4,6-iso-Pr3C6H2; Dipp = 2,6-iso-Pr2C6H3), and Trip2GaNPh2
K. M. Waggoner, K. Ruhlandt-Senge, R. J. Wehmschulte, X. He, M. M. Olmstead, and P. P. Power
pp 2557 - 2561; DOI:
10.1021/ic00063a057
PDF
Symmetrical and unsymmetrical quadruply aza-bridged closely interspaced cofacial bis(5,10,15,20-tetraphenylporphyrins). 4. Structure and conformational effects on electrochemistry and the catalysis of electrochemical reduction of dioxygen by doubly, triply, and quadruply N,N-dimethylene sulfonamide bridged dimer bis(cobalt tetraphenylporphyrins)
Seungwon Jeon, Orn Almarsson, Rafik Karaman, Andrei Blasko, and Thomas C. Bruice
pp 2562 - 2569; DOI:
10.1021/ic00063a058
PDF
Luminescence rigidochromism of fac-tricarbonylchloro(4,7-diphenyl-1,10-phenanthroline)rhenium as a spectroscopic probe in monitoring polymerization of photosensitive thin films
Thomas G. Kotch, Alistair J. Lees, Stephen J. Fuerniss, Kostas I. Papathomas, and Randy W. Snyder
pp 2570 - 2575; DOI:
10.1021/ic00063a059
PDF
An electron spin echo envelope modulation (ESEEM) study of electron-nuclear hyperfine and nuclear quadrupole interactions of dz2 ground state copper(II) complexes with substituted imidazoles
Feng Jiang, Kenneth D. Karlin, and Jack Peisach
pp 2576 - 2582; DOI:
10.1021/ic00063a060
PDF
Langmuir-Blodgett (LB) films of tris(2-phenylpyridine)iridium(III)
H. A. Samha, T. J. Martinez, M. K. De Armond, F. O. Garces, and R. J. Watts
pp 2583 - 2586; DOI:
10.1021/ic00063a061
PDF
Mechanism of bicarbonate CO3H radical generation in the charge-transfer photochemistry of tetraammine(carbonato)cobalt(1+). A picosecond to microsecond flash photochemical investigation of the reaction intermediates
G. Ferraudi and M. Perkovic
pp 2587 - 2590; DOI:
10.1021/ic00063a062
PDF
Cisplatin as a synthon. Synthesis and characterization of triplatinum complexes containing three cis-(Pt(amine)2 units linked in a linear fashion
Yun Qu, Trevor G. Appleton, James D. Hoeschele, and Nicholas Farrell
pp 2591 - 2593; DOI:
10.1021/ic00063a063
PDF
Vibronic structure in the emission spectrum of the tetranuclear copper cluster [Cu4]4(dmpp)4]
Dorothy C. Lai and Jeffrey I. Zink
pp 2594 - 2596; DOI:
10.1021/ic00063a064
PDF
Synthesis, structure, and properties of the novel iron complex of mixed .kappa.3N- and .kappa.3O-tripod ligands: [n-Bu4N][(HB(pz)3)Fe(P3O9)]
Kyu Nam Han, Dongmok Whang, Hae Jeong Lee, Youngkyu Do, and Kimoon Kim
pp 2597 - 2599; DOI:
10.1021/ic00063a065
PDF
Thermolysis of halo- and alkylaluminum silylamido complexes and the Al4N4 cubane core structure of [iso-BuAlNSiPh3]4
Deborah M. Choquette, Mary Jo Timm, Jason L. Hobbs, Thomas M. Nicholson, Marilyn M. Olmstead, and Roy P. Planalp
pp 2600 - 2603; DOI:
10.1021/ic00063a066
PDF
A seven-coordinate mixed-dithiolate complex of niobium(V): synthesis and structure of (PPh4)[Nb(SCH2CH2S)2(SCH2CH2SCH2CH2S)]
Kazuyuki Tatsumi, Hiroyuki Kawaguchi, Ichiro Matsubara, Akira Nakamura, Kunio Miki, and Nobutami Kasai
pp 2604 - 2606; DOI:
10.1021/ic00063a067
PDF

Issue 12


Isolation, reactivity, and molecular structure of bis(2,2'-bipyridine)(.mu.-N-acetyl-L-cysteinato-S)diplatinum: model of the interaction of platinum with protein sulfur residues
Kathryn A. Mitchell, Katherine C. Streveler, and Craig M. Jensen
pp 2608 - 2609; DOI:
10.1021/ic00064a001
PDF
Coordination patterns for oxophlorin ligands. Pyridine-induced cleavage of dimeric manganese(III) and iron(III) octaethyloxophlorin complexes
Alan L. Balch, Bruce C. Noll, Steven M. Reid, and Edward P. Zovinka
pp 2610 - 2611; DOI:
10.1021/ic00064a002
PDF
Synthesis and structure of new aminopentaborane derivatives
Donald F. Gaines, Robert W. McGaff, and Douglas R. Powell
pp 2612 - 2613; DOI:
10.1021/ic00064a003
PDF
Photocatalytic self-generation. Mercury(II) reduction via photochemical reactions of the dimercury(I) cation, Hg22+
O. Horvath, P. C. Ford, and A. Vogler
pp 2614 - 2615; DOI:
10.1021/ic00064a004
PDF
Optical transitions of molybdenum(V) in glycerol-inhibited DMSO reductase from Rhodobacter sphaeroides
Michael G. Finnegan, James Hilton, K. V. Rajagopalan, and Michael K. Johnson
pp 2616 - 2617; DOI:
10.1021/ic00064a005
PDF
Application of time-resolved resonance Raman spectroscopy to intramolecular electron transfer
Jon R. Schoonover, Geoffrey F. Strouse, Pingyun Chen, W. Douglas Bates, and Thomas J. Meyer
pp 2618 - 2619; DOI:
10.1021/ic00064a006
PDF
Synthesis, structural characterization, and properties of singly bridged double molybdenum-iron cubanes containing two [(Cl4-cat)MoFe3S4Cl3]2- subunits and hydrazine or pyrazine bridges
Patrick E. Mosier, Chang G. Kim, and Dimitri Coucouvanis
pp 2620 - 2621; DOI:
10.1021/ic00064a007
PDF
A computational analysis of the bonding in boron trifluoride and boron trichloride and their complexes with ammonia
Tore Brinck, Jane S. Murray, and Peter Politzer
pp 2622 - 2625; DOI:
10.1021/ic00064a008
PDF
Copper(I) tetrahydroborate derivatives containing phosphine and phenanthroline ligands: an electrospray mass spectrometric study of species in solution
Ray Colton, Bruce D. James, Ian D. Potter, and John C. Traeger
pp 2626 - 2629; DOI:
10.1021/ic00064a009
PDF
Structure of tetrakis(phosphine)nitrido- or -phosphinidyne or arsinidyneultragold(1+): Td or C4v?
Jian Li and Pekka Pyykko
pp 2630 - 2634; DOI:
10.1021/ic00064a010
PDF
Ligand-substitution reactions of aquacobalamin (vitamin B12a) revisited. Conclusive evidence for the operation of a dissociative interchange mechanism
Martin Meier and Rudi van Eldik
pp 2635 - 2639; DOI:
10.1021/ic00064a011
PDF
An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5)
Juergen Poppe, Michael Moscherosch, and Wolfgang Kaim
pp 2640 - 2643; DOI:
10.1021/ic00064a012
PDF
Cation complexation by chemically modified calixarenes. 5. Protonation constants for calixarene carboxylates and stability constants of their alkali and alkaline-earth complexes
Francoise Arnaud-Neu, Geraldine Barrett, Steven J. Harris, Michael Owens, M. Anthony McKervey, Marie Jose Schwing-Weill, and Pascale Schwinte
pp 2644 - 2650; DOI:
10.1021/ic00064a013
PDF
Nucleophilic activation of coordinated carbon monoxide. Reaction of tungsten hexacarbonyl with methoxide salts
Allan Bates, Mark T. Muraoka, and Raymond J. Trautman
pp 2651 - 2656; DOI:
10.1021/ic00064a014
PDF
Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution
Etsuko Fujita, Carol Creutz, Norman Sutin, and Bruce S. Brunschwig
pp 2657 - 2662; DOI:
10.1021/ic00064a015
PDF
One- and two-dimensional solution and solid-state NMR studies of di- and trinuclear optically active ferrocenylphosphine complexes of mercury(II)
Ruth E. Blumer, Francesca Lianza, Paul S. Pregosin, Heinz Ruegger, and Antonio Togni
pp 2663 - 2669; DOI:
10.1021/ic00064a016
PDF
Dynamics and phase transitions in spin-crossover complexes: x-ray structures and basic crossover phenomena in the solvate series bis(3-ethoxysalicylideneaziridinopropylaminato)iron perchlorate.solvate
Andrew J. Conti, Raj K. Chadha, Kathryn M. Sena, Arnold L. Rheingold, and David N. Hendrickson
pp 2670 - 2680; DOI:
10.1021/ic00064a017
PDF
Dynamics and phase transitions in spin-crossover complexes: detailed nature of phase transitions in the solvate series bis(3-ethoxysalicylideneaziridinopropylaminato)iron perchlorate.solvate
Andrew J. Conti, Kazutoshi Kaji, Yatsuhisa Nagano, Kathryn M. Sena, Yohko Yumoto, Raj K. Chadha, Arnold L. Rheingold, Michio Sorai, and David N. Hendrickson
pp 2681 - 2693; DOI:
10.1021/ic00064a018
PDF
Structural characterization of two modifications of tris(tetrahydrofuran)(tris(trimethylsilyl)silyl)lithium: a compound with a silicon-29-lithium-7 NMR coupling
Andreas Heine, Regine Herbst-Irmer, George M. Sheldrick, and Dietmar Stalke
pp 2694 - 2698; DOI:
10.1021/ic00064a019
PDF
1,3,5-Triamino-1,3,5-trideoxy-cis-inositol, a new ligand with a remarkable versatility for metal ions. 4. Preparation, characterization, and x-ray structure of the trinuclear lead(II) and bismuth(III) complexes
Kaspar Hegetschweiler, Michele Ghisletta, and Volker Gramlich
pp 2699 - 2704; DOI:
10.1021/ic00064a020
PDF
Preparation of iron indium carbonyl complexes [K][In{Fe2(CO)8}2](THF) and Fe2{.mu.-InCl(THF)}2(CO)8 (THF = tetrahydrofuran)
Chu Chieh Lin, Gapgoung Kong, Hyunho Cho, and Bruce R. Whittlesey
pp 2705 - 2710; DOI:
10.1021/ic00064a021
PDF
Alumatrane, Al(OCH2CH2)3N: a reinvestigation of its oligomeric behavior
Jiri Pinkas and John G. Verkade
pp 2711 - 2716; DOI:
10.1021/ic00064a022
PDF
Synthesis and characterization of platinum(II) complexes with adamantanamine derivatives and related ligands
Fernande D. Rochon, Monique Doyon, and Ian S. Butler
pp 2717 - 2723; DOI:
10.1021/ic00064a023
PDF
Heterobimetallic platinum-titanium complexes: potential anticancer drugs
M. Berardini, T. J. Emge, and J. G. Brennan
pp 2724 - 2728; DOI:
10.1021/ic00064a024
PDF
Vanadium(III)-.alpha.-amino acid homoleptic complexes from nonprotic solutions: reactions of [V(Mes)3(THF)] with .alpha.-amino acids and the structures of tris(L-prolinato)vanadium-dimethyl sulfoxide and tris(D-prolinato)vanadium-dimethyl sulfoxide
C. Philippe Magill, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli
pp 2729 - 2735; DOI:
10.1021/ic00064a025
PDF
Synthesis and characterization of cobalt cyclidene complexes with long polymethylene bridges and their binding to small molecules
Peter S. K. Chia, Mohamad Masarwa, P. Richard Warburton, Wei Wu, Masaaki Kojima, Dennis Nosco, Nathaniel W. Alcock, and Daryle H. Busch
pp 2736 - 2744; DOI:
10.1021/ic00064a026
PDF
Synthesis of III-V semiconductors by solid-state metathesis
Randolph E. Treece, Gerald S. Macala, Lin Rao, Deanna Franke, Hellmut Eckert, and Richard B. Kaner
pp 2745 - 2752; DOI:
10.1021/ic00064a027
PDF
Thermodynamic, kinetic, and structural study of the ligational properties of the macrobicyclic aza-ligand 4,7,10,17,23-pentamethyl-1,4,7,10,13,17,23-heptaazabicyclo[11.7.5]pentacosane (L1) and of its macrocyclic precursor 1,4,7,13-tetramethyl-1,4,7,10,13,16-hexaazacyclooctadecane (L2). Crystal structure of [Zn(L1)(H2O)](BPh4)2
Andrea Bencini, Antonio Bianchi, Paolo Dapporto, Vieri Fusi, Enrique Garcia-Espana, Mauro Micheloni, Piero Paoletti, Paola Paoli, Agustin Rodriguez, and Barbara Valtancoli
pp 2753 - 2760; DOI:
10.1021/ic00064a028
PDF
Syntheses, x-ray crystal structure analyses, and solid-state NMR studies of some zwitterionic organofluorosilicates
Reinhold Tacke, Joachim Becht, Angel Lopez-Mras, William S. Sheldrick, and Angelika Sebald
pp 2761 - 2766; DOI:
10.1021/ic00064a029
PDF
Synthesis and reactions of monomeric hydrazine and hydrazido complexes that contain the Cp*MoMe3 core
Michael G. Vale and Richard R. Schrock
pp 2767 - 2772; DOI:
10.1021/ic00064a030
PDF
Bulky ortho 3-methoxy groups on N4O3 amine phenol ligands producing six-coordinate bis(ligand)lanthanide complex cations [Ln(H3L)2]3+ (Ln = Pr, Gd; H3L = tris(((2-hydroxy-3-methoxybenzyl)amino)ethyl)amine)
Shuang Liu, Li Wei Yang, Steven J. Rettig, and Chris Orvig
pp 2773 - 2778; DOI:
10.1021/ic00064a031
PDF
A new cyclam with an NH2-pendant donor, 6-amino-1,4,8,11-tetraazacyclotetradecane, and its nickel(II) complexes
Eiichi Kimura, Makoto Haruta, Tohru Koike, Mitsuhiko Shionoya, Kazuya Takenouchi, and Yoichi Iitaka
pp 2779 - 2784; DOI:
10.1021/ic00064a032
PDF
Synthesis and x-ray crystal structure of a tetrahedral bismuth-molybdenum carbonyl complex possessing three bridging methoxy ligands, [Et4N]2[BiMo4(CO)12(.mu.3-OMe)3]
Minghuey Shieh, Fu Der Mia, Shie Ming Peng, and Gene Hsiang Lee
pp 2785 - 2787; DOI:
10.1021/ic00064a033
PDF
Quenching of dipolar and/or scalar connectivities in carbon-13-proton shift correlated 2D NMR spectra of paramagnetic metal complexes
Elena Gaggelli, Antonella Maccotta, and Gianni Valensin
pp 2788 - 2790; DOI:
10.1021/ic00064a034
PDF
Improved methods for the synthesis of bis(pentafluorosulfur)oxide and peroxide
Sun Hee Hwang, Kirit Naik, and Darryl D. DesMarteau
pp 2791 - 2792; DOI:
10.1021/ic00064a035
PDF
Editorial - Illustrated Synopsis for Articles and Notes

pp 2607 - 2607; DOI:
10.1021/ic00064a600
PDF

Issue 13


Synthesis and characterization of the cyclopentadienylcobalt trinuclear borohydride complex
Kathryn J. Deck, Thomas P. Fehlner, and Arnold L. Rheingold
pp 2794 - 2795; DOI:
10.1021/ic00065a001
PDF
Evidence for unusual rectangular pyramidal germanium(IV) anion
Maochun Ye and John G. Verkade
pp 2796 - 2797; DOI:
10.1021/ic00065a002
PDF
Prediction and interpretation of electronic spectra of transition metal complexes via the combination of molecular mechanics and angular overlap model calculations
Paul V. Bernhardt and Peter Comba
pp 2798 - 2803; DOI:
10.1021/ic00065a003
PDF
Complexation of cis-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine with the first row transition metal ions cobalt(III), chromium(III), and nickel(II)
Paul V. Bernhardt, Peter Comba, and Trevor W. Hambley
pp 2804 - 2809; DOI:
10.1021/ic00065a004
PDF
Monocomplex formation reactions of hexaaquaruthenium(II): a mechanistic study
Nicolas Aebischer, Gabor Laurenczy, Andreas Ludi, and Andre E. Merbach
pp 2810 - 2814; DOI:
10.1021/ic00065a005
PDF
Stereochemistry of thiocyanate photoanation in trans amminechlorobis(1,3-diaminopropane) chromium(2+)
A. D. Kirk and C. Namasivayam
pp 2815 - 2820; DOI:
10.1021/ic00065a006
PDF
Complexation of indium(III), gallium(III), iron(III), gadolinium(III), and neodymium(III) ions with amino diphosphonic acids in aqueous solution
James E. Bollinger and D. Max Roundhill
pp 2821 - 2826; DOI:
10.1021/ic00065a007
PDF
Investigation of the spectroscopic, electrochemical, and spectroelectrochemical properties of osmium(II) complexes incorporating polyazine bridging ligands: formation of the Os/Os and Os/Ru mixed-valence complexes
Mark M. Richter and Karen J. Brewer
pp 2827 - 2834; DOI:
10.1021/ic00065a008
PDF
Photoredox reactions of lead(IV) and -(II) hydroxo complexes
Alexander Becht and Arnd Vogler
pp 2835 - 2837; DOI:
10.1021/ic00065a009
PDF
Accurate empirical spin-orbit coupling parameters .zeta.nd for gaseous ndq transition metal ions. The parametrical multiplet term model
Jesper Bendix, Michael Brorson, and Claus E. Schaffer
pp 2838 - 2849; DOI:
10.1021/ic00065a010
PDF
Charge-transfer states of bridged transition metal dimers: mono- vs binuclear copper azide systems with relevance to oxy-hemocyanin
Felix Tuczek and Edward I. Solomon
pp 2850 - 2862; DOI:
10.1021/ic00065a011
PDF
Electrocatalytic oxidation by binuclear ruthenium complexes incorporating the anionic tripod ligand [(.eta.5-C5H5)Co{(CH3O)2P:O}3]-
Eric P. Kelson, Lawrence M. Henling, William P. Schaefer, Jay A. Labinger, and John E. Bercaw
pp 2863 - 2873; DOI:
10.1021/ic00065a012
PDF
Reactivity of (.eta.7-cycloheptatrienyl)(.eta.5-cyclopentadienyl)M (M = titanium, niobium) toward dithioacetic acid: preparation and characterization of (.eta.5-C5H5)Ti(S2CCH3)3 and (.eta.5-C5H5)Nb(.eta.2-S2)(S2CCH3)2
Maria T. Andras and Stan A. Duraj
pp 2874 - 2880; DOI:
10.1021/ic00065a013
PDF
A systematic approach in the preparation of compounds with .sigma.2.pi.4 vanadium-to-vanadium triple bonds: synthesis, reactivity, and structural characterization
F. Albert Cotton, Lee M. Daniels, and Carlos A. Murillo
pp 2881 - 2885; DOI:
10.1021/ic00065a014
PDF
Synthesis and structures of polar coordination polymers: [(SALEN)MnO2CCH2D-B:]n (D = NH, S; -B: = 4-pyridyl, 4-cyanophenyl)
William Chiang, Douglas M. Ho, Donna Van Engen, and Mark E. Thompson
pp 2886 - 2893; DOI:
10.1021/ic00065a015
PDF
Molecular hexanuclear clusters in the system rhenium-sulfur-chlorine: solid state synthesis, solution chemistry, and redox properties
Jean Christophe Gabriel, Kamal Boubekeur, and Patrick Batail
pp 2894 - 2900; DOI:
10.1021/ic00065a016
PDF
Structural characterization of low-spin iron(III) complexes of octaethyloxoporphyrin
Alan L. Balch, Bruce C. Noll, and Nasser Safari
pp 2901 - 2905; DOI:
10.1021/ic00065a017
PDF
Site-selective oxidative N-dealkylation in a cobalt(III) polyamine hydrolytic agent
Antonia M. Calafat and Luigi G. Marzilli
pp 2906 - 2911; DOI:
10.1021/ic00065a018
PDF
Synthesis, characterization, and crystal structure of the gadolinium(III) chelate of (1R,4R,7R)-.alpha.,.alpha.',.alpha.''-trimethyl-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid (DO3MA)
Sang I. Kang, Rama S. Ranganathan, John E. Emswiler, Krishan Kumar, Jack Z. Gougoutas, Mary F. Malley, and Michael F. Tweedle
pp 2912 - 2918; DOI:
10.1021/ic00065a019
PDF
Spectroscopic and photophysical studies of the binding interactions between copper phenanthroline complexes and RNA
Kelley A. Meadows, Fang Liu, Jenny Sou, Brian P. Hudson, and David R. McMillin
pp 2919 - 2923; DOI:
10.1021/ic00065a020
PDF
Hydrothermal synthesis and structure of molybdoarsenate [H4AsIII2AsVMoV8MoVI4O40]-, a bicapped, reduced Keggin species
M. Ishaque Khan, Qin Chen, and Jon Zubieta
pp 2924 - 2928; DOI:
10.1021/ic00065a021
PDF
Hydrothermal synthesis and characterization of hexavanadium polyoxo alkoxide anion clusters: crystal structures of the vanadium(IV) species Ba[V6O7(OH)3{(OCH2)3CCH3}3].3H2O and Na2[V6O7{(OCH2)3CCH2CH3}4], of the mixed-valence complex (Me3NH)[VIV5VVO7(OH)3{(OCH2)3CCH3}3], and of the fluoro derivative Na[V6O6F(OH)3{(OCH2)3CCH3}3].3H2O
M. Ishaque Khan, Qin Chen, Hakon Hope, Sean Parkin, Charles J. O'Connor, and Jon Zubieta
pp 2929 - 2937; DOI:
10.1021/ic00065a022
PDF
Dinuclear and tetranuclear copper(II) complexes of the tetradentate ligand 1,4-bis(2-pyridylthio)phthalazine: structural, magnetic, and electrochemical studies
Liqin Chen, Laurence K. Thompson, and John N. Bridson
pp 2938 - 2943; DOI:
10.1021/ic00065a023
PDF
Synthesis of cesium copper sulfide CsCuS6, and Cs6Cu2(TeS3)2(S6)2 in molten cesium sulfide telluride, Cs2SxTey, salts. Novel compounds containing polychalcogenide ligands
Timothy J. McCarthy, Xiang Zhang, and Mercouri G. Kanatzidis
pp 2944 - 2948; DOI:
10.1021/ic00065a024
PDF
Heterodinuclear copper(II)-lead(II) and copper(II)-M(II) (M = manganese, iron, cobalt, nickel, copper, zinc) complexes of macrocycles with dissimilar 4- and 5-coordination sites: synthesis, structures, and properties
Hisashi Okawa, Jun Nishio, Masaaki Ohba, Makoto Tadokoro, Naohide Matsumoto, Masayuki Koikawa, Sigeo Kida, and David E. Fenton
pp 2949 - 2957; DOI:
10.1021/ic00065a025
PDF
Isolation and structural characterization of mixed carbonyl-bis(dimethylphosphino)methane complexes of dirhenium(II)
Irene Ara, Phillip E. Fanwick, and Richard A. Walton
pp 2958 - 2962; DOI:
10.1021/ic00065a026
PDF
Metal-metal bonding in free and ligated nickel clusters
Notker Roesch, Lutz Ackermann, and Gianfranco Pacchioni
pp 2963 - 2964; DOI:
10.1021/ic00065a027
PDF
W(.eta.4-C4Ph4)(.eta.4-C4Ph4H)(.eta.2-CH3C(O)NH): a compound containing .eta.2(3e)-acetamido, .eta.4(4e)-cyclobutadiene, and .eta.4(5e)-butadienyl ligands
Wen Yann Yeh, Shie Ming Peng, and Ling Kang Liu
pp 2965 - 2967; DOI:
10.1021/ic00065a028
PDF
Kinetic investigation of phosphine exchange in CpFe(CO)(L)CH3 (L = PPh3, PPh2Me): rate of thermal formation of the 16-electron species CpFe(CO)CH3
William H. Hersh, Frederick Hunte, and Sondra Siegel
pp 2968 - 2971; DOI:
10.1021/ic00065a029
PDF
Synthesis and structural characterization of a homoleptic bismuth aryl thiolate
David A. Atwood, Alan H. Cowley, Robert D. Hernandez, Richard A. Jones, Lora L. Rand, Simon G. Bott, and Jerry L. Atwood
pp 2972 - 2974; DOI:
10.1021/ic00065a030
PDF
First example of a mixed-ligand bimetallic (Fe-Fe) N-bridged dimer: (.mu.-nitrido)[((tetraphenylporphyrinato)iron)(phthalocyaninato)iron]
C. Ercolani, S. Hewage, R. Heucher, and G. Rossi
pp 2975 - 2977; DOI:
10.1021/ic00065a031
PDF
A new vanadium(V) persulfide complex: (NEt4)[VO(S2)2(bpy)]
Stephanie L. Castro, James D. Martin, and George Christou
pp 2978 - 2980; DOI:
10.1021/ic00065a032
PDF
Editorial - Illustrated Synopses for Articles and Notes

pp 2793 - 2793; DOI:
10.1021/ic00065a600
PDF

Issue 14


Facile dehydrogenation of .alpha.-amino acids chelated to a bis(bipyridine)ruthenium(II) complex: (.alpha.-imino acidato)ruthenium(II) complexes
Motowo Yamaguchi and Takamichi Yamagishi
pp 2981 - 2982; DOI:
10.1021/ic00066a001
PDF
Reduction of a tetraaryldialane to generate aluminum-aluminum .pi.-bonding
Rudolf J. Wehmschulte, Karin Ruhlandt-Senge, Marilyn M. Olmstead, Hakon Hope, Bradley E. Sturgeon, and Philip P. Power
pp 2983 - 2984; DOI:
10.1021/ic00066a002
PDF
Novel coordination geometries in fluoroaluminate salts
Norman Herron, Richard L. Harlow, and David L. Thorn
pp 2985 - 2986; DOI:
10.1021/ic00066a003
PDF
Multifunctional macrocyclic ligands. Synthesis and characterization of nickel(II) and cobalt(II) macrocyclic-catechol complexes and their dimeric, antiferromagnetically coupled, semiquinone derivatives
Dimitri Coucouvanis, Sigridur G. Jonasdottir, Danae Christodoulou, Chang G. Kim, and Jeff W. Kampf
pp 2987 - 2988; DOI:
10.1021/ic00066a004
PDF
Topotactic polymerization of aniline in layered uranyl phosphate
Yu Ju Liu and Mercouri G. Kanatzidis
pp 2989 - 2991; DOI:
10.1021/ic00066a005
PDF
Gaseous complexes of cobalt dichloride with pyridine
Claude Daul, Franzpeter Emmenegger, Michael Mlinar, and Michel Piccand
pp 2992 - 2995; DOI:
10.1021/ic00066a006
PDF
Factors influencing the site of electroreduction in rhodium porphyrins
K. M. Kadish, Y. Hu, P. Tagliatesta, and T. Boschi
pp 2996 - 3002; DOI:
10.1021/ic00066a007
PDF
Electrochemical reduction of (2,2'-bipyridine)- and bis((2-pyridyl)pyrazine)ruthenium(II) complexes used as building blocks for supramolecular species. Redox series made of 8, 10, and 12 redox steps
Sergio Roffia, Massimo Marcaccio, Carmen Paradisi, Francesco Paolucci, Vincenzo Balzani, Gianfranco Denti, Scolastica Serroni, and Sebastiano Campagna
pp 3003 - 3009; DOI:
10.1021/ic00066a008
PDF
Structure of copper(II) ethylenediamine complexes in aqueous and neat ethylenediamine solutions and solvent-exchange kinetics of the copper(II) ion in ethylenediamine as studied by EXAFS and NMR methods
Yasuhiro Inada, Kazuhiko Ozutsumi, Shigenobu Funahashi, Sayo Soyama, Takuji Kawashima, and Motoharu Tanaka
pp 3010 - 3014; DOI:
10.1021/ic00066a009
PDF
Synthesis of ruthenium-phosphine complexes with heterodiene ligands
Olaf C. P. Beers, Michiel M. Bouman, Cornelis J. Elsevier, Wilberth J. J. Smeets, and Anthony L. Spek
pp 3015 - 3021; DOI:
10.1021/ic00066a010
PDF
Macrocyclic titanium thiolate metalloligands: complexation and thiolate-transfer reactions with copper(I), nickel(II), palladium(II)
Yujin Huang, Robert J. Drake, and Douglas W. Stephan
pp 3022 - 3028; DOI:
10.1021/ic00066a011
PDF
Structure determination, spectroscopic characterization, and magnetic properties of a novel dinuclear copper(II) crown ether bipyridine complex
Constantinus F. Martens, Albertus P. H. J. Schenning, Martinus C. Feiters, Jurgen Heck, Gezina Beurskens, Paul T. Beurskens, Erich Steinwender, and Roeland J. M. Nolte
pp 3029 - 3033; DOI:
10.1021/ic00066a012
PDF
Structural and magnetic characterization of alternating AB chains of composition [(Cat)2{MnIII(malonate)2(CH3OH)2][MnIII(malonate)2]}]n and (Cat)2[[MnIII(malonate)2(CH3OH)][MnIII(malonate)2]]n
Salman M. Saadeh, Kathleen L. Trojan, Jeff W. Kampf, William E. Hatfield, and Vincent L. Pecoraro
pp 3034 - 3040; DOI:
10.1021/ic00066a013
PDF
Synthesis, structure, and reactivity of polymetallic sodium and lanthanum 4-methylphenoxide complexes
William J. Evans, Robert E. Golden, and Joseph W. Ziller
pp 3041 - 3051; DOI:
10.1021/ic00066a014
PDF
Lead sequestering agents. 2. Synthesis of mono- and bis(hydroxypyridinethione) ligands and their lead complexes. Structure of bis(6-(diethylcarbamoyl)-1-hydroxy-2(1H)-pyridine-2-thionato-O,S)lead(II)
Kamal Abu-Dari, Timothy B. Karpishin, and Kenneth N. Raymond
pp 3052 - 3055; DOI:
10.1021/ic00066a015
PDF
Synthesis and structures of main group cage compounds containing boron, silicon, and phosphorus atoms
Danan Dou, Bernhard Kaufmann, Eileen N. Duesler, Tuqiang Chen, Robert T. Paine, and H. Noeth
pp 3056 - 3067; DOI:
10.1021/ic00066a016
PDF
Gold(I)-clustering at a primary arylphosphine with bulky substituents: [2,4,6-(Me3C)3C6H2P(AuPR3)n](n-2)+ (R = tert-Bu, Ph; n = 2-4) complexes and crystal structure of the species with n = 3 and R = phenyl
Edgar Zeller, Holger Beruda, Juergen Riede, and Hubert Schmidbaur
pp 3068 - 3071; DOI:
10.1021/ic00066a017
PDF
The synthesis and chemistry of icosahedral bis(phosphine)metalladiarsaboranes and -distibaboranes containing nickel and palladium. Crystal and molecular structures of closo-1,1-(Me2PPh)2-1,2,3-PdAs2B9H9, closo-1,6-Cl2-1,5-(Me2PPh)2-1,2,3-PdAs2B9H7.CH2Cl2, and closo-1,1-(Me2PPh)2-1,2,3-PdSb2B9H9
Steve A. Jasper, Steve Roach, John N. Stipp, J. C. Huffman, and Lee J. Todd
pp 3072 - 3080; DOI:
10.1021/ic00066a018
PDF
Synthesis and high-resolution optical spectroscopy of bis[2-(2-thienyl)pyridinato-C3,N'](2,2'-bipyridine)iridium(III)
Mirco G. Colombo and Hans U. Guedel
pp 3081 - 3087; DOI:
10.1021/ic00066a019
PDF
Evidence for strong mixing between the LC and MLCT excited states in bis(2-phenylpyridinato-C2,N')(2,2'-bipyridine)iridium(III)
Mirco G. Colombo, Andreas Hauser, and Hans U. Guedel
pp 3088 - 3092; DOI:
10.1021/ic00066a020
PDF
The interaction between carbon monoxide and yttrium barium copper oxide, YBa2Cu3Ox, as studied by TG/DTA, FTIR, and XPS
J. Lin, K. G. Neoh, N. Li, T. C. Tan, A. T. S. Wee, A. C. H. Huan, and K. L. Tan
pp 3093 - 3098; DOI:
10.1021/ic00066a021
PDF
Magnetic properties of an octanuclear iron(III) cation
C. Delfs, D. Gatteschi, L. Pardi, R. Sessoli, K. Wieghardt, and D. Hanke
pp 3099 - 3103; DOI:
10.1021/ic00066a022
PDF
Molecular structure of imidazolate-bridged binuclear zinc complex and its single-crystal ESR spectra doped with bridged copper-zinc complex
Z. W. Mao, K. B. Yu, D. Chen, S. Y. Han, Y. X. Sui, and W. X. Tang
pp 3104 - 3108; DOI:
10.1021/ic00066a023
PDF
Insulin mimetic peroxovanadium complexes: preparation and structure of potassium oxodiperoxo(pyridine-2-carboxylato)vanadate(V), K2[VO(O2)2(C5H4NCOO)].2H2O, and potassium oxodiperoxo(3-hydroxypyridine-2-carboxylato)vanadate(V), K2[VO(O2)2(OHC5H3NCOO)].3H2O, and their reactions with cysteine
Alan Shaver, Jesse B. Ng, David A. Hall, Bernadette Soo Lum, and Barry I. Posner
pp 3109 - 3113; DOI:
10.1021/ic00066a024
PDF
Synthesis and characterization of neutral MVO (M = technetium, rhenium) amine-thiol complexes containing a pendant phenylpiperidine group
L. C. Francesconi, G. Graczyk, S. Wehrli, S. N. Shaikh, D. McClinton, S. Liu, J. Zubieta, and H. F. Kung
pp 3114 - 3124; DOI:
10.1021/ic00066a025
PDF
Reaction of 2,2'-bipyridine (bpy) with dirhodium carboxylates: mono-bpy products with variable chelate binding modes and insights into the reaction mechanism
Charles A. Crawford, John H. Matonic, William E. Streib, John C. Huffman, Kim R. Dunbar, and George Christou
pp 3125 - 3133; DOI:
10.1021/ic00066a026
PDF
Aggregation properties of nitroporphyrins: comparisons between solid-state and solution structures
Mathias O. Senge, Charles W. Eigenbrot, Theodore D. Brennan, Janine Shusta, W. Robert Scheidt, and Kevin M. Smith
pp 3134 - 3142; DOI:
10.1021/ic00066a027
PDF
Oxidation reactions of a macrocyclic dinuclear copper(I) dioxygen complex and a dinuclear copper(II) complex
David A. Rockcliffe and Arthur E. Martell
pp 3143 - 3152; DOI:
10.1021/ic00066a028
PDF
Raman spectroscopic characterization of isomers of copper and zinc N-phenylprotoporphyrin IX dimethyl esters
Laurie D. Sparks, James R. Chamberlain, Pam Hsu, Mark R. Ondrias, Barbara A. Swanson, Paul R. Ortiz de Montellano, and John A. Shelnutt
pp 3153 - 3161; DOI:
10.1021/ic00066a029
PDF
Reaction of hydrogen peroxide with the oxochromium(IV) ion by hydride transfer
Ahmad M. Al-Ajlouni, James H. Espenson, and Andreja Bakac
pp 3162 - 3165; DOI:
10.1021/ic00066a030
PDF
Bridging of platinacycles by cis-azobenzenes: synthesis and photochemical study. Structure of the twisted inorganic Z-1,1,2,2-tetrasubstituted diazaethene [(Z)-1,2-diphenyldiazaethene)bis[chloro(((dimethylamino)methyl)phenyl-C,N)platinum(II)]
Alexander D. Ryabov, Ludmila G. Kuz'mina, Natalia V. Dvortsova, Derk J. Stufkens, and Rudi van Eldik
pp 3166 - 3174; DOI:
10.1021/ic00066a031
PDF
Synthesis and structural characterization of lanthanide(III) texaphyrins
Jonathan L. Sessler, Tarak D. Mody, Gregory W. Hemmi, and Vincent Lynch
pp 3175 - 3187; DOI:
10.1021/ic00066a032
PDF
Cobaltocenium metallacarboranide mixed-sandwich salts, Cp2Co+(Et2C2B4H4)2M- (M = CoIII, ironIII) and Cp2Co+(Et2C2B3H4-X)CoIII(Et2C2B4H4)- (X = H, Me)
Xiangsheng Meng, Simon Waterworth, Michal Sabat, and Russell N. Grimes
pp 3188 - 3192; DOI:
10.1021/ic00066a033
PDF
Crystal structure and NMR characterization of the unexpected product of oxidation of the palladium(I), .eta.3-phosphallyl complex [(Ph2PCHCH2)(.mu.-.eta.3-Ph2PCHCH2)PdI]2(BF4)2 with iodine: bis(.mu.-iodo)bis[iodo(diphenylvinylphosphine)palladium(II)]
Nathaniel W. Alcock, William L. Wilson, and John H. Nelson
pp 3193 - 3195; DOI:
10.1021/ic00066a034
PDF
Kinetic studies of chloride displacement from oxo-bridged chromium(III)tris(2-pyridylmethyl)amine complex ([Cr(tmpa)Cl]2O2+) in aqueous solution
Thomas F. Tekut and Robert A. Holwerda
pp 3196 - 3198; DOI:
10.1021/ic00066a035
PDF
Di- and trinuclear complexes with sulfide-bridged rhenium in very different oxidation states (ReIReVII, ReIReVIReI, ReIReVIIReI). The d0/d1 transition in tetrathiometalates
Roland Schaefer, Wolfang Kaim, and Jan Fiedler
pp 3199 - 3200; DOI:
10.1021/ic00066a036
PDF

Issue 15


Synthesis and structural characterization of the telluroargentate [PPh4]2[NEt4][AgTe7] and telluromercurate [PPh4]2[HgTe7] compounds containing the unprecedented .eta.3-Te74- polytelluride anion
Jonathan M. McConnachie, Mohammad A. Ansari, John C. Bollinger, Robert J. Salm, and James A. Ibers
pp 3201 - 3202; DOI:
10.1021/ic00067a001
PDF
Tetrahedral gold cluster [Au4]2+: crystal structure of {[(tert-Bu)3PAu]4}2+(BF4-)2.2CHCl3
Edgar Zeller, Holger Beruda, and Hubert Schmidbaur
pp 3203 - 3204; DOI:
10.1021/ic00067a002
PDF
Reactions of bis(trifluoromethyl)sulfoxy difluoride with nitrogen or oxygen nucleophiles
Arun Sandhu, Gary L. Gard, Nimesh R. Patel, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 3205 - 3208; DOI:
10.1021/ic00067a003
PDF
Rigorous interpretation of electronic wave functions. 2. Electronic structures of selected phosphorus, sulfur, and chlorine fluorides and oxides
Jerzy Cioslowski and Stacey T. Mixon
pp 3209 - 3216; DOI:
10.1021/ic00067a004
PDF
DNA-porphyrin adducts. Five-coordination of DNA-bound VOTMpyP(4) in an aqueous environment: new perspectives on the V=O stretching frequency and DNA intercalation
Mengfen Lin, Minghe Lee, Kwok To Yue, and Luigi G. Marzilli
pp 3217 - 3226; DOI:
10.1021/ic00067a005
PDF
Monomeric Group IIA metal .beta.-diketonates stabilized by multidentate glymes
Simon R. Drake, Stewart A. S. Miller, and David J. Williams
pp 3227 - 3235; DOI:
10.1021/ic00067a006
PDF
Solid-state phosphorus-31 NMR and structural studies on copper(I) complexes of tetradentate-N2P2 ligands
Bernhard Mohr, Johannes Schmidt, Elwood E. Brooks, Mary Jane Heeg, Douglas M. Ho, and Edward Deutsch
pp 3236 - 3240; DOI:
10.1021/ic00067a007
PDF
Structure and bonding of pentaaquanitrosylchromium(2+) sulfate
Michael Ardon and Shmuel Cohen
pp 3241 - 3243; DOI:
10.1021/ic00067a008
PDF
Preparation and phosphorus-31 and selenium-77 NMR spectra of platinum and palladium complexes of a P2N4Se2 ring
Tristram Chivers, Daniel D. Doxsee, and Robert W. Hilts
pp 3244 - 3249; DOI:
10.1021/ic00067a009
PDF
Monomeric selenopalladates and selenoplatinates
Jonathan M. McConnachie, Mohammad A. Ansari, and James A. Ibers
pp 3250 - 3255; DOI:
10.1021/ic00067a010
PDF
X-ray structural and imidazole-binding studies of nickel .beta.-oxoporphyrins
Patricia A. Connick, Kenneth J. Haller, and Kathleen A. Macor
pp 3256 - 3264; DOI:
10.1021/ic00067a011
PDF
A study of high-valent manganese in aqueous phosphoric acid: disproportionation of the bis(.mu.-oxo)dimanganese(III,IV) bipyridine complex [MnIIIMnIV(.mu.-O)2(bpy)4]3+
Joseph E. Sarneski, Linda J. Brzezinski, Brandon Anderson, Mary Didiuk, Rajesh Manchanda, Robert H. Crabtree, Gary W. Brudvig, and Gayle K. Schulte
pp 3265 - 3269; DOI:
10.1021/ic00067a012
PDF
Synthesis and NMR T1 relaxation study of rhenium and manganese hydride complexes
Dmitry G. Gusev, Daniel Nietlispach, Alexey B. Vymenits, Vladimir I. Bakhmutov, and Heinz Berke
pp 3270 - 3276; DOI:
10.1021/ic00067a013
PDF
Iron-iridium mixed-metal carbonyl clusters. 4. Synthesis, characterization, and chemical behavior of [FeIr4(CO)13]2- and [Fe2Ir4(CO)16]2-. Solid-state structures of [PPh4]2[FeIr4(CO)13].C4H8O and [NEt4][NMe3(CH2Ph)][Fe2Ir4(CO)16]
Roberto Della Pergola, Alessandro Ceriotti, Luigi Garlaschelli, Francesco Demartin, Mario Manassero, Norberto Masciocchi, and Mirella Sansoni
pp 3277 - 3281; DOI:
10.1021/ic00067a014
PDF
Ligand effects on heats of protonation of multihydrido-transition metal complexes of osmium and iridium
Mary K. Rottink and Robert J. Angelici
pp 3282 - 3286; DOI:
10.1021/ic00067a015
PDF
Binuclear rhodium hydride complexes: synthesis, structure, and reactivity
Faisal Shafiq and Richard Eisenberg
pp 3287 - 3294; DOI:
10.1021/ic00067a016
PDF
Lead(II)/platinum(II) complexes with and without Pb-Pt interactions
Alan L. Balch, Ella Y. Fung, Jeffrey K. Nagle, Marilyn M. Olmstead, and Stephen P. Rowley
pp 3295 - 3299; DOI:
10.1021/ic00067a017
PDF
Syntheses and characterization of the new homoleptic indium-polysulfide complexes [In2S27]4-, [In2S14]2-, and [In2S16]2-
Sandeep S. Dhingra and Mercouri G. Kanatzidis
pp 3300 - 3305; DOI:
10.1021/ic00067a018
PDF
Complexes of lanthanoid salts with macrocyclic ligands. 41. Photophysical properties of lanthanide dinuclear complexes with p-tert-butylcalix[8]arene
Jean Claude G. Bunzli, Pascal Froidevaux, and Jack M. Harrowfield
pp 3306 - 3311; DOI:
10.1021/ic00067a019
PDF
Angular overlap interpretation of the spectromagnetic properties of the nitrate derivative of cobalt(II)-substituted carbonic anhydrase
Alessandro Bencini, Ivano Bertini, and Tiziano Bini
pp 3312 - 3315; DOI:
10.1021/ic00067a020
PDF
Protonation nitrogen shielding and NOE in aqueous nitrite and solid-state nitrogen-15 NMR of nitrosyl and nitryl tetrafluoroborate
Younghee Ko, Francis T. Bonner, George B. Crull, and Gerard S. Harbison
pp 3316 - 3319; DOI:
10.1021/ic00067a021
PDF
Stabilities of divalent and trivalent metal ion complexes of macrocyclic triazatriacetic acids
Rita Delgado, Yizhen Sun, Ramunas J. Motekaitis, and Arthur E. Martell
pp 3320 - 3326; DOI:
10.1021/ic00067a022
PDF
Kinetics and mechanism of the complexation of cis-diamminedichloroplatinum(II) with the purine nucleoside inosine in aqueous solution
Jorma Arpalahti, Marjaana Mikola, and Sari Mauristo
pp 3327 - 3332; DOI:
10.1021/ic00067a023
PDF
Oxygen atom transfer between cis-coordinated nitrite and nitrosyl ligands: The case of the CpCr(NO)2(NO2)/CpCr(NO)2(ONO) linkage isomers
John L. Hubbard, Christopher R. Zoch, and Wendy L. Elcesser
pp 3333 - 3338; DOI:
10.1021/ic00067a024
PDF
Complex-formation kinetics of iron(III) with chlorite ion in aqueous solution. Mechanistic information from pressure effects
Istvan Fabian and Rudi van Eldik
pp 3339 - 3342; DOI:
10.1021/ic00067a025
PDF
Synthesis, characterization, and molecular structures of supermesitylgallium- and supermesitylindium dihalides
Stephan Schulz, Stefan Pusch, Ehmke Pohl, Sven Dielkus, Regine Herbst-Irmer, Anton Meller, and Herbert W. Roesky
pp 3343 - 3346; DOI:
10.1021/ic00067a026
PDF
Stereoselective isomerization in organoiridium(III) complexes induced by the presence of rigid C,N chelating ligands
Ingrid C. M. Wehman-Ooyevaar, Wiendelt Drenth, David M. Grove, and Gerard van Koten
pp 3347 - 3356; DOI:
10.1021/ic00067a027
PDF
Synthesis and dynamic properties of kinetically inert lanthanide compounds: lanthanum(III) and europium(III) complexes of 1,4,7,10-tetrakis(2-hydroxyethyl)-1,4,7,10-tetraazacyclododecane
Janet R. Morrow and K. O. Aileen Chin
pp 3357 - 3361; DOI:
10.1021/ic00067a028
PDF
2,2'-Azobis(pyridine) (abpy) as a multiply reducible tetradentate ligand. EPR evidence for the configurational dependence of intramolecular electron transfer in the stereoisomeric tris-chelate ruthenium complexes [Ru(abpy)n(bpy)3-n]m (n = 2, 3; m = 2+ to 3-)
Michael Krejcik, Stanislav Zalis, Jiri Klima, David Sykora, Walter Matheis, Axel Klein, and Wolfgang Kaim
pp 3362 - 3368; DOI:
10.1021/ic00067a029
PDF
Synthesis of some 10-, 11-, and 12-atom phosphaboranes. Crystal structure of 2-(trimethylamine)-1-PB11H10
John L. Little, Michael A. Whitesell, Robert W. Chapman, John G. Kester, John C. Huffman, and Lee J. Todd
pp 3369 - 3372; DOI:
10.1021/ic00067a030
PDF
Reactivity of the methylcyclopentadienylmanganese cyanometalate Na[Cp'Mn(CO)2CN] with titanium, zirconium, and hafnium halides. Crystal and molecular structure of the .mu.-cyano .mu.-oxo tetranuclear complex [Cp2Zr{(.mu.-NC)MnCp'(CO)2}]2(.mu.-O) (Cp = .eta.-C5H5; Cp' = .eta.-MeC5H4)
Pierre Braunstein, Daniele Cauzzi, David Kelly, Maurizio Lanfranchi, and Antonio Tiripicchio
pp 3373 - 3377; DOI:
10.1021/ic00067a031
PDF
A tetranuclear rhomblike cluster of manganese(II). Crystal structure and magnetic properties of the heteropoly complex K10[Mn4(H2O)2(PW9O34)2].cntdot.20H2O
C. J. Gomez-Garcia, E. Coronado, P. Gomez-Romero, and N. Casan-Pastor
pp 3378 - 3381; DOI:
10.1021/ic00067a032
PDF
Synthesis and crystal structure of the gold-carborane anion [11-endo-{Au(PPh3)}-7,9-Me2-nido-7,9-C2B10H10]-
John C. Jeffery, Paul A. Jelliss, and F. Gordon A. Stone
pp 3382 - 3384; DOI:
10.1021/ic00067a033
PDF
The copper(I) complex of a metallocyclam-functionalized phenanthroline: a poorly stable species that is very resistant to oxidation
Giancarlo De Santis, Luigi Fabbrizzi, Maurizio Licchelli, Carlo Mangano, and Piersandro Pallavicini
pp 3385 - 3387; DOI:
10.1021/ic00067a034
PDF
Preparation and characterization of iron complexes of the penta-p-tolylcyclopentadienyl and o-tolyltetraphenylcyclopentadienyl ligands. [Erratum to document cited in CA118(13):124740r]
Leslie D. Field, Anthony F. Masters, Michelle Gibson, Devin R. Latimer, Trevor W. Hambley, and Irmi E. Buys
pp 3388 - 3388; DOI:
10.1021/ic00067a035
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Issue 16


An unusual mixed tellurium-iron carbonylate: synthesis, structure, and reactivity of [PhCH2NMe3]2[Te6Fe8(CO)24]
Minghuey Shieh, Pao Fei Chen, Shie Ming Peng, and Gene Hsiang Lee
pp 3389 - 3390; DOI:
10.1021/ic00068a001
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Preparation and structures of the osmaborides boridohexadecacarbonylhydridopentaosmium and (dihydroborato)dodecacarbonylhydridotetraosmium
Jang Hoon Chung, David Knoeppel, Deborah McCarthy, Anne Columbie, and Sheldon G. Shore
pp 3391 - 3392; DOI:
10.1021/ic00068a002
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Facile conversion of the dimeric [{Ph3PRhB10H10CNH2}2H]-[PPN]+ cluster to 16-electron mononuclear closo-rhodacarboranes by N-quaternization
Igor T. Chizhevsky, Irina V. Pisareva, Pavel V. Petrovskii, Vladimir I. Bregadze, Alexandr I. Yanovsky, Yuri T. Struchkov, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 3393 - 3394; DOI:
10.1021/ic00068a003
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Preparation and molecular structure of the first structurally characterized MABCDEF octahedral dimer, [Cl(CO)(PPh3)(.eta.2-MeC2Me)Mo(.mu.-SCN)(.mu.-NCS)MoCl(CO)(PPh3)(.eta.2-MeC2Me)]
Paul K. Baker, Mary E. Harman, Dafydd ap Kendrick, and Michael B. Hursthouse
pp 3395 - 3396; DOI:
10.1021/ic00068a004
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The compressed tetragonal hexafluorocuprate(4-) (CuF64-) complex in potassium aluminum copper fluoride (KAlCuF6): an angular overlap treatment of the electronic structure and magnetic exchange coupling
Michail Atanasov, Michael A. Hitchman, Rudolf Hoppe, Keith S. Murray, Boujemaa Moubaraki, Dirk Reinen, and Horst Stratemeier
pp 3397 - 3401; DOI:
10.1021/ic00068a005
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Electronic structure and spectroscopy of luminescent heterobimetallic platinum(II)-rhodium(I), gold(I)-Rh(I), and silver(I)-Rh(I) complexes
Hon Kay Yip, Hsiu Mei Lin, Yu Wang, and Chi Ming Che
pp 3402 - 3407; DOI:
10.1021/ic00068a006
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Electrospray mass spectrometric study of [M3O(RCOO)6L3]+ cations (M = chromium, iron; L = H2O, MeOH, py)
Adrian van den Bergen, Ray Colton, Matthew Percy, and Bruce O. West
pp 3408 - 3411; DOI:
10.1021/ic00068a007
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Kinetics of the heterolysis of benzyl and cyanobenzyl complexes of pentaaquachromium(III) in acetate and phosphate buffers
Zhongsheng Zhang and R. B. Jordan
pp 3412 - 3417; DOI:
10.1021/ic00068a008
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Interaction of hexaazaalkanes with phosphate type anions. Thermodynamic, kinetic, and electrochemical considerations
Antonio Andres, Juan Arago, Andrea Bencini, Antonio Bianchi, Antonio Domenech, Vieri Fusi, Enrique Garcia-Espana, Piero Paoletti, and Jose A. Ramirez
pp 3418 - 3424; DOI:
10.1021/ic00068a009
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Kinetics and mechanism of ligand substitution reactions of pentacyanoferrate(II) complexes with bridging N-heterocyclic dications in aqueous media
Daniel A. Foucher, Donal H. Macartney, Lauren J. Warrack, and John P. Wilson
pp 3425 - 3432; DOI:
10.1021/ic00068a010
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Oxidation of ruthenium(II) tris(2,2'-bipyridine) ions by thallic ions in nitric acid, mediated by ruthenium dioxide hydrate: an example of reversible heterogeneous redox catalysis
Andrew Mills and Grant Meadows
pp 3433 - 3437; DOI:
10.1021/ic00068a011
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Application of a universal force field to metal complexes
A. K. Rappe, K. S. Colwell, and C. J. Casewit
pp 3438 - 3450; DOI:
10.1021/ic00068a012
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Structural investigation into the steric control of polyether complexation in the lanthanide series: macrocyclic 18-crown-6 versus acyclic pentaethylene glycol
Robin D. Rogers, Andrew N. Rollins, Russell D. Etzenhouser, Eric J. Voss, and Cary B. Bauer
pp 3451 - 3462; DOI:
10.1021/ic00068a013
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Doubly-hydrated hexafluoroacetylacetone as a tetradentate ligand: synthesis, magnetochemistry, and thermal transformations of a dimanganese(III) complex
Elisabeth Bouwman, Kenneth G. Caulton, George Christou, Kirsten Folting, Christophe Gasser, David N. Hendrickson, John C. Huffman, Emil B. Lobkovsky, James D. Martin, and et al.
pp 3463 - 3470; DOI:
10.1021/ic00068a014
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Hydrotris(3-mesitylpyrazol-1-yl)borate and hydrobis(3-mesitylpyrazol-1-yl)(5-mesitylpyrazol-1-yl)borate: symmetric and asymmetric ligands with rotationally restricted aryl substituents
Arnold L. Rheingold, Corbet B. White, and Swiatoslaw Trofimenko
pp 3471 - 3477; DOI:
10.1021/ic00068a015
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Synthesis and characterization of the monomeric three-coordinate indium thiolate and selenolate complexes In[E(2,4,6-tert-Bu3C6H2)]3 (E = S, Se)
K. Ruhlandt-Senge and P. P. Power
pp 3478 - 3481; DOI:
10.1021/ic00068a016
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Mixed-donor and monomeric N-donor adducts of alane
Jerry L. Atwood, Kirk W. Butz, Michael G. Gardiner, Cameron Jones, George A. Koutsantonis, Colin L. Raston, and Kerry D. Robinson
pp 3482 - 3487; DOI:
10.1021/ic00068a017
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Hybrid ligands. A new route to (carbamoylmethyl)phosphines. Molecular structure of [(o-C6H4CH2NMe2)Pd{Ph2P-cyclo-C=C(O)N(Ph)N=C(Me)}]
Dominique Matt, Nohma Sutter-Beydoun, Jean Pierre Brunette, Fadila Balegroune, and Daniel Grandjean
pp 3488 - 3492; DOI:
10.1021/ic00068a018
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Structure and stereodynamics of iron carbonyl phosphine or arsine Fe(CO)4L complexes (L = P(o-tolyl)3, As(o-tolyl)3, P(o-tolyl)2CH2Ph, (o-tolyl)2PP(o-tolyl)2)
James A. S. Howell, Michael G. Palin, Patrick McArdle, Desmond Cunningham, Zeev Goldschmidt, Hugo E. Gottlieb, and Daphna Hezroni-Langerman
pp 3493 - 3500; DOI:
10.1021/ic00068a019
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Synthesis, characterization, and crystal structures of M(DO3A) (M = iron, gadolinium) and Na[M(DOTA)] (M = Fe, yttrium, Gd)
C. Allen Chang, Lynn C. Francesconi, Mary F. Malley, Krishan Kumar, Jack Z. Gougoutas, Michael F. Tweedle, Daniel W. Lee, and Lon J. Wilson
pp 3501 - 3508; DOI:
10.1021/ic00068a020
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The tetrachloroplatinate(2-)/thiamin system. 2. Structure of trans-[Pt(dmso-S)(thiamin)Cl2](Ph4B) and its equilibria in dmso
Roger E. Cramer and Michel J. J. Carrie
pp 3509 - 3515; DOI:
10.1021/ic00068a021
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1,10-Phenanthroline-linked Escherichia coli Trp repressor as a site-specific scission reagent. Metal ion requirement
Abhijit Mazumder, Christopher L. Sutton, and David S. Sigman
pp 3516 - 3520; DOI:
10.1021/ic00068a022
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Electrochemistry in liquid sulfur dioxide. 12. Electrochemical and pulse radiolysis studies on oxidation of tris(2,2'-bipyridine)zinc(2+), tris(2,2'-bipyridine)cadmium(2+) and 2,2'-bipyridine
Jerzy B. Chlistunoff and Allen J. Bard
pp 3521 - 3527; DOI:
10.1021/ic00068a023
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Electrochemistry of metallocenes at very negative and very positive potentials. Electrogeneration of 17-electron Cp2Co2+, 21-electron Cp2Co2-, and 22-electron Cp2Ni2- species
Allen J. Bard, Edwin Garcia, S. Kukharenko, and Vladimir V. Strelets
pp 3528 - 3531; DOI:
10.1021/ic00068a024
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The lanthanum-germanium system. Nineteen isostructural interstitial compounds of the La5Ge3 host
Arnold M. Guloy and John D. Corbett
pp 3532 - 3540; DOI:
10.1021/ic00068a025
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Synthesis, structure, and properties of a dimolybdenum N,N-dimethylethylenediamine trifluoroacetate complex [Mo2(O2CCF3)3(udmed)2](O2CCF3)
Kevin J. Snowden, Thomas R. Webb, and Brian Snoddy
pp 3541 - 3545; DOI:
10.1021/ic00068a026
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Synthesis of high-purity phthalocyanines (pc): high intrinsic conductivities in the molecular conductors H2(pc)I and Ni(pc)I
Julia A. Thompson, Kazuhiko Murata, Douglas C. Miller, Judith L. Stanton, William E. Broderick, Brian M. Hoffman, and James A. Ibers
pp 3546 - 3553; DOI:
10.1021/ic00068a027
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Pressure-induced temperature dependence of a weak exchange coupling in dichlorobis(1-phenyl-3,5-dimethylpyrazole)copper(II) crystals
S. K. Hoffmann, J. Goslar, W. Hilczer, and M. Krupski
pp 3554 - 3556; DOI:
10.1021/ic00068a028
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New antiferromagnetic dinuclear complexes of nickel(II) with two azides as bridging ligands. Magneto-structural correlations
Joan Ribas, Montserrat Monfort, Carmen Diaz, Carles Bastos, and Xavier Solans
pp 3557 - 3561; DOI:
10.1021/ic00068a029
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Synthesis of dinickel(I) and dinickel(II) complexes of bismacrocyclic ligands
Myunghyun Paik Suh and Sung Kwon Kim
pp 3562 - 3564; DOI:
10.1021/ic00068a030
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Syntheses and structures of the seven-coordinate molybdenum carbonyl complexes containing both dithiocarbamate and the uninegative nitrogen-tripod ligand
Kom Bei Shiu, Jean Y. Lee, Yu Wang, and Ming Chu Cheng
pp 3565 - 3567; DOI:
10.1021/ic00068a031
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1-(Pentafluoro-.lambda.6-sulfanyl)-2,2,2-trifluoroethanethione, F5S(F3C)C:S, and related compounds
Raimund Kuschel and Konrad Seppelt
pp 3568 - 3569; DOI:
10.1021/ic00068a032
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Photochemical dealkylation of the bridging phosphite-type ligand (iso-PrO)2PN(Et)P(OPr-iso)2 in the electronically unsaturated diruthenium complex [Ru2(.mu.sb-CO)2(CO)2{.mu.-(iso-PrO)2PN(Et)P(OPr-iso)2}2]
Robert M. Granger, Phillip E. Fanwick, Raymond J. Haines, and Clifford P. Kubiak
pp 3570 - 3572; DOI:
10.1021/ic00068a033
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X-ray structure and solution characterization of tetracarbonylmolybdenumbis(.mu.-diphenylphosphinoethanethiolato)nickel (Ni(.mu.-SCH2CH2PPh2)2Mo(CO)4)
Stephen S. Chojnacki, Yui May Hsiao, Marcetta Y. Darensbourg, and Joseph H. Reibenspies
pp 3573 - 3576; DOI:
10.1021/ic00068a034
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Issue 17


Structural characterization of {(.eta.2-C60)RhH(CO)(PPh3)2}: product of the reaction of fullerene C60 with the hydrogenation catalyst carbonylhydridotris(triphenylphosphine)rhodium
Alan L. Balch, Joong W. Lee, Bruce C. Noll, and Marilyn M. Olmstead
pp 3577 - 3578; DOI:
10.1021/ic00069a001
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Geometric families of giant fullerenes
John S. Rutherford
pp 3579 - 3580; DOI:
10.1021/ic00069a002
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Effect of donors and acceptors on the twist angle of a ruthenium complex of bis(bipyridine)ruthenium(II) 3,4-diamino-3',4'-diimino-3',4'-dihydrobiphenyl. A bifunctional biphenyl derivative and a potential molecular switch
Robert A. Metcalfe, Elaine S. Dodsworth, A. B. P. Lever, William J. Pietro, and Derk J. Stufkens
pp 3581 - 3582; DOI:
10.1021/ic00069a003
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Novel formation of a linear trinuclear ferric complex containing a .mu.-oxo bis(.mu.-acetato) and a .mu.-hydroxo bis(.mu.-acetato) bridge
Nobumasa Kitajima, Hironobu Amagai, Nobuchika Tamura, Masami Ito, Yoshihiko Morooka, Kristel Heerwegh, Alain Penicaud, Rajeev Mathur, Christopher A. Reed, and Peter D. W. Boyd
pp 3583 - 3584; DOI:
10.1021/ic00069a004
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Selective catalytic hydrolysis of a simple phosphodiester by a macrocyclic copper(II) complex
Judith N. Burstyn and Kim A. Deal
pp 3585 - 3586; DOI:
10.1021/ic00069a005
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COSY and NOESY characterization of cobalt(II)-substituted azurin from Pseudomonas aeruginosa
Jose Maria Moratal, Jesus Salgado, Antonio Donaire, Hermas R. Jimenez, and Josep Castells
pp 3587 - 3588; DOI:
10.1021/ic00069a006
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Structural and magnetic consequences of protonation of the oxo bridge in bis(hydridotripyrazolylborato)(.mu.-oxo)bis(.mu.-carboxylato)divanadium complexes
Carl J. Carrano, Ruben Verastgue, and Marcus R. Bond
pp 3589 - 3590; DOI:
10.1021/ic00069a007
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Macrocyclic catechol complexes as ligands in the synthesis of heterometallic supramolecules
Sigridur G. Jonasdottir, Chang G. Kim, and Dimitri Coucouvanis
pp 3591 - 3592; DOI:
10.1021/ic00069a008
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Oxidative charge storage on an oxomanganese(IV) dimer containing a bis(.mu.-oxo)mono(.mu.-carboxylato) bridge and two coordinated water molecules: [Mn2O2(O2CCH3)(H2O)2(bpy)2](ClO4)3
Bakul C. Dave, Roman S. Czernuszewicz, Marcus R. Bond, and Carl J. Carrano
pp 3593 - 3594; DOI:
10.1021/ic00069a009
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Gas-phase reactions of iron(benzyne)+ [.eta.6-1,3-cyclohexadien-5-yne)iron(1+)] with simple alkyl halides
Edna Garcia, Yongqing Huang, and Ben S. Freiser
pp 3595 - 3600; DOI:
10.1021/ic00069a010
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Electrochemical oxidation of nickel-phosphine complexes of the type [NiII(.eta.5-C5Ph5){Ph2PCH:C(O)R}] (R = Ph, ferrocenyl). Direct and indirect generation of nickel(III) and nickel(II)-cation radical species
A. Louati and M. Huhn
pp 3601 - 3607; DOI:
10.1021/ic00069a011
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Dinuclear titanium metallocene-type complexes with the bridging (dimethylsilylidene)bis(cyclopentadienyl) ligand. X-ray structures of [{TiCl2(.eta.5-C5Me5)}2{.mu.-.eta.5-.eta.5-(C5H4)2SiMe2}] and of [{TiCl(.eta.5-C5H5)}2(.mu.-O){.mu.-.eta.5-.eta.5-(C5H4)2SiMe2}]
Tomas Cuenca, Juan Carlos Flores, Rafael Gomez, Pilar Gomez-Sal, Miguel Parra-Hake, and Pascual Royo
pp 3608 - 3612; DOI:
10.1021/ic00069a012
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Heterodinuclear bis(diphenylphosphino)methane-bridged molybdenum(d6)-palladium(d8) complexes with dative Mo.fwdarw.Pd bonding
Alan L. Balch, Bruce C. Noll, Marilyn M. Olmstead, and Dawn V. Toronto
pp 3613 - 3619; DOI:
10.1021/ic00069a013
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Edge-sharing bioctahedral dimolybdenum and dirhenium compounds with polydentate phosphines
F. Albert Cotton, Bo Hong, Maoyu Shang, and George G. Stanley
pp 3620 - 3627; DOI:
10.1021/ic00069a014
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Structure and solution behavior of a series of classical and nonclassical rhenium hydride complexes
Dmitry G. Gusev, Daniel Nietlispach, Igor L. Eremenko, and Heinz Berke
pp 3628 - 3636; DOI:
10.1021/ic00069a015
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Bridging methylene addition to the disulfur ligands of an iron-sulfur cluster compound. X-ray structure of [Fe4(.mu.3-S)2((.mu.3-S2)CH2(.mu.3-S2))(C5H4Me)4]2+ (FeCl4)2-
Wouter van den Berg, Johannes G. M. van der Linden, Bart A. van Riessen, Bas de Bruin, Wil P. Bosman, Jan M. M. Smits, and Paul T. Beurskens
pp 3637 - 3639; DOI:
10.1021/ic00069a016
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Reactions of monoazadienes with metal carbonyl complexes. 17. Photochemically induced reversible carbon monoxide insertion into ruthenium-amido bonds
Olaf C. P. Beers, Jos G. P. Delis, Wilhelmus P. Mul, Kees Vrieze, Cornelis J. Elsevier, Wilberth J. J. Smeets, and Anthony L. Spek
pp 3640 - 3647; DOI:
10.1021/ic00069a017
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Derivatized cyclophane chemistry. Synthesis of new (.pi.-benzene)ruthenium(II) complexes of 2,11-dithia- and 2,11-diselena[3.3]orthocyclophane
Lyall R. Hanton and Tim Kemmitt
pp 3648 - 3653; DOI:
10.1021/ic00069a018
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Multiple desilylation of silylated cyclopentadienes promoted by ionic ruthenium and rhodium halides
Charles H. Winter, Shahin Pirzad, David D. Graf, Danh H. Cao, and Mary Jane Heeg
pp 3654 - 3659; DOI:
10.1021/ic00069a019
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Ruthenium tri- and digold hydride clusters
Alberto Albinati, Luigi M. Venanzi, and Guozhi Wang
pp 3660 - 3669; DOI:
10.1021/ic00069a020
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Chemistry of iridium carbonyl cluster complexes. Synthesis and x-ray crystal structure of [PPh4]2[Ir12(.mu.-CO)5(CO)19], containing an unprecedented metal skeleton
Roberto Della Pergola, Francesco Demartin, Luigi Garlaschelli, Mario Manassero, Secondo Martinengo, Norberto Masciocchi, and Piero Zanello
pp 3670 - 3674; DOI:
10.1021/ic00069a021
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Reactivity of palladium complex [Pd(CN)(C6F5)(NCMe)] [CN = ((dimethylamino)methyl)phenyl-C2,N, 8-quinolylmethyl-C,N] toward 2,2'-bipyridine or 1,10-phenanthroline. Synthesis and structures of [{Pd(8-mq)(C6F5)}2(.mu.-bpy)] and [(C6F5)(8-mq)Pd(.mu.-8-mq)Pd(C6F5)(phen)], dinuclear complexes containing unusual 2,2'-bipyridine or unprecedented 8-quinolylmethyl-C,N acting as bridging ligands
Juan Fornies, Rafael Navarro, Violeta Sicilia, and Milagros Tomas
pp 3675 - 3681; DOI:
10.1021/ic00069a022
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Electrochemical preparation and characterization of binuclear palladium(I) complexes containing aromatic isocyanide and chelating diphosphine ligands
Tomoaki Tanase, Kenji Kawahara, Hirokazu Ukaji, Kimiko Kobayashi, Hiroshi Yamazaki, and Yasuhiro Yamamoto
pp 3682 - 3688; DOI:
10.1021/ic00069a023
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Synthesis, structure, and emission spectroscopy of luminescent platinum(II) Pt(COD)(dithiolate) complexes
Joanne M. Bevilacqua, Juan A. Zuleta, and Richard Eisenberg
pp 3689 - 3693; DOI:
10.1021/ic00069a024
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Conductivity, FT-Raman spectra, and x-ray crystal structures of two novel [D2I]In (n = 3 and D = N-methylbenzothiazole-2(3H)-selone; n = 7 and D = N-methylbenzothiazole-2(3H)-thione) iodonium salts. First example of I-.3I2 heptaiodide
Francesco Demartin, Paola Deplano, Francesco A. Devillanova, Francesco Isaia, Vito Lippolis, and Gaetano Verani
pp 3694 - 3699; DOI:
10.1021/ic00069a025
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Octahedral-tetrahedral framework solids of the vanadium phosphate system. Hydrothermal syntheses and crystal structures of the vanadium(III) phosphate Cs[VIII2(PO4)(HPO4)2(H2O)2] and of the mixed-valence species K[(VIVO)VIII(HPO4)3(H2O)2]
Robert C. Haushalter, Zhanwen Wang, Mark E. Thompson, and Jon Zubieta
pp 3700 - 3704; DOI:
10.1021/ic00069a026
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A novel trinuclear cobalt complex: crystal and electronic structure of perylene bis(maleonitriledithiolato)cobaltate (Per)4[Co(mnt)2]3
Vasco Gama, Rui T. Henriques, Manuel Almeida, Luis Veiros, M. J. Calhorda, Auke Meetsma, and Jan L. de Boer
pp 3705 - 3711; DOI:
10.1021/ic00069a027
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Pyramidality effect on rhodium(II)-Rh(II) single bonds
Gabriel Aullon and Santiago Alvarez
pp 3712 - 3719; DOI:
10.1021/ic00069a028
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Two phases of [Me4N][Ni(dmise)2]2: syntheses, crystal structures, electrical conductivities, and intermolecular orbital overlap calculations of .alpha.- and .beta.-tetramethylammonium bis[bis(2-selenoxo-1,3-dithiole-4,5-dithiolato)nickelate], the first conductors based on the M(C3S4Se)2 system
Joost P. Cornelissen, Brigitte Pomarede, Anthony L. Spek, Derk Reefman, Jaap G. Haasnoot, and Jan Reedijk
pp 3720 - 3726; DOI:
10.1021/ic00069a029
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Two new .mu.-azido nickel(II) uniform chains: syntheses, structures, and magneto-structural correlations
Albert Escuer, Ramon Vicente, Joan Ribas, M. Salah El Fallah, Xavier Solans, and M. Font-Bardia
pp 3727 - 3732; DOI:
10.1021/ic00069a030
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Tailored magnetic properties in trinuclear copper(II) complexes: synthesis, structure, and magnetic properties of complexes derived from [1,3-propanediylbis(oxamato)]cuprate(II) ([Cu(pba)]2-)
Ramon Costa, Auxiliadora Garcia, Joan Ribas, Talal Mallah, Yves Journaux, Jorunn Sletten, Xavier Solans, and Victor Rodriguez
pp 3733 - 3742; DOI:
10.1021/ic00069a031
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Synthesis and magnetic properties of a binuclear copper(II) complex with a .mu.-1,2-squarato coordination mode. Crystal structure of (.mu.-1,2-squarato)bis[(N-(2-(diethylamino)ethyl]salicylidenaminato)aquacopper(II)] hydrate
C. E. Xanthopoulos, M. P. Sigalas, G. A. Katsoulos, C. A. Tsipis, C. C. Hadjikostas, A. Terzis, and M. Mentzafos
pp 3743 - 3747; DOI:
10.1021/ic00069a032
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Synthesis of gold [Au3]3+, gold-silver [Au2Ag]3+, and gold-copper [Au2Cu]3+ loose clusters
Jose Vicente, Maria Teresa Chicote, and Maria Cristina Lagunas
pp 3748 - 3754; DOI:
10.1021/ic00069a033
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Fully inorganic (carbon-free) fullerenes? The boron-nitrogen case
Ioan Silaghi-Dumitrescu, Ionel Haiduc, and D. Bryan Sowerby
pp 3755 - 3758; DOI:
10.1021/ic00069a034
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Evidence of spin crossover phenomena deduced from gas-phase photoelectron spectra of the bis[tetrakis(pyrazol-1-yl)borato]iron(II) complex
Antonio Gulino, Enrico Ciliberto, Santo Di Bella, and Ignazio Fragala
pp 3759 - 3761; DOI:
10.1021/ic00069a035
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New tris(amido)vanadium(V) imides: iminoazavanadatranes
Winfried Plass and John G. Verkade
pp 3762 - 3765; DOI:
10.1021/ic00069a036
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Simultaneous coordination of hydrides and .eta.1-S thiophenes made possible at iridium
Roberto A. Sanchez-Delgado, Veronica Herrera, Claudio Bianchini, Dante Masi, and Carlo Mealli
pp 3766 - 3770; DOI:
10.1021/ic00069a037
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Quadruple bonds between molybdenum atoms supported by alkoxide ligands
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, Elena F. Putilina, William E. Streib, and Robert J. Tatz
pp 3771 - 3780; DOI:
10.1021/ic00069a038
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Synthesis and characterization of di-tert-butylgallium hydroxide cyclic trimer [t-Bu2Ga(.mu.-OH)]3
Ahmad A. Naiini, Victor Young, Yong Han, Mufit Akinc, and John G. Verkade
pp 3781 - 3782; DOI:
10.1021/ic00069a039
PDF
Acetylacetonato as bridging .kappa.(O),.kappa.(O') ligand. X-ray structure of (.mu.-acetylacetonato)bis[tricarbonyl(bis(diphenylphosphino)ethane)manganese](1+) perchlorate
Bernardo Alvarez, Claudette Bois, Yves Jeannin, Daniel Miguel, and Victor Riera
pp 3783 - 3785; DOI:
10.1021/ic00069a040
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Reactions of hydrated aqua halo cluster complexes [(M6X12)(H2O)4X2].4H2O (M = niobium, tantalum; X = chloride, bromide) in methanol. Substitution of coordinated water and halogen by methanol as determined by proton NMR spectra and conductance data
N. Brnicevic, P. Planinic, I. Basic, R. E. McCarley, V. Rutar, and X. Xie
pp 3786 - 3788; DOI:
10.1021/ic00069a041
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Preparation and crystal structure of d-.mu.-chlorooctacarbonylbis(THF)triruthenium
Hyunho Cho and Bruce R. Whittlesey
pp 3789 - 3792; DOI:
10.1021/ic00069a042
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Synthesis of the first metal dihydrogen M(.eta.2-H2) complexes containing sulfur-donor ligands
Miguel A. Esteruelas, Luis A. Oro, and Natividad Ruiz
pp 3793 - 3794; DOI:
10.1021/ic00069a043
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Issue 18


A unique supramolecular structure of catena-poly[bis(.mu.-diphenylphosphinodithioato)ditellurium(I)(Te-Te)], [Te2(S2PPh2)2]n, containing Te-Te.cntdot..cntdot..cntdot.Te-Te.cntdot..cntdot..cntdot. chains
M. G. Newton, R. B. King, Ionel Haiduc, and Anca Silvestru
pp 3795 - 3796; DOI:
10.1021/ic00070a001
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Influence of halide ligands on the energetics of the reversible loss of hydrogen from the iridium nonclassical polyhydride complexes IrXH2(H2)(PPri3)2 (X = Cl, Br, I)
Trang Le-Husebo and Craig M. Jensen
pp 3797 - 3798; DOI:
10.1021/ic00070a002
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Generation of Cp2Mo:S and cycloaddition of the molybdenum sulfido bond with di-p-tolylcarbodiimide
Robert S. Pilato, Kenneth A. Eriksen, Edward I. Stiefel, and Arnold L. Rheingold
pp 3799 - 3800; DOI:
10.1021/ic00070a003
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Electrochemical evidence for a two-electron reduction process in a (.mu.-oxo)bis(.mu.-acetato)diruthenium(III) complex containing terminal 1-methylimidazole ligands
Chellamma Sudha, Sisir K. Mandal, and Akhil R. Chakravarty
pp 3801 - 3802; DOI:
10.1021/ic00070a004
PDF
Kinetics and mechanism of the facile diastereomeric isomerization of a tris(bidentate)ruthenium(II) complex bearing a misdirected bipyridyl ligand: .DELTA...LAMBDA.-(.delta./.lambda.-1,1'-biisoquinoline)bis(2,2'-bipyridine)ruthenium(II)
Michael T. Ashby, Geetha N. Govindan, and Anthony K. Grafton
pp 3803 - 3804; DOI:
10.1021/ic00070a005
PDF
Synthesis and reactivity of a tungsten(0) anion stabilized by chelating tertiary amines. The oxidative addition and reductive elimination of a carbon-tin bond at tungsten
Brian P. Buffin, Mitchell J. Poss, Atta M. Arif, and Thomas G. Richmond
pp 3805 - 3806; DOI:
10.1021/ic00070a006
PDF
A class of single-source precursors to titanium disulfide films. Synthesis, structure, and chemical vapor deposition studies of [TiCl4(HSR)2]
Charles H. Winter, T. Suren Lewkebandara, James W. Proscia, and Arnold L. Rheingold
pp 3807 - 3808; DOI:
10.1021/ic00070a007
PDF
Speciation of the proton in ambient-temperature molten salts
John L. E. Campbell and Keith E. Johnson
pp 3809 - 3815; DOI:
10.1021/ic00070a008
PDF
Attempted oxidative generation of a dihydrogen complex
Andrei A. Zlota, Mats Tilset, and Kenneth G. Caulton
pp 3816 - 3821; DOI:
10.1021/ic00070a009
PDF
Early excited state dynamics of pentacarbonyl(4-cyanopyridine)tungsten and pentacarbonyl(4-formylpyridine)tungsten: observation of an ultrafast intersystem crossing
Elspeth Lindsay, Antonin Vlcek, and Cooper H. Langford
pp 3822 - 3825; DOI:
10.1021/ic00070a010
PDF
Kinetics of autoxidation of cobalt(II) cyclidene dioxygen carriers
Mohamad Masarwa, P. Richard G. Warburton, Wayne E. Evans, and Daryle H. Busch
pp 3826 - 3835; DOI:
10.1021/ic00070a011
PDF
Photophysical properties of rhenium(I) tricarbonyl complexes containing alkyl- and aryl-substituted phenanthrolines as ligands
Lynne Wallace and D. Paul Rillema
pp 3836 - 3843; DOI:
10.1021/ic00070a012
PDF
Oxygen-17 NMR study of water exchange on gadolinium polyaminopolyacetates [Gd(DTPA)(H2O)]2- and [Gd(DOTA)(H2O)]- related to NMR imaging
Karoly Micskei, Lothar Helm, Erno Brucher, and Andre E. Merbach
pp 3844 - 3850; DOI:
10.1021/ic00070a013
PDF
Stereochemical properties and x-ray structure of a water-soluble diastereomeric (arene)ruthenium(II) Schiff-base complex: [Ru(.eta.-MeC6H4Pri-p)(H2O)(L*)](ClO4), containing a weakly bound aqua ligand [HL* = (S)-(.alpha.-methylbenzyl)salicylaldimine]
Sisir K. Mandal and Akhil R. Chakravarty
pp 3851 - 3854; DOI:
10.1021/ic00070a014
PDF
Structural and spectroscopic characterization of dioxovanadium(V) complexes with asymmetric Schiff base ligands
Charles A. Root, James D. Hoeschele, Charles R. Cornman, Jeff W. Kampf, and Vincent L. Pecoraro
pp 3855 - 3861; DOI:
10.1021/ic00070a015
PDF
Solid-state cadmium-113 NMR studies on cadmium complexes with glycine, L-alanine, and L-cysteine
Patrick J. Barrie, Angeli Gyani, Majid Motevalli, and Paul O'Brien
pp 3862 - 3867; DOI:
10.1021/ic00070a016
PDF
Sequence-specific cleavage of DNA by oligonucleotide-bound metal complexes
John T. Groves and Ismail O. Kady
pp 3868 - 3872; DOI:
10.1021/ic00070a017
PDF
Photoelectron spectroscopy of f-element organometallic complexes. 9. A comparative fully relativistic/nonrelativistic first-principles X.alpha.-DVM and photoelectron spectroscopic investigation of electronic structure in homologous 4f and 5f tris(.eta.5-cyclopentadienyl)metal(IV) alkoxide complexes
Antonino Gulino, Santo Di Bella, Ignazio Fragala, Maurizio Casarin, Afif M. Seyam, and Tobin J. Marks
pp 3873 - 3879; DOI:
10.1021/ic00070a018
PDF
Nature of metal-metal interactions in systems with bridging ligands. 2. Electronic and molecular structure of the cyclopentadienylnitrosylcobalt dimer and related molecules
Arthur A. Low and Michael B. Hall
pp 3880 - 3889; DOI:
10.1021/ic00070a019
PDF
Resonance Raman and time-resolved resonance Raman studies of tris(4-methyl-2,2'-bipyridine)ruthenium(II). Polarization of the radical fragment of the 3MLCT states
Shelly M. Treffert-Ziemelis, Janusz Golus, Dennis P. Strommen, and James R. Kincaid
pp 3890 - 3894; DOI:
10.1021/ic00070a020
PDF
Electronic coupling in mixed-valence binuclear ruthenium ammine complexes as probed by an electrochemical method and an extension of Mulliken's theory of donor-acceptor interactions
Faleh Salaymeh, Samson Berhane, Rohana Yusof, Roger de la Rosa, Ella Y. Fung, Regina Matamoros, Kent W. Lau, Qian Zheng, Edward M. Kober, and Jeff C. Curtis
pp 3895 - 3908; DOI:
10.1021/ic00070a021
PDF
Electronic structure and spectra for square complexes containing sulfur-donor ligands: M(dto)22+ (M = platinum(II), palladium(II); dto = 3,6-dithiaoctane), M(SCN)42- (M = Pt(II), Pd(II)), and M(Et-Xan)2 (M = Pt(II), Pd(II), nickel(II); Et-Xan- = C2H5OCS2-)
Huseyin Isci, Omer Dag, and W. Roy Mason
pp 3909 - 3914; DOI:
10.1021/ic00070a022
PDF
Structural and compositional basis of high-temperature superconductivity: properties of the magic electronic state
Jeremy K. Burdett
pp 3915 - 3922; DOI:
10.1021/ic00070a023
PDF
Chalcogenide substitution reactions
Jonathan M. McConnachie, John C. Bollinger, and James A. Ibers
pp 3923 - 3927; DOI:
10.1021/ic00070a024
PDF
First crystallographically authenticated example of cis-trans isomerism in octahedral tin(IV) halide complexes
David Tudela, Jesus D. Tornero, Angeles Monge, and Antonio J. Sanchez-Herencia
pp 3928 - 3930; DOI:
10.1021/ic00070a025
PDF
Identification of isomeric meso-Dioxo derivatives of octaethylporphyrin and separation and structural characterization of the nickel(II) complexes
Alan L. Balch, Marilyn M. Olmstead, and Shane L. Phillips
pp 3931 - 3936; DOI:
10.1021/ic00070a026
PDF
Complexes with a trifluorophosphine ligand bridging a tripalladium triangle. Structure of tris(.mu.-bis(diphenylphosphino)methane)(.mu.3-iodo)(.mu.3-phosphorus trifluoride)tripalladium(1+) iodide
Alan L. Balch, Brian J. Davis, and Marilyn M. Olmstead
pp 3937 - 3942; DOI:
10.1021/ic00070a027
PDF
Reactions of [NEt4][10-endo-{Au(PPh3)}-7,8-R'2-nido-7,8-C2B9H9] (R' = Me or H): synthesis of platinum-gold carborane complexes
John C. Jeffery, Paul A. Jelliss, and F. Gordon A. Stone
pp 3943 - 3947; DOI:
10.1021/ic00070a028
PDF
Hexacoordinate organobismuth compounds
Stephan Wallenhauer, Dieter Leopold, and Konrad Seppelt
pp 3948 - 3951; DOI:
10.1021/ic00070a029
PDF
Electrospray mass spectrometric study of the nature and lability of cationic complexes generated by the reaction of solutions of neutral iron(III), cobalt(III), nickel(II) and copper(II) dithiocarbamates with nitrosonium tetrafluoroborate
Alan M. Bond, Ray Colton, Antonella D'Agostino, Justin Harvey, and John C. Traeger
pp 3952 - 3956; DOI:
10.1021/ic00070a030
PDF
Cyclic voltammetric characterization of rate constants for conformational change in an electron-transfer square scheme involving a copper(II)/(I) macrocyclic tetrathiaether complex
Paul V. Robandt, Ronald R. Schroeder, and D. B. Rorabacher
pp 3957 - 3963; DOI:
10.1021/ic00070a031
PDF
Monodentate coordination of the potentially bidentate ligand methyl 2-(N-ethylamino)-1-cyclopentenedithiocarboxylate to rhenium(V) via a neutral thiocarbonyl sulfur atom
Giuliano Bandoli, Jan G. H. du Preez, Thomas I. A. Gerber, and Hannelie J. Kemp
pp 3964 - 3965; DOI:
10.1021/ic00070a032
PDF
A stair step layer structure encapsulating interlayer potassium(1+) cations: hydrothermal synthesis, crystal structure, and magnetic properties of the mixed-valence vanadium phosphate K2[(VIVO)2VIII(PO4)2(HPO4)(H2PO4)(H2O)2]
Robert C. Haushalter, Zhanwen Wang, Mark E. Thompson, Jon Zubieta, and Charles J. O'Connor
pp 3966 - 3969; DOI:
10.1021/ic00070a033
PDF
A method for trimethylphosphine-pentaborane(9) preparation utilizing facile formation of trimethylamine-trimethylphosphine-pentaborane(9)
Andreas Schwarz and Goji Kodama
pp 3970 - 3972; DOI:
10.1021/ic00070a034
PDF
d-Orbital energies in .beta.-ketoenolate copper(II) complexes
Michail A. Atanasov and Michael A. Hitchman
pp 3973 - 3975; DOI:
10.1021/ic00070a035
PDF
Chemical shift range of thioether-bridged face-sharing bioctahedral complexes: a tungsten-183 NMR study
Heinz Bernhard Kraatz, James M. Aramini, Xiaoliang Gao, P. Michael Boorman, and Hans J. Vogel
pp 3976 - 3979; DOI:
10.1021/ic00070a036
PDF
Clusters derived from the hydrocarboration of decacarbonyldi-.mu.-hydridotriosmium and their derivatives. [Erratum to document cited in CA118(9):81164m]
Deng Yang Jan, David P. Workman, Leh Yeh Hsu, Jeanette A. Krause, and Sheldon G. Shore
pp 3980 - 3980; DOI:
10.1021/ic00070a037
PDF
The (.mu.-oxo)bis[trichloroferrate(III)] dianion revisited. [Erratum to document cited in CA118(12):113635j]
Gabriele Haselhorst, Karl Wieghardt, Stefan Keller, and Bernhard Schrader
pp 3980 - 3980; DOI:
10.1021/ic00070a038
PDF

Issue 19


Selectivity of antibody-chelate conjugates for binding copper in the presence of competing metals
David L. Kukis, Min Li, and Claude F. Meares
pp 3981 - 3982; DOI:
10.1021/ic00071a001
PDF
Trivalent lanthanide ions do not cleave RNA in DNA-RNA hybrids
Kimberly A. Kolasa, Janet R. Morrow, and Arun P. Sharma
pp 3983 - 3984; DOI:
10.1021/ic00071a002
PDF
Adsorption of gallane on oxidized silicon
Kirk W. Butz, Fiona M. Elms, Colin L. Raston, Robert N. Lamb, and Paul J. Pigram
pp 3985 - 3986; DOI:
10.1021/ic00071a003
PDF
Clusters of clusters. 25. Synthesis and structure of a new [gold-silver]-38-metal-atom cluster [(Ph3P)14Au18Ag20Cl12]Cl2 and its implications with regard to intracavity chemistry on metal cluster surfaces
Boon K. Teo, Xiaobo Shi, and Hong Zhang
pp 3987 - 3988; DOI:
10.1021/ic00071a004
PDF
Gated glyoximes: conformationally flexible boron-linked superstructure in iron (dioximato)borate complexes
Dennis V. Stynes, Daniel B. Leznoff, and D. G. A. Harshani de Silva
pp 3989 - 3990; DOI:
10.1021/ic00071a005
PDF
Deprotonated thioamides as thiolate S-donor ligands with a high tendency to avoid M-S-M bridge formation: crystal and molecular structure of bis(2-hydroxy-5-methylacetophenone N,N-dimethylthiosemicarbazonato)dinickel
Zheng Lu, Corbet White, Arnold L. Rheingold, and Robert H. Crabtree
pp 3991 - 3994; DOI:
10.1021/ic00071a006
PDF
Synthesis and characterization of copper(II) complexes containing N-glycosides ligands and their use in the catalytic epoxidation of olefins
Tomoaki Tanase, Keisuke Mano, and Yasuhiro Yamamoto
pp 3995 - 4003; DOI:
10.1021/ic00071a007
PDF
Mercaptide complexes of osmium porphyrins. Structure of Os(TTP)(SC6F4H)2
James P. Collman, D. Scott Bohle, and Anne K. Powell
pp 4004 - 4011; DOI:
10.1021/ic00071a008
PDF
Control of axial ligand substitution in trans-bis(2,2'-bipyridine)ruthenium(II) complexes. Crystal and molecular structure of trans-(4-ethylpyridine)(dimethyl sulfoxide)bis(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, trans-[Ru(bpy)2(4-Etpy)(DMSO)](PF6)2
Benjamin J. Coe, Thomas J. Meyer, and Peter S. White
pp 4012 - 4020; DOI:
10.1021/ic00071a009
PDF
Complex formation and water exchange on the trinuclear dioxo-capped complexes [M3(.mu.3-O)2(.mu.-CH3CO2)6(OH2)3]2+ (M = molybdenum, tungsten) and monooxo-capped complex [W3(.mu.3-O)(.mu.-CH3CO2)6(OH2)3]2+
Glenmore Powell and David T. Richens
pp 4021 - 4029; DOI:
10.1021/ic00071a010
PDF
Electronic effects in transition metal porphyrins. 7. Synthesis and spectroscopic investigations of a series of octasubstituted porphyrin isomers and their iron(III) complexes
Meden F. Isaac, Qing Lin, Ursula Simonis, Daniel J. Suffian, Debra L. Wilson, and F. Ann Walker
pp 4030 - 4041; DOI:
10.1021/ic00071a011
PDF
Electrochemical and spectroelectrochemical behavior of cobalt(III), cobalt(II), and cobalt(I) complexes of meso-tetraphenylporphyrinate bearing bromides on the .beta.-pyrrole positions
Francis D'Souza, Anne Villard, Eric Van Caemelbecke, Michelle Franzen, Tristano Boschi, Pietro Tagliatesta, and Karl M. Kadish
pp 4042 - 4048; DOI:
10.1021/ic00071a012
PDF
Synthesis, kinetics, and physicochemical studies of a new mixed-valent heterobinuclear cyano-bridged ruthenium(III)-iron(II) complex
Debabrata Chatterjee, H. C. Bajaj, and Amitava Das
pp 4049 - 4052; DOI:
10.1021/ic00071a013
PDF
The apparent "dual emitter" characteristics of iridium bipyridine phenanthroline complexes, [Ir(bpy)x(phen)3-x]3+ for x = 1,2
Elmars Krausz, John Higgins, and Hans Riesen
pp 4053 - 4056; DOI:
10.1021/ic00071a014
PDF
Complementarity and internal consistency between magnetic and optical properties for the manganese(II) copper(II) heterodinuclear compound [Mn(Me6-[14]ane-N4)Cu(oxpn)](CF3SO3)2 (Me6-[14]ane-N4 = (.+-.)-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; oxpn = N,N'-bis(3-aminopropyl)oxamide
Corine Mathoniere, Olivier Kahn, Jean Claude Daran, Harald Hilbig, and Frank H. Koehler
pp 4057 - 4062; DOI:
10.1021/ic00071a015
PDF
Synthetic, structural, and spectroscopic studies on copper(II), copper(I), and silver(I) complexes of a series of pyridazinophane and phthalazinophane macrocycles. Unusual extended metallocyclic structures
Liqin Chen, Laurence K. Thompson, Santokh S. Tandon, and John N. Bridson
pp 4063 - 4068; DOI:
10.1021/ic00071a016
PDF
Synthetic and structural studies on (RC5H4)4Ru4E40/2+ (E = sulfur, selenium, tellurium): mobile metal-metal bonds within a mixed-valence ruthenium (IV)/ruthenium(III) cluster
Eric J. Houser, Thomas B. Rauchfuss, and Scott R. Wilson
pp 4069 - 4076; DOI:
10.1021/ic00071a017
PDF
Aliphatic neodymium alkoxides with sterically demanding ligands. Preparation and x-ray crystal structures of Nd2(OCH-iso-Pr2)6L2 (L = THF, py) and [Nd2(OCH-iso-Pr2)6(.mu.-DME)].infin.
David M. Barnhart, David L. Clark, John C. Huffman, Rebecca L. Vincent, and John G. Watkin
pp 4077 - 4083; DOI:
10.1021/ic00071a018
PDF
Synthesis of new tetradentate oligophosphine ligands
Nick Bampos, Leslie D. Field, Barbara A. Messerle, and Ronald J. Smernik
pp 4084 - 4088; DOI:
10.1021/ic00071a019
PDF
The hexafluorooxotechnetate(2-) anion: the first example of a multiply charged, pentagonal bipyramidal, main-group element AX5YZ species and the vibrational spectra of the TeOF5- anion
Karl O. Christe, David A. Dixon, Jeremy C. P. Sanders, Gary J. Schrobilgen, and William W. Wilson
pp 4089 - 4093; DOI:
10.1021/ic00071a020
PDF
Factors governing the charge density wave patterns of layered transition-metal compounds of octahedral coordination with d2 and d3 electron counts
Carme Rovira and Myung Hwan Whangbo
pp 4094 - 4097; DOI:
10.1021/ic00071a021
PDF
The phenomenon of conglomerate crystallization. 24. Spontaneous resolution in coordination compounds. Classical and spontaneous resolution of the amminebromobis(ethylenediamine)cobalt(2+) cation. Crystal structures and absolute configurations of resolved (+)589-[cis-.LAMBDA.(.delta..lambda.)-Co(en)2(NH3)Br]S4O6 (I) and of conglomerate crystals of [cis-.LAMBDA.(.delta..lambda.)-Co(en)2(NH3)Br]S4O6 (II)
Ivan Bernal, James Cetrullo, and W. Gregory Jackson
pp 4098 - 4101; DOI:
10.1021/ic00071a022
PDF
Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes. 2. Refined distances and other enzymes
Wentian Liu and H. Holden Thorp
pp 4102 - 4105; DOI:
10.1021/ic00071a023
PDF
Synthesis and characterization of mononuclear bis(para-substituted phenolato)oxomolybdenum(V) complexes: dependence of the molecular properties upon remote substituent effects
Chaung Sheng J. Chang, Tonia J. Pecci, Michael D. Carducci, and John H. Enemark
pp 4106 - 4110; DOI:
10.1021/ic00071a024
PDF
Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2)2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4)
Paul A. van der Schaaf, Johann T. B. H. Jastrzebski, Marinus P. Hogerheide, Wilberth J. J. Smeets, Anthony L. Spek, Jaap Boersma, and Gerard van Koten
pp 4111 - 4118; DOI:
10.1021/ic00071a025
PDF
Bioorganometallic chemistry. 3. Role of the phosphate group during reactions of adenosine monophosphate derivatives with an (.eta.5-pentamethylcyclopentadienyl)rhodium aqua complex in the diastereoselective formation of cyclic trimers, [Cp*Rh(AMP)]3
David P. Smith, Elizabeth Kohen, Marcos F. Maestre, and Richard H. Fish
pp 4119 - 4122; DOI:
10.1021/ic00071a026
PDF
Structures and magnetic properties of [M(cyclam)(CH3CN)2][Ni(dmit)2]2 (M = copper, nickel) and [Cu(cyclam)]2[2,5-DM-DCNQI]5
Hiroki Oshio
pp 4123 - 4130; DOI:
10.1021/ic00071a027
PDF
Comparative study on the coordination chemistry of cobalt(II), nickel(II), and copper(II) with derivatives of salen and tetrahydrosalen: metal-catalyzed oxidative dehydrogenation of the carbon-nitrogen bond in coordinated tetrahydrosalen
Arnd Boettcher, Horst Elias, Ernst Gottfried Jaeger, Helena Langfelderova, Milan Mazur, Lutz Mueller, Helmut Paulus, Peter Pelikan, Manfred Rudolph, and Marian Valko
pp 4131 - 4138; DOI:
10.1021/ic00071a028
PDF
Structural and photophysical properties of lanthanide complexes with planar aromatic tridentate nitrogen ligands as luminescent building blocks for triple-helical structures
Claude Piguet, Alan F. Williams, Gerald Bernardinelli, and Jean Claude G. Buenzli
pp 4139 - 4149; DOI:
10.1021/ic00071a029
PDF
Synthesis, characterization, and decomposition of the first mononuclear eight-coordinate indium(III) benzoate, In(.eta.2-O2CC6H5)3(4-Mepy)2
Maria T. Andras, Aloysius F. Hepp, Stan A. Duraj, Eric B. Clark, Daniel A. Scheiman, Phillip E. Fanwick, and David G. Hehemann
pp 4150 - 4152; DOI:
10.1021/ic00071a030
PDF
Crystal structure of nickel vanadyl phosphate hydrate, Ni0.5VOPO4.2H2O, a layered vanadyl(IV) phosphate hydrate with tetragonal symmetry
Kwang Hwa Lii, Liang Shen Wu, and Han Mou Gau
pp 4153 - 4154; DOI:
10.1021/ic00071a031
PDF
Exchange of oxo ligands in osmium tetroxide with imido ligands in bis(arylimido)bis(tert-butoxo)molybdenum complexes, Mo(NAr)2(O-tert-Bu)2. A facile route to Os(NAr)2O2 and Os(NAr)3O and osmium(IV) complexes of the type Os(NAr)2L2 (NAr = N-2,6-C6H3-iso-Pr2; L = a phosphine)
Jennifer R. Wolf, Guillermo C. Bazan, and Richard R. Schrock
pp 4155 - 4156; DOI:
10.1021/ic00071a032
PDF
Structures of the isomeric forms of tris(triphenylphosphine)copper(I) tetrachloroferrate(III), (PPh3)3CuFeCl4: examples of the weakly coordinated and uncoordinated tris(triphenylphosphine)copper(I) cation
Dennis J. Saturnino and Atta M. Arif
pp 4157 - 4160; DOI:
10.1021/ic00071a033
PDF
Hydro(methano)thermal synthesis and characterization of two new platinum polysulfides: [Pt4S22]4- and [Pt(S4)2]2-
Kang Woo Kim and Mercouri G. Kanatzidis
pp 4161 - 4163; DOI:
10.1021/ic00071a034
PDF
Reinvestigation of the infrared spectra of oxoosmium(VI) esters by isotopic labeling
Dominic V. McGrath, G. Dana Brabson, K. Barry Sharpless, and Lester Andrews
pp 4164 - 4165; DOI:
10.1021/ic00071a035
PDF
Regulation of the ligand field strength of a cobalt(III) complex by methyl substitutions on a tetraamine ligand: an important factor for the dissociation of a generally inert chelated amino acidato ligand from a cobalt(III) complex
Morio Yashiro, Sadao Yoshikawa, and Shigenobu Yano
pp 4166 - 4167; DOI:
10.1021/ic00071a036
PDF
The use of carbon-13 NMR isotopomer distributions for following proton exchange and unambiguously assigning the carbons and coordinated amine protons in multidentate chelate complexes of cobalt (III). [Erratum to document cited in CA114(16):155645k]
W. Gregory Jackson
pp 4168 - 4168; DOI:
10.1021/ic00071a037
PDF
Synthesis, solution structure, and reactivity of oxygen-bound amides on cobalt(III). [Erratum to document cited in CA118(14):138542q]
Patricia M. Angus, David P. Fairlie, and W. Gregory Jackson
pp 4168 - 4168; DOI:
10.1021/ic00071a038
PDF

Issue 20


Hydrogen bridging rhodium and tin: an NMR study of [Rh(H){(.mu.-H)SnR3}2(PPh3)2] (R = nBu, Ph)
Laurence Carlton and Rosemarie Weber
pp 4169 - 4170; DOI:
10.1021/ic00072a001
PDF
Divergent pathways for the addition of dioxygen to sulfur in nickel cis-dithiolates: an isotopomeric analysis
Patrick J. Farmer, Touradj Solouki, Takako Soma, David H. Russell, and Marcetta Y. Darensbourg
pp 4171 - 4172; DOI:
10.1021/ic00072a002
PDF
Structural and reactivity patterns in .pi.-complexes of o-benzoquinone
D. Scott Bohle, A. Noerlund Christensen, and Patrica A. Goodson
pp 4173 - 4174; DOI:
10.1021/ic00072a003
PDF
A novel diamagnetic diruthenium(III) complex bridged by four unsymmetrical carboxylate-type ligands. Synthesis, molecular structure, electrochemistry, and spectroelectrochemistry of Ru2(pfap)4(C.tplbond.CC6H5)2, where pfap is 2,3,4,5,6-pentafluoro-2-anilinopyridinate
Yulan Li, Baocheng Han, Karl M. Kadish, and John L. Bear
pp 4175 - 4176; DOI:
10.1021/ic00072a004
PDF
First reversible electrogeneration of triply oxidized nickel porphyrins and porphycenes. Formation of nickel(III) .pi. dications
Karl M. Kadish, Eric Van Caemelbecke, Pierre Boulas, Francis D'Souza, Emanuel Vogel, Michael Kisters, Craig J. Medforth, and Kevin M. Smith
pp 4177 - 4178; DOI:
10.1021/ic00072a005
PDF
Mechanistic details for the electroreduction of fluorophenyl .sigma.-bonded iron(III) porphyrins in noncoordinating solvents
Karl M. Kadish, Francis D'Souza, Eric Van Caemelbecke, Anne Villard, Jae Duck Lee, Alain Tabard, and Roger Guilard
pp 4179 - 4185; DOI:
10.1021/ic00072a006
PDF
Synthesis, characterization, substitution, and atom-transfer reactions of (.eta.2-alkyne)(tetratolylporphyrinato)titanium(II). X-ray structure of trans-bis(4-picoline)(tetratolylporphyrinato)titanium(II)
L. Keith Woo, J. Alan Hays, Victor G. Young, Catherine L. Day, Cecile Caron, Francis D'Souza, and Karl M. Kadish
pp 4186 - 4192; DOI:
10.1021/ic00072a007
PDF
Ligand basicity and rigidity control formation of macrocyclic polyamino carboxylate complexes of gadolinium(III)
Krishan Kumar and M. F. Tweedle
pp 4193 - 4199; DOI:
10.1021/ic00072a008
PDF
Reductive quenching of the emission of trans-dioxo(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)osmium(VI) in water
Siegfried Schindler, Edward W. Castner, Carol Creutz, and Norman Sutin
pp 4200 - 4208; DOI:
10.1021/ic00072a009
PDF
Synthesis and characterization of iron clathrochelate complexes derived from oxime-hydrazone ligands and capped by ferrocenylborate and 1,1'-ferrocenediyldiborate
Kelly L. Bieda, Alison L. Kranitz, and Joseph J. Grzybowski
pp 4209 - 4213; DOI:
10.1021/ic00072a010
PDF
Photoprotonation of a metal nitride complex
William J. Vining, Gregory A. Neyhart, Stephan Nielsen, and B. Patrick Sullivan
pp 4214 - 4217; DOI:
10.1021/ic00072a011
PDF
Theoretical study of the activation of the nitrogen-hydrogen bond in ammonia by second row transition metal atoms
Margareta R. A. Blomberg, Per E. M. Siegbahn, and Mats Svensson
pp 4218 - 4225; DOI:
10.1021/ic00072a012
PDF
Time-resolved IR study of the photobehavior of 4-acetylpyridine pentacarbonyltungsten
Frank P. A. Johnson, Michael W. George, and James J. Turner
pp 4226 - 4229; DOI:
10.1021/ic00072a013
PDF
Theoretical studies of boranamine and its conjugate base. Comparison of the boron-nitrogen and boron-phosphorus .pi. bond energies
Thomas L. Allen and William H. Fink
pp 4230 - 4234; DOI:
10.1021/ic00072a014
PDF
Reactions of peroxovanadates with amino acids and related compounds in aqueous solution
Alan S. Tracey and Jaswinder S. Jaswal
pp 4235 - 4243; DOI:
10.1021/ic00072a015
PDF
Kinetics of oxygen atom transfer in an analog reaction system of the molybdenum oxotransferases
Brian E. Schultz and R. H. Holm
pp 4244 - 4248; DOI:
10.1021/ic00072a016
PDF
Chemistry of variable-valence oxovanadium VOz+ (z = 2, 3) complexes: synthesis structure, and metal redox of new VV O(ONO)/(ON) and VIV O(ONO)/(NN) families
Joydip Chakravarty, Somnath Dutta, Swapan Kumar Chandra, Partha Basu, and Animesh Chakravorty
pp 4249 - 4255; DOI:
10.1021/ic00072a017
PDF
Binding of the lopsided 1,5,6-trimethylbenzimidazole ligand to inorganic and organometallic cobaloxime B12 models
Jean Pierre Charland, Ennio Zangrando, Nevenka Bresciani-Pahor, Lucio Randaccio, and Luigi G. Marzilli
pp 4256 - 4267; DOI:
10.1021/ic00072a018
PDF
Hexadentate N3O3 amine phenol ligands for Group 13 metal ions: evidence for intrastrand and interstrand hydrogen-bonds in polydentate tripodal amine phenols
Shuang Liu, Ernest Wong, Steven J. Rettig, and Chris Orvig
pp 4268 - 4276; DOI:
10.1021/ic00072a019
PDF
Oxo-bridged iron clusters. Synthesis of 1,3-bis(1,4,7-triaza-1-cyclononyl)-2-hydroxypropane and its stabilization of the Fe4O6 core
Jonathan L. Sessler, John W. Sibert, Anthony K. Burrell, Vincent Lynch, John T. Markert, and Chris L. Wooten
pp 4277 - 4283; DOI:
10.1021/ic00072a020
PDF
Crown thioether complexes of iron(II). Crystal structures of meso-bis(1,4,7-trithiacyclodecane)iron(II) perchlorate and (1,4,7,11,14,17-hexathiacycloeicosane)iron(II) perchlorate
Gregory J. Grant, Saju M. Isaac, William N. Setzer, and Donald G. VanDerveer
pp 4284 - 4290; DOI:
10.1021/ic00072a021
PDF
Coupled substitution of niobium and silicon in potassium titanyl phosphate and arsenate (KTiOPO4 and KTiOAsO4. Synthesis and nonlinear optical properties of KTi1-xNbxOX1-xSixO4 (X = P, As)
K. Kasthuri Rangan, B. Raghavendra Prasad, C. K. Subramanian, and J. Gopalakrishnan
pp 4291 - 4293; DOI:
10.1021/ic00072a022
PDF
Synthesis and crystal structures of three zinc (chloromethyl)phosphonates
Chhaya Bhardwaj, Hengliang Hu, and Abraham Clearfield
pp 4294 - 4299; DOI:
10.1021/ic00072a023
PDF
Synthesis and x-ray and neutron structures of anti-dihydridodi-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dirhodium(2+) hexafluorophosphate and a related species containing a syn-[Rh2(H)2(.mu.-H)2]2+ core. Isolation of tri-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)diiron(1+) tetraphenylborate
Dieter Hanke, Karl Wieghardt, Bernhard Nuber, Roy Song Lu, Richard K. McMullan, Thomas F. Koetzle, and Robert Bau
pp 4300 - 4305; DOI:
10.1021/ic00072a024
PDF
Reduced molybdenum-niobium oxides. 1. Synthesis, structure, and physical properties of K2Mo4Nb3O20
S. C. Chen, B. Wang, and M. Greenblatt
pp 4306 - 4310; DOI:
10.1021/ic00072a025
PDF
Gas-phase electron diffraction study of ruthenium(V) fluoride and osmium(V) fluoride
Elizabeth M. Page, David A. Rice, Matthew J. Almond, Kolbjoern Hagen, Hans Vidar Volden, John H. Holloway, and Eric G. Hope
pp 4311 - 4316; DOI:
10.1021/ic00072a026
PDF
Lithium cations tightly bound to polychalcogenides: synthesis and solid-state structures of Li2S6(teeda)2, Li2S4(pmdeta)2, and Li2Se5(pmdeta)2
Kazuyuki Tatsumi, Hiroyuki Kawaguchi, Koji Inoue, Kazuhide Tani, and Roger E. Cramer
pp 4317 - 4323; DOI:
10.1021/ic00072a027
PDF
1,3-Diaryltriazenido compounds of aluminum
John T. Leman, Janet Braddock-Wilking, Alanna J. Coolong, and Andrew R. Barron
pp 4324 - 4336; DOI:
10.1021/ic00072a028
PDF
Ferromagnetism and the .alpha. and .beta. polymorphs of anhydrous copper(II) formate: two molecular-based ferromagnets with ordering temperatures of 8.2 and 30.4 K
Fernando Sapina, Marcelino Burgos, Emilio Escriva, Jose Vicente Folgado, Dolores Marcos, Aurelio Beltran, and Daniel Beltran
pp 4337 - 4344; DOI:
10.1021/ic00072a029
PDF
Solid state structures of [hydrotris(3-tert-butyl-5-methylpyrazolyl)borato]chlorotin and -cadmium. Stereochemical influence of a central atom lone pair
Daniel L. Reger, Scott S. Mason, Josef Takats, Xing Wang Zhang, Arnold L. Rheingold, and Brian S. Haggerty
pp 4345 - 4348; DOI:
10.1021/ic00072a030
PDF
Calcium-tin (Ca31Sn20) and related compounds: novel Zintl phases containing dimers and pentamers of tin or lead
Ashok K. Ganguli, Arnold M. Guloy, E. Alejandro Leon-Escamilla, and John D. Corbett
pp 4349 - 4353; DOI:
10.1021/ic00072a031
PDF
Three novel Zintl phases in the magnesium-lanthanum-antimony system based on intergrowth of LaSb and Mg3Sb2 slabs
Ashok K. Ganguli, Young Uk Kwon, and John D. Corbett
pp 4354 - 4359; DOI:
10.1021/ic00072a032
PDF
Pentacoordinated molecules. Part 97. Variations in sulfur-containing eight-membered ring conformations of hydrogen-bonded and non-hydrogen-bonded cyclic phosphates and octahedrally coordinated cyclic pentaoxyphosphoranes
Robert R. Holmes, T. K. Prakasha, and Roberta O. Day
pp 4360 - 4367; DOI:
10.1021/ic00072a033
PDF
Hydrothermal synthesis and structural characterization of mixed-valence iron phosphates: AFe5(PO4)5(OH).H2O (A = Ca, Sr)
Edita Dvoncova and Kwang Hwa Lii
pp 4368 - 4372; DOI:
10.1021/ic00072a034
PDF
Am3(P2O7)2 (A = alkaline-earth metals; M - iron, cobalt, nickel): diphosphates containing infinite chains of edge-sharing MO6 octahedra
Kwang Hwa Lii, Pei Fen Shih, and Teng Ming Chen
pp 4373 - 4377; DOI:
10.1021/ic00072a035
PDF
Syntheses and solid-state NMR of tetrabutylammonium hydrogen telluride, tetramethylammonium hydrogen selenide and bis(tetramethylammonium) ditelluride and x-ray crystal structures of Me4NSeH and (Me4N)2Te2
R. J. Batchelor, F. W. B. Einstein, I. D. Gay, C. H. W. Jones, and R. D. Sharma
pp 4378 - 4383; DOI:
10.1021/ic00072a036
PDF
Synthesis and structural and magnetic studies of diazine-bridged complexes of copper(II) cyanate. Crystal structure of poly[bis(cyanato-N)bis(.mu.-methylpyrazine)copper(II)]
Tom Otieno, Steven J. Rettig, Robert C. Thompson, and James Trotter
pp 4384 - 4390; DOI:
10.1021/ic00072a037
PDF
Synthesis and characterization of selenium-nitrogen chlorides: force-field calculations for the Se3N2Cl+ cation
Jari Siivari, Tristram Chivers, and Risto S. Laitinen
pp 4391 - 4395; DOI:
10.1021/ic00072a038
PDF
NMR studies of the proton equilibrium in basic ambient-temperature chloroaluminate ionic liquids
Paul C. Trulove, Dinesh K. Sukumaran, and Robert A. Osteryoung
pp 4396 - 4401; DOI:
10.1021/ic00072a039
PDF
Photophysical and photochemical properties of dinuclear ruthenium(II) complexes containing 2,2'-bipyridine and 1,10-phenanthroline moieties
Helen P. Hughes, Ditanya Martin, Stephen Bell, John J. McGarvey, and Johannes G. Vos
pp 4402 - 4408; DOI:
10.1021/ic00072a040
PDF
F430 model chemistry. Evidence for alkyl- and hydrido-nickel intermediates in the reactions of the nickel(I) octaethylisobacteriochlorin anion
Goutam K. Lahiri and Alan M. Stolzenberg
pp 4409 - 4413; DOI:
10.1021/ic00072a041
PDF
Adocobalamin (AdoCbl or coenzyme B12) cobalt-carbon bond homolysis radical-cage effects: product, kinetic, mechanistic, and cage efficiency factor (Fc) studies, plus the possibility that coenzyme B12-dependent enzymes function as "ultimate radical cages" and "ultimate radical traps"
Cheryl D. Garr and Richard G. Finke
pp 4414 - 4421; DOI:
10.1021/ic00072a042
PDF
Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 2. Copper-containing double-stranded helicates derived from functionalized quaterpyridine and quinquepyridine: redox state-induced transformations and electron communication in mixed-valence systems
Kevin T. Potts, Majid Keshavarz-K, Fook S. Tham, Hector D. Abruna, and Claudia R. Arana
pp 4422 - 4435; DOI:
10.1021/ic00072a043
PDF
Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 3. Metal-metal interaction and redox state-induced transformations in double-stranded helicates derived from functionalized quinquepyridine and sexipyridine
Kevin T. Potts, Majid Keshavarz-K, Fook S. Tham, Hector D. Abruna, and Claudia Arana
pp 4436 - 4449; DOI:
10.1021/ic00072a044
PDF
Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 4. Metal-metal interaction in double-stranded, dicuprous helicates derived from terpyridine derivatives
Kevin T. Potts, Majid Keshavarz-K, Fook S. Tham, Hector D. Abruna, and Claudia Arana
pp 4450 - 4456; DOI:
10.1021/ic00072a045
PDF
Trans-Aquacarbonyldichlorobis(triethylphosphine)ruthenium, an aquo carbonyl complex of ruthenium: synthesis, structural characterization, and reactivity
Yan Sun, Nicholas J. Taylor, and Arthur J. Carty
pp 4457 - 4459; DOI:
10.1021/ic00072a046
PDF
Preparation of cyclopentadienyltrihalomolybdenum, CpMoX3 (Cp = .eta.-C5H5; X = Cl, Br, I) by thermal decarbonylation of CpMoX3(CO)2, a previously overlooked phenomenon
John C. Gordon, Vincent T. Lee, and Rinaldo Poli
pp 4460 - 4463; DOI:
10.1021/ic00072a047
PDF
Oxygen or nitrogen chelates stabilizing barium and yttrium .beta.-diketonates
Simon R. Drake, Michael B. Hursthouse, K. M. Abdul Malik, Stewart A. S. Miller, and David J. Otway
pp 4464 - 4471; DOI:
10.1021/ic00072a048
PDF
Solid-state tin-119 NMR studies of poly(pyrazolyl)borate complexes of tin(II). Correlation of solution- and solid-state structures
Daniel L. Reger, Mark F. Huff, Steven J. Knox, Richard J. Adams, David C. Apperley, and Robin K. Harris
pp 4472 - 4473; DOI:
10.1021/ic00072a049
PDF
Charge distribution in complexes derived from o-benzoquinones
Bruce R. McGarvey, Andrzej Ozarowski, and Dennis G. Tuck
pp 4474 - 4474; DOI:
10.1021/ic00072a050
PDF
Angular geometry and the electronic spectrum of cis- and trans-diammine(1,4,8,11-tetraazacyclotetradecane)chromium(III)
Patrick E. Hoggard and Alexander D. Kirk
pp 4475 - 4477; DOI:
10.1021/ic00072a051
PDF
Iridium-193 Moessbauer study of chloro(carbonyl)bis(triphenylphosphine)(buckminsterfullerene)iridium
A. Vertes, M. Gal, F. E. Wagner, F. Tuczek, and P. Guetlich
pp 4478 - 4479; DOI:
10.1021/ic00072a052
PDF
Reaction of hydrogen sulfide with native horse spleen ferritin
T. G. St. Pierre, W. Chua-anusorn, P. Sipos, I. Kron, and J. Webb
pp 4480 - 4482; DOI:
10.1021/ic00072a053
PDF

Issue 21


Widely varying photophysical properties of ligand-nitrated bis(.mu.-chloro)tetrakis(2-phenylpyridinato)diiridium(III)
Gregory A. Carlson, Peter I. Djurovich, and Richard J. Watts
pp 4483 - 4484; DOI:
10.1021/ic00073a001
PDF
Synthesis and structural characterization of binuclear vanadium-oxo-organophosphonato complexes: building blocks for oxovanadium organophosphonate solids
Qin Chen, Jose Salta, and Jon Zubieta
pp 4485 - 4486; DOI:
10.1021/ic00073a002
PDF
Heteronuclear NMR studies of cobalt corrinoids. 16. Indirect detection of the nitrogen-15 NMR resonances of the axial 5,6-dimethylbenzimidazole nucleotide and of corrin ring N22 and N23 via the heteronuclear multiple-quantum coherence (HMQC) experiment
Kenneth L. Brown, Daniel R. Evans, Xiang Zou, and Guo Zhang Wu
pp 4487 - 4488; DOI:
10.1021/ic00073a003
PDF
Evidence for the photodeposition of elemental iron in porous Vycor glass
D. Sunil, J. Sokolov, M. H. Rafailovich, H. D. Gafney, and X. Duan
pp 4489 - 4490; DOI:
10.1021/ic00073a004
PDF
Rhenium(V) and technetium(V) complexes of bidentate (O,O) monobasic 3-oxy-4-pyronato and -4-pyridinonato ligands. X-ray structures of cis-bromobis(3-methyl-2-oxy-4-pyronato)oxorhenium(V), tetra-n-butylammonium tribromo(3-methyl-2-oxy-4-pyronato)oxorhenate(V), and tetra-n-butylammonium trichloro(3-methyl-2-oxy-4-pyronato)oxotechnetate(V)
Hongyan Luo, Steven J. Rettig, and Chris Orvig
pp 4491 - 4497; DOI:
10.1021/ic00073a005
PDF
X-ray and molecular structure of the diastereomeric pair .LAMBDA.- and .DELTA.-tris(ethylenediamine)cobalt(III) .DELTA.-(ethylenediamine)bis(oxalato)cobaltate(II) dioidide trihydrate and monohydrate and comparisons with [.LAMBDA.-Co(en)3][.DELTA.-Co(gly)(ox)2]I.cntdot.H2O
A. Graham Lappin, Kenneth J. Haller, Robert M. L. Warren, and Akira Tatehata
pp 4498 - 4504; DOI:
10.1021/ic00073a006
PDF
Compounds with M3Se3 (M = lithium, zinc) rings: synthesis and characterization of [Zn(CH2SiMe3)Se-2,4,6-tert-Bu3C6H2]3.cntdot.0.5C6H14 and [Li(THF)Se-2,4,6-tert-Bu3C6H2]3.cntdot.PhMe
Karin Ruhlandt-Senge and Philip P. Power
pp 4505 - 4508; DOI:
10.1021/ic00073a007
PDF
Intercalation of aminophenyl- and pyridinium-substituted porphyrins into zirconium hydrogen phosphate: evidence for substituent-derived orientational selectivity
Ronald M. Kim, John E. Pillion, David A. Burwell, John T. Groves, and Mark E. Thompson
pp 4509 - 4516; DOI:
10.1021/ic00073a008
PDF
Methyltrioxorhenium-catalyzed oxidation of a (thiolato)cobalt(III) complex by hydrogen peroxide
Patrick Huston, James H. Espenson, and Andreja Bakac
pp 4517 - 4523; DOI:
10.1021/ic00073a009
PDF
Hexa- and octanuclear gold complexes of p-phenylenediphosphine
Hubert Schmidbaur, Edgar Zeller, and Joji Ohshita
pp 4524 - 4526; DOI:
10.1021/ic00073a010
PDF
Kinetics and mechanism for manganese-catalyzed oxidation of sulfur(IV) by oxygen in aqueous solution
Johan Berglund, Sture Fronaeus, and Lars I. Elding
pp 4527 - 4538; DOI:
10.1021/ic00073a011
PDF
Highly coupled mixed-valence dinuclear ruthenium and osmium complexes with a bis-cyclometalating terpyridine analog as bridging ligand
Marc Beley, Jean Paul Collin, and Jean Pierre Sauvage
pp 4539 - 4543; DOI:
10.1021/ic00073a012
PDF
Versatile complex-formation kinetics observed for the reactions of a model cis-bis(amine)palladium(II) complex with DNA nucleosides and nucleotides
S. Suvachittanont, H. Hohmann, R. van Eldik, and J. Reedijk
pp 4544 - 4548; DOI:
10.1021/ic00073a013
PDF
Theoretical investigation of four-center two-electron bonding involving boron derivatives
Michael L. McKee, Michael Buehl, Oleg P. Charkin, and Paul v. R. Schleyer
pp 4549 - 4554; DOI:
10.1021/ic00073a014
PDF
Magnetooptical investigation of the broad spin-allowed bands in the metal-metal-bonded complexes nonahalodimolybdate(3-), Mo2X93- (X = Cl, Br)
Robert Stranger, Grainne Moran, Elmars Krausz, and Greg Medley
pp 4555 - 4560; DOI:
10.1021/ic00073a015
PDF
Synthesis and characterization of a (.mu.-oxo)(.mu.-carboxylato)dimanganese(III) polyimidazole complex
Kenneth J. Oberhausen, Robert J. O'Brien, John F. Richardson, Robert M. Buchanan, Raman Costa, Jean Marc Latour, Hui Lien Tsai, and David N. Hendrickson
pp 4561 - 4565; DOI:
10.1021/ic00073a016
PDF
Synthesis, structure, and dynamic properties of the lanthanum(III) complex of 1,4,7,10-tetrakis(2-carbamoylethyl)-1,4,7,10-tetraazacyclododecane
Janet R. Morrow, Shahid Amin, Charles H. Lake, and Melvyn Rowen Churchill
pp 4566 - 4572; DOI:
10.1021/ic00073a017
PDF
Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n
Helmut Rothfuss, Jane T. Barry, John C. Huffman, Kenneth G. Caulton, and Malcolm H. Chisholm
pp 4573 - 4577; DOI:
10.1021/ic00073a018
PDF
Studies on interactions of isocyanide with transition metal complexes. 36. Synthesis and characterization of a binuclear palladium(I) complex with bridging .eta.3-indenyl ligands, Pd2(.mu.-.eta.3-indenyl)2(isocyanide)2, and its transformation to a tetranuclear palladium(I) cluster of isocyanides, Pd4(.mu.-acetate)4(.mu.-isocyanide)4
Tomoaki Tanase, Takahito Nomura, Toshihiro Fukushima, Yasuhiro Yamamoto, and Kimiko Kobayashi
pp 4578 - 4584; DOI:
10.1021/ic00073a019
PDF
Thermal and photochemical oxidative addition of alkyl halides to the cyclometalated complex cis-bis[2-(2-thienyl)pyridine]platinum(II)
Alex von Zelewsky, Adrian P. Suckling, and H. Stoeckli-Evans
pp 4585 - 4593; DOI:
10.1021/ic00073a020
PDF
Spectroscopic investigation of the reactivity of Cp*Ru(PPr-iso2Ph)X toward molecular hydrogen and silanes: formation in solution of Cp*Ru(PPr-iso2Ph)(H)3 and Cp*Ru(PPr-iso2Ph)(H)2Y (Y = halide, OR, and SiR'3)
Todd J. Johnson, Paul S. Coan, and Kenneth G. Caulton
pp 4594 - 4599; DOI:
10.1021/ic00073a021
PDF
Preparation and characterization of zirconium phosphate phosphonates, ZrPO4(H2PO4)1-x(RPO2OH)x.nH2O, with .gamma.-layer structure (R = CH3, C3H7, C6H11)
G. Alberti, M. Casciola, R. Vivani, and R. K. Biswas
pp 4600 - 4604; DOI:
10.1021/ic00073a022
PDF
Interligand carbon-carbon .sigma.-bond breaking and repair in a "stapled" bis(phthalocyaninato)titanium complex. Synthesis, characterization, and electrical conductivity properties of oxidation products of bis(phthalocyaninato)titanium(IV) and bis(phthalocyaninato)tin(IV) and x-ray crystal structure of [Pc2Ti](I3)0.66
A. Capobianchi, C. Ercolani, A. M. Paoletti, G. Pennesi, G. Rossi, A. Chiesi-Villa, and C. Rizzoli
pp 4605 - 4611; DOI:
10.1021/ic00073a023
PDF
Magnetic properties of a layered molecular material comprising manganese hexafluoroacetylacetonate and nitronyl nitroxide radicals
Andrea Caneschi, Dante Gatteschi, and Roberta Sessoli
pp 4612 - 4616; DOI:
10.1021/ic00073a024
PDF
Preparation and structure of copper(II) ethylphosphonate. Structural transition between its hydrated and dehydrated forms
Jean Le Bideau, Bruno Bujoli, Alain Jouanneaux, Christophe Payen, Pierre Palvadeau, and Jean Rouxel
pp 4617 - 4620; DOI:
10.1021/ic00073a025
PDF
Synthesis and structural and magnetic properties of mononuclear, dinuclear, and tetranuclear copper(II) complexes of a 17-membered macrocyclic ligand (HM3), capable of forming endogenous phenoxide and pyridazino bridges. X-ray crystal structures of [Cu2(M3)(.mu.2-OMe)(NO3)2], [Cu4(M3)2(.mu.3-OMe)2(.mu.2-Cl)2Cl2], [Cu4(M3)2(.mu.3-OEt)2(.mu.2-N3)2(N3)2](MeOH), [Cu4(M3)2(.mu.3-OMe)2(NCS)4](DMF), and [Cu(M3)(NCS)2]
Santokh. S. Tandon, Laurence K. Thompson, John N. Bridson, and Monica Bubenik
pp 4621 - 4631; DOI:
10.1021/ic00073a026
PDF
Synthesis and NMR spectra (phosphorus-31, cadmium-111/113, selenium-77) of adamantane-like phosphine complexes with the (.mu.-ER)6Cd4 core and the crystal and molecular structure of [(.mu.-SPri)6(CdPPh3)2(CdOClO3)2].cntdot.EtOH
Philip A. W. Dean, Nicholas C. Payne, Jagadese J. Vittal, and Yuyang Yu
pp 4632 - 4639; DOI:
10.1021/ic00073a027
PDF
Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex
Javier A. Cabeza, R. Jesus Franco, Angela Llamazares, Victor Riera, Claudette Bois, and Yves Jeannin
pp 4640 - 4642; DOI:
10.1021/ic00073a028
PDF
Oxidation of alcohols by hexanuclear cluster ions
Julie A. Jackson, Robert D. Mussell, and Daniel G. Nocera
pp 4643 - 4645; DOI:
10.1021/ic00073a029
PDF
An NMR study of the step by step pyrolysis of a polysilazane precursor of silicon nitride
Nancy Brodie, Jean Pierre Majoral, and Jean Pierre Disson
pp 4646 - 4649; DOI:
10.1021/ic00073a030
PDF
Methanothermal synthesis of two dimeric vanadium polyselenides, [V2O2Se10]4- and [V2O2Se8]4-
Ju Hsiou Liao, Laurie Hill, and Mercouri G. Kanatzidis
pp 4650 - 4652; DOI:
10.1021/ic00073a031
PDF
Synthesis and single-crystal x-ray structure of the diglyme-bridged barium complex [Ba(thd)2(diglyme)]2
Simon R. Drake, Michael B. Hursthouse, K. M. Abdul Malik, and Stewart A. S. Miller
pp 4653 - 4657; DOI:
10.1021/ic00073a032
PDF
Dinitrogen or dichloromethane?
Richard E. Marsh, Marilyn M. Olmstead, William P. Schaefer, and Verner Schomaker
pp 4658 - 4659; DOI:
10.1021/ic00073a033
PDF
Di-.mu.-sulfidotetrakis(triphenylphosphine)diplatinum as a metalloligand towards main-group Lewis acids. Crystal structures of two complex adducts of lead nitrate, [(PPh3)4Pt2(.mu.3-S)2Pb(NO3)2] and [(PPh3)4Pt2(.mu.3-S)2Pb(NO3)]PF6
Meisheng Zhou, Yan Xu, Choon Fui Lam, Lip Lin Koh, K. F. Mok, Pak Hing Leung, and T. S. Andy Hor
pp 4660 - 4662; DOI:
10.1021/ic00073a034
PDF
A monophenyl phenanthroline complex of copper(I) that binds to DNA but not by intercalation
Kelley A. Meadows, Fang Liu, Brian P. Hudson, and David R. McMillin
pp 4663 - 4666; DOI:
10.1021/ic00073a035
PDF
Synthesis and characterization of tetrakis(carbonyl)platinum(II) hexakis(fluorosulfato)platinate(IV), [Pt(CO)4][Pt(SO3F)6]
G. Hwang, M. Bodenbinder, H. Willner, and F. Aubke
pp 4667 - 4669; DOI:
10.1021/ic00073a036
PDF
Additions and Corrections - Oxygen Atom Transfer between Cis-Coordinated Nitrite and Nitrosyl Ligands: The Case of the CpCr(NO)2(NO2)/CpCr(NO)2(ONO) Linkage Isomers
John I. Hubbard, Christopher R. Zoch, and Wendy L. Elcesser
pp 4670 - 4670; DOI:
10.1021/ic00073a600
PDF

Issue 22


Facile transmetalation reactions of macrocyclic (C22H22N4) complexes of germanium(II), tin(II), and lead(II)
David A. Atwood, Vicki O. Atwood, Alan H. Cowley, Hala R. Gobran, and Jerry L. Atwood
pp 4671 - 4672; DOI:
10.1021/ic00074a001
PDF
Nitrido-technetium(V) complexes with amino acids: preparation and x-ray crystal structure of the L-cysteinate ethyl ester technetium(V) complex
Andrea Marchi, Roberto Rossi, Lorenza Marvelli, and Valerio Bertolasi
pp 4673 - 4674; DOI:
10.1021/ic00074a002
PDF
Synthesis and reactivity of tungsten pentacarbonyl hydroxo and bicarbonato complexes. Molecular structure of [PPN][W(CO)5HCO3], an organometallic analog for carbonic anhydrase
Donald J. Darensbourg, Monica L. Meckfessel Jones, and Joseph H. Reibenspies
pp 4675 - 4676; DOI:
10.1021/ic00074a003
PDF
Bioorganometallic chemistry. 4. The bonding role of carbonyl and amino functionalities in the reactions of guanine nucleobase derivatives with (.eta.5-pentamethylcyclopentadienyl)rhodium complexes in methanol and aqueous solutions
David P. Smith, Malaika T. Griffin, Marilyn M. Olmstead, Marcos F. Maestre, and Richard H. Fish
pp 4677 - 4678; DOI:
10.1021/ic00074a004
PDF
Straightforward synthesis of polyallylphosphazenes from poly(dichlorophosphazene)
Herve Rolland, Philippe Potin, Jean Pierre Majoral, and Guy Bertrand
pp 4679 - 4680; DOI:
10.1021/ic00074a005
PDF
Excited states of nitrogen, silicon-chelated transition metal complexes: characteristics of .sigma.-bond-to-ligand charge-transfer (SBLCT) excited states in fac-Ir[(6-isopropyl-8-quinolyl)diorganosilyl]3
Peter I. Djurovich and Richard J. Watts
pp 4681 - 4682; DOI:
10.1021/ic00074a006
PDF
Equilibria and kinetics of the reactions between hydrogen peroxide and methyltrioxorhenium in aqueous perchloric acid solutions
Shigekazu Yamazaki, James H. Espenson, and Patrick Huston
pp 4683 - 4687; DOI:
10.1021/ic00074a007
PDF
Kinetic study of .beta.-hydride elimination from monoalkyl solvento complexes of platinum(II)
Raffaello Romeo, Giuseppe Alibrandi, and Luigi Monsu Scolaro
pp 4688 - 4694; DOI:
10.1021/ic00074a008
PDF
Ab initio study of the coordination modes of tetrahydroborato ligands: structure of the tris(tetrahydroborato)titanium
Abdellah Jarid, Agusti Lledos, Yves Jean, and Francois Volatron
pp 4695 - 4699; DOI:
10.1021/ic00074a009
PDF
3-Dimensional Hueckel theory for cluster compounds
Ming Zhao and B. M. Gimarc
pp 4700 - 4707; DOI:
10.1021/ic00074a010
PDF
Ab initio theoretical study on geometries, chemical bonding, and infrared and electronic spectra of the M2O72- (M = chromium, molybdenum, tungsten) anions
Jordi Mestres, Miquel Duran, Pedro Martin-Zarza, Eduardo Medina de la Rosa, and Pedro Gili
pp 4708 - 4713; DOI:
10.1021/ic00074a011
PDF
Crystal structure and spectroscopic characterization of cesium vanadium sulfate CsV(SO4)2. Evidence for an electronic Raman transition
R. W. Berg, S. Boghosian, N. J. Bjerrum, R. Fehrmann, B. Krebs, N. Straeter, O. S. Mortensen, and G. N. Papatheodorou
pp 4714 - 4720; DOI:
10.1021/ic00074a012
PDF
Properties of PdI-PdI bonds. Theoretical and spectroscopic study of palladium Pd2(dmb)2X2 complexes (dmb = 1,8-diisocyano-p-menthane; X = Cl, Br)
Pierre D. Harvey and Zakir Murtaza
pp 4721 - 4729; DOI:
10.1021/ic00074a013
PDF
Nickel(II) complexes of the octaethyloxophlorin dianion and octaethyloxophlorin radical dianion
Alan L. Balch, Bruce C. Noll, Shane L. Phillips, Steven M. Reid, and Edward P. Zovinka
pp 4730 - 4736; DOI:
10.1021/ic00074a014
PDF
Cobalt complexes of octaethyloxophlorin. Metal-centered redox chemistry in the presence of a redox-active ligand
Alan L. Balch, Marinella Mazzanti, and Marilyn M. Olmstead
pp 4737 - 4744; DOI:
10.1021/ic00074a015
PDF
Fluoride-bridged dimers: binuclear copper(II) complexes and iron(III)-copper(II) assemblies
Sonny C. Lee and R. H. Holm
pp 4745 - 4753; DOI:
10.1021/ic00074a016
PDF
Biomimics of vanadium bromoperoxidase: Vanadium(V)-Schiff base catalyzed oxidation of bromide by hydrogen peroxide
Melissa J. Clague, Nancy L. Keder, and Alison Butler
pp 4754 - 4761; DOI:
10.1021/ic00074a017
PDF
Influence of chromium binding on the kinetics of aqueous chromium(II) reduction of the blue copper proteins azurin and stellacyanin
Lars K. Skov, Karsten Olsen, Ulla Christensen, and Ole Farver
pp 4762 - 4765; DOI:
10.1021/ic00074a018
PDF
Alkane oxidation catalyzed by .mu.-oxo-bridged diferric complexes: a structure/reactivity correlation study
Stephane Menage, Jean Marc Vincent, Claude Lambeaux, Genevieve Chottard, Andre Grand, and Marc Fontecave
pp 4766 - 4773; DOI:
10.1021/ic00074a019
PDF
Nature of the specific interaction of rhodium acetate dimer with adenosine
D. Waysbort, E. Tarien, and G. L. Eichhorn
pp 4774 - 4779; DOI:
10.1021/ic00074a020
PDF
Electron transfer. 119. Reductions of rhodium-bound superoxide
Sanchita Purohit Ghosh, E. Gelerinter, Gloria Pyrka, and E. S. Gould
pp 4780 - 4784; DOI:
10.1021/ic00074a021
PDF
Molecular orbital analysis of the intermediates and products generated by the photooxidation of iron pentacarbonyl
Paul D. Lyne, D. Michael P. Mingos, Tom Ziegler, and Anthony J. Downs
pp 4785 - 4796; DOI:
10.1021/ic00074a022
PDF
Magnetic interactions and magnetic ordering in rare earth metal nitronyl nitroxide chains
Cristiano Benelli, Andrea Caneschi, Dante Gatteschi, and Roberta Sessoli
pp 4797 - 4801; DOI:
10.1021/ic00074a023
PDF
Silylated compounds as transfer reagents with active carbon-chlorine, carbon-fluorine or sulfur-fluorine bonds
Nimesh R. Patel, Robert L. Kirchmeier, and Jean'ne M. Shreeve
pp 4802 - 4806; DOI:
10.1021/ic00074a024
PDF
Binding of copper(I) and copper(II) to the pendent O3-face of iron arylazo oximates: synthesis and structure of CuIFeII and CuIIFeII2 families
Vadivelu Manivannan, Somnath Dutta, Partha Basu, and Animesh Chakravorty
pp 4807 - 4811; DOI:
10.1021/ic00074a025
PDF
Optical resolutions and chelating properties of (.+-.)-[2-(methylsulfinyl)ethyl]diphenylarsine and its phosphorus analog
Simon Y. M. Chooi, Soh Yun Siah, Pak Hing Leung, and K. F. Mok
pp 4812 - 4818; DOI:
10.1021/ic00074a026
PDF
X-ray and neutron diffraction studies of tricarbonyl(.eta.-pentamethylcyclopentadienyl)hydridomolybdenum at 163 K
Lee Brammer, Dong Zhao, R. Morris Bullock, and Richard K. McMullan
pp 4819 - 4824; DOI:
10.1021/ic00074a027
PDF
Crystal structure of cesium (.mu.-oxo)bis(oxodisulfatovanadate) Cs4(VO)2O(SO4)4
Kurt Nielsen, Rasmus Fehrmann, and Kim Michael Eriksen
pp 4825 - 4828; DOI:
10.1021/ic00074a028
PDF
X-ray powder diffraction as a tool for facing twins: the case of the monoclinic niobium cobalt ditelluride and tantalum cobalt ditelluride phases
Jing Li, Frank McCulley, Susan L. McDonnell, Norberto Masciocchi, Davide M. Proserpio, and Angelo Sironi
pp 4829 - 4833; DOI:
10.1021/ic00074a029
PDF
Further neighbor magnetic exchange interaction in a novel pseudolinear tetramer of copper(II)
B. Chiari, O. Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 4834 - 4838; DOI:
10.1021/ic00074a030
PDF
Synthesis and characterization of the multidentate ligand 2,9-bis(N-pyrazolylmethyl)-1,10-phenanthroline (bpmp) and its copper(I) and copper(II) complexes
M. Athar Masood and Derek J. Hodgson
pp 4839 - 4844; DOI:
10.1021/ic00074a031
PDF
Complexes of functional phosphines. 22. Cobalt(II) complexes with .beta.-keto phosphines and corresponding cobalt(III) enolates. Crystal and molecular structures of the fac and mer isomers of [Co{Ph2PCHC(O)Ph}3]
Pierre Braunstein, David G. Kelly, Antonio Tiripicchio, and Franco Ugozzoli
pp 4845 - 4852; DOI:
10.1021/ic00074a032
PDF
Solid solutions of a Jahn-Teller compound in an undistorted host. 3. The chromium/zinc Tutton salt system
Miguel A. Araya, F. Albert Cotton, Lee M. Daniels, Larry R. Falvello, and Carlos A. Murillo
pp 4853 - 4860; DOI:
10.1021/ic00074a033
PDF
Hexaaqua dipositive ions of the first transition series: new and accurate structures; expected and unexpected trends
F. Albert Cotton, Lee M. Daniels, Carlos A. Murillo, and Jaime F. Quesada
pp 4861 - 4867; DOI:
10.1021/ic00074a034
PDF
X-ray structural characterization of a pair of isotypic tetraaqua compounds of the Jahn-Teller species chromium(II) and copper(II)
F. Albert Cotton, Lee M. Daniels, and Carlos A. Murillo
pp 4868 - 4870; DOI:
10.1021/ic00074a035
PDF
Preparation and structural characterization of molybdenum acetato phosphine dinuclear Mo2Cl4(OAc)2(PR3)2 compounds (R = Me, Et) and a comparative study of the singlet-triplet separation for Mo2Cl4(OAc)2(PEt3)2 with that for Mo2Cl6(dppm)2
F. Albert Cotton, Jianrui Su, Zhong Sheng Sun, and Hong Chen
pp 4871 - 4875; DOI:
10.1021/ic00074a036
PDF
Structural characterization of the first cyclotetramolybdenum diynes with bidentate phosphines, Mo4Cl4(.mu.-Cl)2(.mu.-OMe)2(.mu.-dppm)2 and Mo4Cl4(.mu.4-O)(.mu.-Cl)3(.mu.-OMe)3(.mu.-dmpm)2
F. Albert Cotton, Bo Hong, and Maoyu Shang
pp 4876 - 4881; DOI:
10.1021/ic00074a037
PDF
Tetradentate macrocyclic complexes of platinum. Evaluation of the stereochemical alterations of redox behavior and the x-ray crystal structure of (1,4,7,10-tetrathiacyclododecane)platinum(II) chloride
Murielle A. Watzky, David Waknine, Mary Jane Heeg, John F. Endicott, and L. A. Ochrymowyzc
pp 4882 - 4888; DOI:
10.1021/ic00074a038
PDF
Synthesis, structural characterization, and electrochemical behavior of copper(I) complexes of sterically hindered tris(3-tert-butyl- and 3,5-diphenylpyrazolyl)hydroborate ligands
Susan M. Carrier, Christy E. Ruggiero, Robert P. Houser, and William B. Tolman
pp 4889 - 4899; DOI:
10.1021/ic00074a039
PDF
Synthesis and ligational behavior toward hydrogen and copper(II) ions of the two new oxa-aza macrocyclic receptors 10,13,16-trimethyl-1,4-dioxa-7,10,13,16,19-pentaazacyclohenicosane (Me3[21]aneN5O2) and 13,16,19-trimethyl-1,4,7-trioxa-10,13,16,19,22-pentaazacyclotetracosane (Me3[24]aneN5O3)
Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Vieri Fusi, Enrique Garcia-Espana, Piero Paoletti, Paola Paoli, and Barbara Valtancoli
pp 4900 - 4908; DOI:
10.1021/ic00074a040
PDF
Coordination chemistry of 2-(2'-hydroxyphenyl)-2-benzoxazole with gallium(III) and aluminum(III): two uncommon Group 13 metal environments stabilized by a biologically relevant binding group
H. R. Hoveyda, Steven J. Rettig, and Chris Orvig
pp 4909 - 4913; DOI:
10.1021/ic00074a041
PDF
X-ray diffraction study of the molecular structure of a spherohydridosilasesquioxane, H10Si10O15, a flexible assembly of rigid tetrahedra
Hans Beat Buergi, Karl Wilhelm Toernroos, Gion Calzaferri, and Heribert Buergy
pp 4914 - 4919; DOI:
10.1021/ic00074a042
PDF
Synthesis and characterization of the cobalt(III) complexes with tetraaza macrocyclic ligands having strategically appended functional groups
Ruohua Zhang and Daryle H. Busch
pp 4920 - 4924; DOI:
10.1021/ic00074a043
PDF
Mononuclear and dinuclear ruthenium complexes containing the LRu(acac) fragment. Crystal structures of [LRuIII(acac)(OH)]PF6.cntdot.H2O, [{LRuIII(acac)}2(.mu.-O2H3)](PF6)3, and [{LRuIII(acac)}2(.mu.-O)](PF6)2. Characterization of the mixed-valence species [{LRu(acac)}2(.mu.-O)](PF6)3 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)
Ralf Schneider, Thomas Weyhermueller, Karl Wieghardt, and Bernhard Nuber
pp 4925 - 4934; DOI:
10.1021/ic00074a044
PDF
New .mu.-disulfido and .mu.-diselenido complexes of ruthenium(III). Crystal structure of [{LRuIII(acac)}2(.mu.-S2)](PF6)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; acac = pentane-2,4-dionate)
Ralf Schneider, Karl Wieghardt, and Bernhard Nuber
pp 4935 - 4939; DOI:
10.1021/ic00074a045
PDF
Ruthenium(II) complexes containing bis(2-(diphenylphosphino)ethyl)phenylphosphine and bis(3-(diphenylphosphino)propyl)phenylphosphine
Alberto Albinati, Qiongzhong Jiang, Heinz Ruegger, and Luigi M. Venanzi
pp 4940 - 4950; DOI:
10.1021/ic00074a046
PDF
Ternary metal(II) complexes with tyrosine-containing dipeptides. Structures of copper(II) and palladium(II) complexes involving L-tyrosylglycine and stabilization of copper(II) complexes due to intramolecular aromatic ring stacking
Tamotsu Sugimori, Kimio Shibakawa, Hideki Masuda, Akira Odani, and Osamu Yamauchi
pp 4951 - 4959; DOI:
10.1021/ic00074a047
PDF
(Diphenylphosphine)-, (diphenylphosphido)-, and (diphenylphosphinito)gold(I) complexes. Crystal structure of [(PPh3)2N][Au{P(O)Ph2}2]
Jose Vicente, Maria Teresa Chicote, and Peter G. Jones
pp 4960 - 4964; DOI:
10.1021/ic00074a048
PDF
Synthesis of a novel palladium(0) carbonyl complex containing a tridentate phosphorus ligand. X-ray crystal structure of [Pd(CO)(CH3C(CH2PPh2)3)]
J. Grevin, P. Kalck, J. C. Daran, J. Vaissermann, and C. Bianchini
pp 4965 - 4967; DOI:
10.1021/ic00074a049
PDF
Synthesis, structure, and reactivity of {.eta.3-HB(3-tert-Bupz)3}BeCH3, a terminal beryllium alkyl complex supported by tris(3-tert-butylpyrazolyl)hydroborato ligation
Runyu Han and Gerard Parkin
pp 4968 - 4970; DOI:
10.1021/ic00074a050
PDF
Formation of a bridging sulfide in chlorotris(1,2-ethanedithiolato)(.mu.3-sulfido)tris(triphenylphosphino)tetracobalt via disruption of the carbon-sulfur bond from dithiolate
Feilong Jiang, Zhiying Huang, Daxu Wu, Beisheng Kang, Maochun Hong, and Hanqin Liu
pp 4971 - 4973; DOI:
10.1021/ic00074a051
PDF
Synthesis, characterization, and crystal structure of hydroxyruthenocene
Karl Kirchner, Keh Shin Kwan, and Henry Taube
pp 4974 - 4975; DOI:
10.1021/ic00074a052
PDF
Novel crystal structure of a tetranuclear platinum complex: bis(.mu.4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II)) tetranitrate trihydrate
Hans K. Mahtani, Shih Chi Chang, John R. Ruble, Iona N. L. Black, and Paul B. Stein
pp 4976 - 4978; DOI:
10.1021/ic00074a053
PDF
Intramolecular hydrogen-bonding from heme carboxylic acid side chains to axial ligands
Kyoungja Woo and D. A. Sweigart
pp 4979 - 4981; DOI:
10.1021/ic00074a054
PDF
Spectroscopic and electrochemical characterization of the asymmetric bimetallic ruthenium(II) complex [(bpy)2RuII(bpym)RuII(NH3)4](PF6)4.cntdot.3H2O
Rick A. Pavinato, Jeff A. Walk, and Mark E. McGuire
pp 4982 - 4984; DOI:
10.1021/ic00074a055
PDF

Issue 23


Tris(acetato)bis(N,N,N',N'-tetramethylethylenediamine)(urea)dinickel(1+) triflate and [Ni(OAc)(urea)2(tmen)](OTf), model complexes for the enzyme urease
Heather E. Wages, Kingsley L. Taft, and Stephen J. Lippard
pp 4985 - 4987; DOI:
10.1021/ic00075a001
PDF
Spontaneous formation of a dicoordinate iminophosphine from a tricoordinate triaminophosphine via a tetracoordinate phosphorane
Neil Burford, Jason A. C. Clyburne, Simon Mason, and John F. Richardson
pp 4988 - 4989; DOI:
10.1021/ic00075a002
PDF
A dinucleating bis(dimethylcyclam) ligand and its dinickel(II) and dizinc(II) complexes with the face-to-face ring arrangement
Takashi Kajiwara, Tadashi Yamaguchi, Hiroaki Kido, Satoshi Kawabata, Reiko Kuroda, and Tasuku Ito
pp 4990 - 4991; DOI:
10.1021/ic00075a003
PDF
Synthesis and crystal structure of a dinuclear yttrium(III)- (lanthanide(III)-) copper(II) complex with an unusual 2-methyl-2,4,6-tris(trifluoromethyl)-1,3-dioxane-4,6-diolato ligand
Suning Wang, Zhen Pang, and Karen D. L. Smith
pp 4992 - 4993; DOI:
10.1021/ic00075a004
PDF
A chromophore-quencher-based luminescence probe for DNA
Nancy B. Thornton and Kirk S. Schanze
pp 4994 - 4995; DOI:
10.1021/ic00075a005
PDF
Tetranuclear platinum(II) cluster complexes having nonbridging chelate ligands in the plane of the square planer cluster core: [Pt4(CH3COO)4(en)4]Cl4.cntdot.4H2O and [Pt4(CH3COO)4(pic)4].cntdot.CH3OH.cntdot.4H2O (en = ethylenediamine; picH = picolinic acid)
Tadashi Yamaguchi, Tetsuji Ueno, and Tasuku Ito
pp 4996 - 4997; DOI:
10.1021/ic00075a006
PDF
Synthesis and characterization of (trialkylstannyl)hexacarbonyltitanate ([R3SnTi(CO)6]-), a new class of titanium carbonyls. Molecular structure of (tricyclohexylstannyl)hexacarbonyltitanate [(C6H11)3SnTi(CO)6]-
John E. Ellis and Pong Yuen
pp 4998 - 4999; DOI:
10.1021/ic00075a007
PDF
A new hydrotalcite-like compound containing vanadium(3+) ions in the layers
Vicente Rives, Francisco M. Labajos, Maria A. Ulibarri, and Pilar Malet
pp 5000 - 5001; DOI:
10.1021/ic00075a008
PDF
Photochemistry of peroxotitanium(IV) porphyrin. A novel photocleavage of the oxygen-oxygen bond
Mikio Hoshino, Kiyoko Yamamoto, Jerome P. Lillis, Tamiko Chijimatsu, and Jun Uzawa
pp 5002 - 5003; DOI:
10.1021/ic00075a009
PDF
Pair potentials and the ordered defect structure of niobium monoxide
Jeremy K. Burdett and John F. Mitchell
pp 5004 - 5006; DOI:
10.1021/ic00075a010
PDF
Synthesis of perhaloalkanesulfonyl halides and their sulfonimide derivatives
Li Qing Hu and Darryl D. DesMarteau
pp 5007 - 5010; DOI:
10.1021/ic00075a011
PDF
Perfluorovinylamines: reactions of the perfluorovinyl group with nucleophiles and electrophiles
Ashwani Vij, Robert L. Kirchmeier, Jeanne M. Shreeve, Takashi Abe, Haruhiko Fukaya, Eiji Hayashi, Yoshio Hayakawa, and Taizo Ono
pp 5011 - 5020; DOI:
10.1021/ic00075a012
PDF
Unsubstituted 1- and 2-phosphabutadienes: preparation and spectroscopic characterization
Jean Claude Guillemin, Jean Luc Cabioch, Xavier Morise, Jean Marc Denis, Sylvie Lacombe, Danielle Gonbeau, Genevieve Pfister-Guillouzo, Pierre Guenot, and Philippe Savignac
pp 5021 - 5028; DOI:
10.1021/ic00075a013
PDF
Novel aluminophosphate-based compounds with a layered structure and intercalation behavior
Bettina Kraushaar-Czarnetzki, Wim H. J. Stork, and Ronald J. Dogterom
pp 5029 - 5033; DOI:
10.1021/ic00075a014
PDF
Kinetics and mechanisms of the redox reactions of the hydroperoxochromium(III) ion
Wei Dong Wang, Andreja Bakac, and James H. Espenson
pp 5034 - 5039; DOI:
10.1021/ic00075a015
PDF
Nucleophilic activation of carbon monoxide. A kinetics investigation of the reaction of chloride with triruthenium dodecacarbonyl
Jerome Lillis, Andrzej Rokicki, Tyrena Chin, and Peter C. Ford
pp 5040 - 5043; DOI:
10.1021/ic00075a016
PDF
New lamellar oxophosphorus derivatives of nickel(II): x-ray powder diffraction structure determinations and magnetic studies of Ni(HPO3).H2O, NiCl(H2PO2).H2O, and NixCo1-x(HPO3).H2O solid solutions
M. Dolores Marcos, Pedro Amoros, Fernando Sapina, Aurelio Beltran-Porter, Ramon Martinez-Manez, and J. Paul Attfield
pp 5044 - 5052; DOI:
10.1021/ic00075a017
PDF
1-Alkyl-1-aza-closo-dodecaborane: a novel access to the icosahedral NB11 skeleton
Franc Meyer, Jens Mueller, Martin U. Schmidt, and Peter Paetzold
pp 5053 - 5057; DOI:
10.1021/ic00075a018
PDF
Synthesis and an ab initio/IGLO/NMR study of 7-vertex nido-phosphacarboranes: nido-6-R'-3,4-R2-6,3,4-PC2B4H4
Willi Keller, Beverly A. Barnum, Joseph W. Bausch, and Larry G. Sneddon
pp 5058 - 5066; DOI:
10.1021/ic00075a019
PDF
Synthesis of the 1- and 2-dimethyl sulfide.cntdot.undecaborane (13) isomers. Crystal structures of 2-Me2S.cntdot.B11H13 and 7-Me2S.cntdot.B11H13
David L. Keller, John G. Kester, John C. Huffman, and Lee J. Todd
pp 5067 - 5070; DOI:
10.1021/ic00075a020
PDF
Kinetic control of the oxidative coupling of [B2H4Fe2(CO)6][Li]2. X-ray crystal structures and interconversion of B,Fe-conjuncto-{B2H4Fe2(CO)6}2 and B,B-conjuncto-{B2H4Fe2(CO)6}2
Chang Soo Jun, Douglas R. Powell, Kenneth J. Haller, and Thomas P. Fehlner
pp 5071 - 5078; DOI:
10.1021/ic00075a021
PDF
Synthesis, properties, and reactions of new perfluorinated diketones
John D. O. Anderson, William T. Pennington, and Darryl D. DesMarteau
pp 5079 - 5083; DOI:
10.1021/ic00075a022
PDF
Synthesis and characterizations of a new bulky disilazane and two lithium disilazides
Lauren M. Atagi, David M. Hoffman, and David C. Smith
pp 5084 - 5087; DOI:
10.1021/ic00075a023
PDF
Reactivity and polymerization behavior of a pentachlorocyclocarbophosphazene, N3P2CCl5
Harry R. Allcock, Suzanne M. Coley, Ian Manners, Karyn B. Visscher, Masood Parvez, Oskar Nuyken, and Gerhard Renner
pp 5088 - 5094; DOI:
10.1021/ic00075a024
PDF
Polyoxoanions derived from tungstosilicate (A-.beta.-SiW9O3410-): synthesis, single-crystal structural determination, and solution structural characterization by tungsten-183 NMR and IR of titanotungstosilicate (A-.beta.-Si2W18Ti6O7714-)
Yin Lin, Timothy J. R. Weakley, Brian Rapko, and Richard G. Finke
pp 5095 - 5101; DOI:
10.1021/ic00075a025
PDF
Oxo fluorides of titanium and vanadium. Preparation and crystal structures of [Cp*TiF(.mu.-O)]4 and OVF2N:PPh3
Herbert W. Roesky, Iring Leichtweis, and Mathias Noltemeyer
pp 5102 - 5104; DOI:
10.1021/ic00075a026
PDF
Chemistry of the tetraselenidotungstate(2-): synthesis, NMR spectroscopy, and crystal structure of the selenium insertion product [NEt4]2[.mu.-WSe4][(SC4H3)SeCu]2
Christopher C. Christuk and James A. Ibers
pp 5105 - 5107; DOI:
10.1021/ic00075a027
PDF
Mononuclear tungsten(VI) phenylimido phenoxide and alkoxide complexes with intramolecular amine coordination: molecular structure of WCl3(=NPh)[OC6H2(CH2NMe2)2-2,6-Me-4]
Paul A. van der Schaaf, Jaap Boersma, Wilbert J. J. Smeets, Anthony L. Spek, and Gerard van Koten
pp 5108 - 5113; DOI:
10.1021/ic00075a028
PDF
Synthesis and characterization of rhenium complexes with the stabilizing ligand tetrakis(pyrazol-1-yl)borate
Angela Domingos, Joaquim Marcalo, Antonio Paulo, Antonio Pires de Matos, and Isabel Santos
pp 5114 - 5118; DOI:
10.1021/ic00075a029
PDF
Synthesis, characterization, and reactions of platinum and rhodium complexes of the hybrid phosphorus-nitrogen ligand 4-CH3C6H4C[N(SiMe3)](NPPh2): x-ray structures of [ML2(PPh2NHC(4-CH3C6H4)NH)]X (M = Pt, X = Cl; M = Rh, X = BF4)
Tristram Chivers, Katherine McGregor, and Masood Parvez
pp 5119 - 5125; DOI:
10.1021/ic00075a030
PDF
Synthesis and characterization of gold(I) thiolates, selenolates, and tellurolates: x-ray crystal structures of Au4[TeC(SiMe3)3]4, Au4[SC(SiMe3)3]4, and Ph3PAu[TeC(SiMe3)3]
Philip J. Bonasia, David E. Gindelberger, and John Arnold
pp 5126 - 5131; DOI:
10.1021/ic00075a031
PDF
Synthesis of arylbis[(triorganophosphine)gold(I)]oxonium tetrafluoroborates [RO(AuPR'3)2]+BF4-. Crystal structure of (8-quinolinyl)bis[(triphenylphosphine)gold(I)]oxonium tetrafluoroborate
Andreas Kolb, Peter Bissinger, and Hubert Schmidbauer
pp 5132 - 5135; DOI:
10.1021/ic00075a032
PDF
Hypervalent bismuth alkoxide dimer complexes: syntheses, structures, and thermal decompositions of [Bi(OCH(CF3)2)2(.mu.-OCH(CF3)2)(THF)]2 and [Bi(OC6F5)2(.mu.-OC6F5)Xn]2.cntdot.zY (X = Y = C7H8, n = 1, z = 1 or 2; X = THF, Y = C6H14, n = 2, z = 0 or 1)
Carolyn M. Jones, Michael D. Burkart, Robert E. Bachman, Deborah L. Serra, Shiou Jyh Hwu, and Kenton H. Whitmire
pp 5136 - 5144; DOI:
10.1021/ic00075a033
PDF
Azastannatranes: synthesis and structural characterization
Winfried Plass and John G. Verkade
pp 5145 - 5152; DOI:
10.1021/ic00075a034
PDF
New azastannatranes: substitution at the axial amide bond
Winfried Plass and John G. Verkade
pp 5153 - 5159; DOI:
10.1021/ic00075a035
PDF
Transition-metal complexes of (1S,2S,3R)-3-hydroxycamphorsultam
M. Fernanda N. N. Carvalho, Ana Cristina Consiglieri, M. Teresa Duarte, Adelino M. Galvao, Armando J. L. Pombeiro, and Rudolf Herrmann
pp 5160 - 5164; DOI:
10.1021/ic00075a036
PDF
Hexakis(triethylphosphine)octatelluridohexachromium and a molecule-based synthesis of chromium telluride, Cr3Te4
B. Hessen, T. Siegrist, T. Palstra, S. M. Tanzler, and M. L. Steigerwald
pp 5165 - 5169; DOI:
10.1021/ic00075a037
PDF
Synthesis of 12-metal clusters based on the ([Mo6Cl8]4+) core. X-ray structure of (PPN)2[Mo6Cli8{(.mu.-NC)Mn(CO)2Cp}a6]
Dean H. Johnston, Charlotte L. Stern, and Duward F. Shriver
pp 5170 - 5175; DOI:
10.1021/ic00075a038
PDF
Octamolybdenum oxo-pyrazolate clusters. Syntheses, characterization, and crystal and molecular structures of the Mo(V)/Mo(VI) and Mo(VI) octamolybdenum clusters Mo8(pz)6O18(pzH)6 and Mo8(pz)6O21(pzH)6
M. K. Ehlert, S. J. Rettig, A. Storr, R. C. Thompson, and J. Trotter
pp 5176 - 5182; DOI:
10.1021/ic00075a039
PDF
Complexes containing heteronuclear and homonuclear quadruple bonds. Preparation and characterization of bis[bis(dimethylphosphino)methane]tetrachloromolybdenumtungsten and Mo2X4(dmpm)2 (X = bromide, iodide)
F. A. Cotton, K. R. Dunbar, B. Hong, C. A. James, J. H. Matonic, and J. L. C. Thomas
pp 5183 - 5187; DOI:
10.1021/ic00075a040
PDF
Multiple bonds between transition metals and main-group elements. 124. Structures and reactivity of acylperrhenates
Wolfgang A. Herrmann, Werner R. Thiel, Fritz E. Kuehn, Richard W. Fischer, Matthias Kleine, Eberhardt Herdtweck, Wolfgang Scherer, and Janos Mink
pp 5188 - 5194; DOI:
10.1021/ic00075a041
PDF
Transition-metal (phosphinoalkyl)silanols: ligand functionality designed for surface attachment. Chemistry of P-coordinated [(diphenylphosphino)alkyl]dimethylsilanol complexes of ruthenium, rhodium, and iridium
Ron D. Brost, Gregg C. Bruce, Stephen L. Grundy, and Stephen R. Stobart
pp 5195 - 5200; DOI:
10.1021/ic00075a042
PDF
Synthesis, structural characterization, and reactivity of the (.eta.2-benzoato)iridium(III) hydride complex [mer-(Me3P)3Ir(.eta.2-O2CC6H5)(H)][PF6]
Folami T. Ladipo and Joseph S. Merola
pp 5201 - 5205; DOI:
10.1021/ic00075a043
PDF
Synthesis of some tetrahedral mixed metal platinum-gold clusters and x-ray crystal structure of [{Au(PCy3)}{Pt3(.mu.-CNXyl)2(.mu.-CO)(CNXyl)(PCy3)2}][PF6]
Daniel Imhof, Urs Burckhardt, Klaus Hermann Dahmen, Heinz Ruegger, Tobias Gerfin, and Volker Gramlich
pp 5206 - 5211; DOI:
10.1021/ic00075a044
PDF
Synthesis and structure of tetrabutylammonium hexakis(perfluorophenyl)bis(.mu.-tetrahydrothiophene)diplatinum argentate(1-), a trinuclear compound displaying two structurally different anions in the solid state
R. Uson, J. Fornies, L. R. Falvello, M. Tomas, J. M. Casas, and A. Martin
pp 5212 - 5215; DOI:
10.1021/ic00075a045
PDF
Syntheses, structures, 113Cd solution NMR chemical shifts, and investigations of fluxional processes of bis[poly(pyrazolyl)borato]cadmium complexes
Daniel L. Reger, Scott S. Mason, Arnold L. Rheingold, and Robert L. Ostrander
pp 5216 - 5222; DOI:
10.1021/ic00075a046
PDF
Mixed-valence state of halo-1'-ethylbiruthenocenium(II,IV)+ Y- and halo-1'-acetylbiruthenocenium(II,IV)+ Y- salts
Masanobu Watanabe, Toschitake Iwamoto, Hirotoshi Sano, and Izumi Motoyama
pp 5223 - 5227; DOI:
10.1021/ic00075a047
PDF
Photoinduced energy and electron transfer processes in supramolecular species, tris(bipyridine) complexes of ruthenium(II)/osmium(II), Ru(II)/Ru(III), Os(II)/Os(III), and Ru(II)/Os(III) separated by a rigid spacer
Luisa De Cola, Vincenzo Balzani, Francesco Barigelletti, Lucia Flamigni, Peter Belser, Alex von Zelewsky, Michael Frank, and Fritz Voegtle
pp 5228 - 5238; DOI:
10.1021/ic00075a048
PDF
Electrochemistry and absorption and emission spectroscopy of new orthometalated complexes of rhodium(III) and iridium(III) with the ligands 1,4,5,8-tetraazaphenanthrene and 1,4,5,8,9,12-hexaazatriphenylene
P. Didier, I. Ortmans, A. Kirsch-De Mesmaeker, and R. J. Watts
pp 5239 - 5245; DOI:
10.1021/ic00075a049
PDF
Matrix isolation spectroscopic study of the 1/1 complexes of trimethylgallium with Group VI alkyls
Elizabeth A. Piocos and Bruce S. Ault
pp 5246 - 5250; DOI:
10.1021/ic00075a050
PDF
Spectroscopically distinct geometrical isomers in a single crystal. Characterization of the eight-coordinate adducts of tris(dipivaloylmethanato)lanthanide(III) with 2,9-dimethyl-1,10-phenanthroline
Richard C. Holz and Larry C. Thompson
pp 5251 - 5256; DOI:
10.1021/ic00075a051
PDF
Metal complexes of macrocyclic ligands containing pyridine
Judite Costa and Rita Delgado
pp 5257 - 5265; DOI:
10.1021/ic00075a052
PDF
Synthesis and characterization of iron and cobalt clathrochelate complexes derived from oxime-hydrazone ligands
Joseph J. Grzybowski, R. Daniel Allen, Judy A. Belinski, Kelly L. Bieda, Todd A. Bish, Patricia A. Finnegan, Matthew L. Hartenstein, Craig S. Regitz, Diane M. Ryalls, and et al.
pp 5266 - 5272; DOI:
10.1021/ic00075a053
PDF
1,3,5-Triamino-1,3,5-trideoxy-cis-inositol, a ligand with a remarkable versatility for metal ions. 5. Complex formation with magnesium(II), calcium(II), strontium(II), barium(II), and cadmium(II)
Kaspar Hegetschweiler, Robert D. Hancock, Michele Ghisletta, Thomas Kradolfer, Volker Gramlich, and Helmut W. Schmalle
pp 5273 - 5284; DOI:
10.1021/ic00075a054
PDF
Synthesis and reactivity of the linkage isomers of pentaammine(glycinamide)cobalt(III)
Patricia M. Angus, W. Gregory Jackson, and Alan M. Sargeson
pp 5285 - 5290; DOI:
10.1021/ic00075a055
PDF
Molybdenum oxo nitrosyl complexes. 1. Defect Lindqvist compounds of the type [Mo5O13(OR)4(NO)]3- (R = CH3, C2H5). Solid-state interactions with alkali-metal cations
Anna Proust, Pierre Gouzerh, and Francis Robert
pp 5291 - 5298; DOI:
10.1021/ic00075a056
PDF
Molybdenum oxo nitrosyl complexes. 2. Molybdenum-95 NMR studies of defect and complete Lindqvist-type derivatives. Crystal and molecular structure of (n-Bu4N)2[Mo6O17(OCH3)(NO)]
Anna Proust, Rene Thouvenot, Francis Robert, and Pierre Gouzerh
pp 5299 - 5304; DOI:
10.1021/ic00075a057
PDF
High-pressure single-crystal x-ray diffraction study of two spin-crossover iron(II) complexes: Fe(Phen)2(NCS)2 and Fe(Btz)2(NCS)2
Thierry Granier, Bernard Gallois, Jacques Gaultier, Jose Antonio Real, and Jacqueline Zarembowitch
pp 5305 - 5312; DOI:
10.1021/ic00075a058
PDF
Dinuclear rhodium(I) and iridium(I) dicarboxytriazolate complexes and their oxidation products. Crystal structures of [NBu4][Rh2(Dcbt)(CO)4].cntdot.0.4CH2Cl2 and [NBu4][Rh2(Dcbt)(CO)2(PPh3)2]
G. Net, J. C. Bayon, P. Esteban, P. G. Rasmussen, A. Alvarez-Larena, and J. F. Piniella
pp 5313 - 5321; DOI:
10.1021/ic00075a059
PDF
Synthesis, structure, and spectroscopic characterization of bismuth citrate compounds and bismuth-containing ulcer healing agent colloidal bismuth subcitrate (CBS). 3. Crystal and solution structures of K(NH4)[Bi2(cit)2(H2O)2](H2O)x (x = 2, 4)
Eiji Asato, Kosho Katsura, Masahiro Mikuriya, Toshinori Fujii, and Jan Reedijk
pp 5322 - 5329; DOI:
10.1021/ic00075a060
PDF
A dicopper(I) complex and its oxygenation chemistry using a dinucleating ligand with a pendant alkene group
Indrajit Sanyal, Narasappa Narasimha Murthy, and Kenneth D. Karlin
pp 5330 - 5337; DOI:
10.1021/ic00075a061
PDF
Preparation and structures of two sterically protected ruthenium porphyrin compounds of the type Ru(Por)(H2O)in(CO)out
Carla Slebodnick, Kimoon Kim, and James A. Ibers
pp 5338 - 5342; DOI:
10.1021/ic00075a062
PDF
Chemistry of mononuclear and binuclear oxidic vanadium(V), VVVV, and VVVIV azophenolates
Somnath Dutta, Partha Basu, and Animesh Chakravorty
pp 5343 - 5348; DOI:
10.1021/ic00075a063
PDF
Thioether binding of manganese oxidation states. Chemistry of an MnII,IIIS2N2O2 family
Partha Chakraborty, Swapan Kumar Chandra, and Animesh Chakravorty
pp 5349 - 5353; DOI:
10.1021/ic00075a064
PDF
trans-Chlorotetracarbonyl(phenylmethylidyne)chromium: experimental electron deformation density
Anne Spasojevic-de Bire, Nguyen Quy Dao, Ernst Otto Fischer, and Niels K. Hansen
pp 5354 - 5361; DOI:
10.1021/ic00075a065
PDF
Binding of cyanide and thiocyanate to manganese reconstituted myoglobin and formation of peroxide compound: optical spectral, multinuclear NMR, and kinetic studies
Madhu Sudan Mondal, Shyamalava Mazumdar, and Samaresh Mitra
pp 5362 - 5367; DOI:
10.1021/ic00075a066
PDF
Reactivity of superoxide toward iron(II) complexes with pentadentate and hexadentate ligands derived from cyclononane
Witold S. Szulbinski, P. Richard Warburton, and Daryle H. Busch
pp 5368 - 5376; DOI:
10.1021/ic00075a067
PDF
Solvent-dependent metal ion-adenine recognition. Quantification of the intramolecular equilibria between various isomers of the copper(2+) complexes formed in water-dioxane mixtures with the anions of the antiviral 9-(2-(phosphonomethoxy)ethyl)adenine (PMEA), an adenosine monophosphate (AMP) analog
Dong Chen, Fridrich Gregan, Antonin Holy, and Helmut Sigel
pp 5377 - 5384; DOI:
10.1021/ic00075a068
PDF
Oxalate-bridged dinuclear chromium(III)-M(II) (M = copper, nickel, cobalt, iron, manganese) complexes: synthesis, structure, and magnetism
Masaaki Ohba, Hiroko Tamaki, Naohide Matsumoto, and Hisashi Okawa
pp 5385 - 5390; DOI:
10.1021/ic00075a069
PDF
Redox-induced linkage isomerizations of acrylamide complexes of pentaammineruthenium(II) and -(III)
Nestor E. Katz and Florencia Fagalde
pp 5391 - 5393; DOI:
10.1021/ic00075a070
PDF
Synthesis and pyrolysis studies of [(tert-Bu)2GaPR2]x
A. A. Naiini, Y. Han, M. Akinc, and J. G. Verkade
pp 5394 - 5395; DOI:
10.1021/ic00075a071
PDF
First convenient route to classical molybdenum(III) ammine complexes. Preparation and characterization of fac-Mo(NH3)3(CF3SO3)3
Claus J. H. Jacobsen, Joergen Villadsen, and Hoegni Weihe
pp 5396 - 5397; DOI:
10.1021/ic00075a072
PDF
A new cationic palladium(I) dinuclear complex with a short Pd-Pd bond having P.intrsec.O.intrsec.N tridentate bridges. Preparation and structure
Kazuhide Tani, Shingo Nakamura, Tsuneaki Yamagata, and Yasutaka Kataoka
pp 5398 - 5401; DOI:
10.1021/ic00075a073
PDF
Chromium(II) and chromium(III) tri-tert-butoxysiloxy complexes
Karl W. Terry, Peter K. Gantzel, and T. Don Tilley
pp 5402 - 5404; DOI:
10.1021/ic00075a074
PDF
Acid-catalyzed hydrolysis of the carbonatobis(ethylenediamine)cobalt(1+) ion revisited
D. A. Buckingham and C. R. Clark
pp 5405 - 5407; DOI:
10.1021/ic00075a075
PDF
Structural variations in the [Mo4As6O20(OH)2]4- core: influence of cation structure on molybdenum...molybdenum distances
M. Ishaque Khan, Qin Chen, and Jon Zubieta
pp 5408 - 5411; DOI:
10.1021/ic00075a076
PDF
Synthesis, structure, and properties of the [Mo2Q2(.mu.-Se)2(.eta.2-Se2)2]2- (Q = O, Se) ions: influence of Mo-Q .pi.-bonding
Bryan W. Eichhorn, Donna R. Gardner, Ann Nichols-Ziebarth, Kazi J. Ahmed, and Simon G. Bott
pp 5412 - 5414; DOI:
10.1021/ic00075a077
PDF
Ionic liquid mediated synthesis and x-ray crystal structure of trans-difluorotetrakis- (1-methylimidazole)iron(III) tetrafluoroborate
Sean Christie, S. Subramanian, Lihong Wang, and Michael J. Zaworotko
pp 5415 - 5417; DOI:
10.1021/ic00075a078
PDF
Characterization of new tungsten(VI) amide complexes
Steven Dietz, V. Allured, and M. Rakowski DuBois
pp 5418 - 5420; DOI:
10.1021/ic00075a079
PDF

Christoph Elschenbroich, Annette Bretschneider-Hurley, James Hurley, Werner Massa, Sigrid Wocadlo, Juergen Pebler, and Edward Reijerse
pp 5421 - 5424; DOI:
10.1021/ic00075a080
PDF

Issue 24


Reactions of singlet oxygen with organometallic complexes. 2. Formation of a metastable rhodium-dioxygen complex
Matthias Selke, Christopher S. Foote, and William L. Karney
pp 5425 - 5426; DOI:
10.1021/ic00076a001
PDF
Bismuth calcium titanium sulfide [Bi6-xCaxTi5S16 (x = 3.08)]: the first example of a commensurate structure in the class of misfit-layer compounds
Yi Chung Hung and Shiou Jyh Hwu
pp 5427 - 5428; DOI:
10.1021/ic00076a002
PDF
Synthesis and reactivity of the phosphinidene cluster complex Fe3(CO)9(.mu.3-PH)2: a versatile cluster building-block
Maria T. Bautista, Michael R. Jordan, Peter S. White, and Cynthia K. Schauer
pp 5429 - 5430; DOI:
10.1021/ic00076a003
PDF
Heterobimetallic aggregates of copper(I) with thiovanadate. Syntheses and characterizations of (Et4N)3[VS4Cu4(OC4H8dtc)n(PhS)4-n] (n = 0, 1, 2)
Yu Yang, Qiutian Liu, Liangren Huang, Daxu Wu, Beisheng Kang, and Jiaxi Lu
pp 5431 - 5432; DOI:
10.1021/ic00076a004
PDF
Crystal and molecular structure and magnetism of (.mu.-terephthalato)bis[(N-(2-diethylamino)ethyl)salicylidenaminato)copper(II)]-water-methanol
C. E. Xanthopoulos, M. P. Sigalas, G. A. Katsoulos, C. A. Tsipis, A. Terzis, M. Mentzafos, and A. Hountas
pp 5433 - 5436; DOI:
10.1021/ic00076a005
PDF
Dicarbonyltungsten(II) thiolate complexes of hydridotris(3,5-dimethylpyrazolyl)borate
C. C. Philipp, C. G. Young, P. S. White, and J. L. Templeton
pp 5437 - 5443; DOI:
10.1021/ic00076a006
PDF
Insertion of zinc into the cyclophosphazene skeleton: synthesis and structure of six-membered-ring complexes of zinc
Sushil K. Pandey, Alexander Steiner, Herbert W. Roesky, and Dietmar Stalke
pp 5444 - 5446; DOI:
10.1021/ic00076a007
PDF
Syntheses, spectroscopy, structures, and conformations of .lambda.3-cyclotriphosphazanes: role of negative hyperconjugation
Ramaswamy Murugavel, Setharampattu Krishnamurthy, Jayaraman Chandrasekhar, and Munirathinam Nethaji
pp 5447 - 5453; DOI:
10.1021/ic00076a008
PDF
Isolation and x-ray molecular structure of the first oxo- and phosphanido-bridged diniobium(III) complex with a short double Nb:Nb bond. Oxidation of the dichloro(pentamethylcyclopentadienyl)niobium(III) dimer
Javier de la Mata, Manuel Gomez, Pilar Gomez-Sal, and Pascual Royo
pp 5454 - 5457; DOI:
10.1021/ic00076a009
PDF
Effects on molecular association, chelate conformation, and reactivity toward substitution in copper Cu(5-X-salen) complexes, salen2- = N,N'-ethylenebis(salicylidenaminato), X = H, CH3O, and Cl: synthesis, x-ray structures, and EPR investigations
Mohan M. Bhadbhade and D. Srinivas
pp 5458 - 5466; DOI:
10.1021/ic00076a010
PDF
New carbon sulfides based on 4,5-dimercapto-1,2-dithiole-3-thione (.beta.-C3S52-): [C3S5]n, C6S8, and C5S7
Daniel D. Doxsee, Collin P. Galloway, Thomas B. Rauchfuss, Scott R. Wilson, and Xiaoguang Yang
pp 5467 - 5471; DOI:
10.1021/ic00076a011
PDF
Kinetics of heterolysis of pentaaquachromium(III) complexes of benzyl and 4-methyl, cyano and fluoro-substituted benzyl ligands
Zhongsheng Zhang and R. B. Jordan
pp 5472 - 5476; DOI:
10.1021/ic00076a012
PDF
Di-, tri-, and tetrametallic double-stranded helical complexes derived from alkylthio-substituted septipyridines: synthesis, structure, and redox properties
Kevin T. Potts, Majid Keshavarz-K, Fook S. Tham, Kimberly A. Gheysen Raiford, Claudia Arana, and Hector D. Abruna
pp 5477 - 5484; DOI:
10.1021/ic00076a013
PDF
Photoredox chemistry of chloromercurate(II) complexes in acetonitrile
Otto Horvath and Arnd Vogler
pp 5485 - 5489; DOI:
10.1021/ic00076a014
PDF
Modulation of reactivity and stereochemistry of substrate binding by the group X in RuHX(CO)(P-tert-Bu2Me)2
Jason T. Poulton, Michael P. Sigalas, Odile Eisenstein, and Kenneth G. Caulton
pp 5490 - 5501; DOI:
10.1021/ic00076a015
PDF
Oxo complexes, pH effects, and catalysis in films formed by electropolymerization
Ana R. Guadalupe, Xiaohong Chen, B. Patrick Sullivan, and Thomas J. Meyer
pp 5502 - 5512; DOI:
10.1021/ic00076a016
PDF
Photoinduced addition of oxygen ion (O-) to perbromate in a crystalline matrix: a pentacoordinated bromine(VIII) species studied by ESR
J. R. Byberg
pp 5513 - 5516; DOI:
10.1021/ic00076a017
PDF
Structural characterization of various dirhodium compounds using fast atom bombardment and collision-induced dissociation mass spectrometry
Johnny D. Reynolds, James L. E. Burn, Bill Boggess, Kelsey D. Cook, and Clifton Woods
pp 5517 - 5521; DOI:
10.1021/ic00076a018
PDF
XPS/FTIR study of the interaction between nitric oxide and yttrium barium copper oxide (YBa2Cu3O7)
Jianyi Lin, Andrew T. S. Wee, Kuang Lee Tan, Koon Gee Neoh, and Wah Koon Teo
pp 5522 - 5527; DOI:
10.1021/ic00076a019
PDF
Kinetic and thermodynamic products in the reaction of poly(dichlorodicarbonylruthenium) with pyridinecarbaldimine ligands and the crystal structure of trans-Cl2Ru(CO)2(N-(pyrid-2-ylmethoxymethyl)(3-isopropoxypropyl)amine)
Barbara de Klerk-Engles, Hans Werner Fruhauf, Kees Vrieze, Huub Kooijman, and Anthony L. Spek
pp 5528 - 5535; DOI:
10.1021/ic00076a020
PDF
Synthesis and characterization of novel types of adducts of nickel carbonyl clusters with indium halides: x-ray structures of [NEt4]3[Ni6(.mu.3-InBr3)(.eta.2-.mu.6-In2Br5)(CO)11].cntdot.Me2CO, [NEt4]4[Ni6(.eta.2-.mu.6-In2Br5)2(CO)10].cntdot.Me2CO, and [NEt4]4[Ni12(.mu.6-In)(.eta.2-.mu.6-In2Br4OH)(CO)22]
Francesco Demartin, Maria Carmela Iapalucci, and Giuliano Longoni
pp 5536 - 5543; DOI:
10.1021/ic00076a021
PDF
Coupling of acetylenes held proximate to a metal: alkyne-alkyne interactions in cis-phosphinoacetylene complexes, including structural characterization of the unsymmetrical diphosphine 1-phenyl-2,3-bis(diphenylphoshino)naphthalene and three platinum(II) complexes of Ph2PC.tplbond.CPh
David K. Johnson, Thitima Rukachaisirikul, Yan Sun, Nicholas J. Taylor, Allan J. Canty, and Arthur J. Carty
pp 5544 - 5552; DOI:
10.1021/ic00076a022
PDF
Reactions of tertiary phosphines, phosphites, and arsines with [Ru(.eta.5-C5H5)(.eta.4-C5H4O)]+ derivatives: x-ray structures of [Ru(.eta.5-C5H4PCy3)(.eta.5-C5H4OH)]+, [Ru(.eta.5-C5H5)(.eta.4-C5H4O)(P(OPh)3]+, and [Ru(.eta.5-C5H5)(.eta.4-C5H3O-2-PPh3)(MeCN)2+
Karl Kirchner, Kurt Mereiter, Roland Schmid, and Henry Taube
pp 5553 - 5561; DOI:
10.1021/ic00076a023
PDF
Reactions of the polyhydride complex ReH7(PPh3)2 with quinoline, 2-hydroxyquinoline, and 2-mercaptoquinoline. The preparation and characterization of hydrido complexes of rhenium(V) and chloro complexes of rhenium(III)
Malee Leeaphon, Kymberly Rohl, Robert J. Thomas, Phillip E. Fanwick, and Richard A. Walton
pp 5562 - 5568; DOI:
10.1021/ic00076a024
PDF
Molybdenum and tungsten complexes of S2CPMe3 and related ligands. Crystal and molecular structures of W(.eta.3-S2CPMe3)(CO)2(PMe3)2, [Mo(.eta.2-S2C(H)PMe3)(CO)2(PMe3)2]BF4, and [Mo(.eta.3-SC(SMe)PMe3)(CO)2(PMe3)2]I
Agustin Galindo, Enrique Gutierrez-Puebla, Angeles Monge, Antonio Pastor, Antonio Pizzano, Caridad Ruiz, Luis Sanchez, and Ernesto Carmona
pp 5569 - 5575; DOI:
10.1021/ic00076a025
PDF
Structural isomers of [Au(CH2)2PPh2]2Br4. 2. Crystal structures of cis/cis-[Au(CH2)2PPh2]2Br4 and the cationic A-frame [(.mu.-Br)(Au(CH2)2PPh2)2Br2][IBr2]
Raphael G. Raptis, H. H. Murray, Richard J. Staples, Leigh C. Porter, and John P. Fackler
pp 5576 - 5581; DOI:
10.1021/ic00076a026
PDF
Californium-252 plasma desorption mass spectrometry of gold clusters: fragmentation patterns in small clusters and differences in sample composition in large clusters
C. J. McNeal, J. M. Hughes, L. H. Pignolet, L. T. J. Nelson, T. G. Gardner, J. P. Fackler, R. E. P. Winpenny, L. H. Irgens, G. Vigh, and R. D. Macfarlane
pp 5582 - 5590; DOI:
10.1021/ic00076a027
PDF
Ruthenium(II) complexes of a fused phenanthroline-pteridinedione ligand
Kirk J. Black, Huakai Huang, Stacie High, Lee Starks, Mark Olson, and Mark E. McGuire
pp 5591 - 5596; DOI:
10.1021/ic00076a028
PDF
Kinetics of the tris(1,10-phenanthroline)cobalt(III/II) self-exchange reaction in aqueous solution at variable pressure
Michael R. Grace and Thomas W. Swaddle
pp 5597 - 5602; DOI:
10.1021/ic00076a029
PDF
A molecular mechanics model of ligand effects. 5. Ligand repulsive energy values for phosphines and phosphites bound to CpRh(CO) and the crystal structure of CpRh(CO)(PPh3)
Moon Gun Choi and Theodore L. Brown
pp 5603 - 5610; DOI:
10.1021/ic00076a030
PDF
Electronic structures of nitridometalates: molecular and extended-chain ions
Michael T. Green and Timothy Hughbanks
pp 5611 - 5615; DOI:
10.1021/ic00076a031
PDF
Transition metal derivatives of a chelating nitronyl nitroxide ligand. Nickel(II) and manganese(II) complexes
Dominique Luneau, Gerard Risoan, Paul Rey, Andre Grand, Andrea Caneschi, Dante Gatteschi, and Jean Laugier
pp 5616 - 5622; DOI:
10.1021/ic00076a032
PDF
Synthesis and characterization of hexakis(trimethylsilyl)digermane and -distannane
Siva P. Mallela and R. A. Geanangel
pp 5623 - 5625; DOI:
10.1021/ic00076a033
PDF
The cerium(IV)/cerium(III) electrode potential in hydrochloric acid solution
Andrew W. Maverick and Qin Yao
pp 5626 - 5628; DOI:
10.1021/ic00076a034
PDF
Luminescence of rhenium(I) complexes with highly sterically hindered .alpha.-diimine ligands
Arden P. Zipp, LouAnn Sacksteder, Julie Streich, Andrew Cook, J. N. Demas, and B. A. DeGraff
pp 5629 - 5632; DOI:
10.1021/ic00076a035
PDF
Luminescence characterizations of cyclometalated rhenium(I) carbonyl complexes
Peter Spellane, Richard J. Watts, and Arnd Vogler
pp 5633 - 5636; DOI:
10.1021/ic00076a036
PDF
Porphyrin vs phthalocyanine metallomacrocycles based one-dimensional "molecular metals". Insights from density functional calculations
Angela Rosa and Evert Jan Baerends
pp 5637 - 5639; DOI:
10.1021/ic00076a037
PDF
The diazidoiodine(1+) cation: preparation, identification by Raman spectroscopy, and ab initio quantum mechanical studies
Inis C. Tornieporth-Oetting, Thomas M. Klapoetke, Axel Schulz, Peter Buzek, and Paul v. R. Schleyer
pp 5640 - 5642; DOI:
10.1021/ic00076a038
PDF
"Solvent-free" impregnation of dinuclear metal complexes into polyethylene: use of supercritical carbon dioxide and the in situ photochemical assembly of decacarbonyldimanganese from hydridomanganese pentacarbonyl
Matthew J. Clarke, Steven M. Howdle, Margaret Jobling, and Martyn Poliakoff
pp 5643 - 5644; DOI:
10.1021/ic00076a039
PDF

Issue 25


Osmium(VI) complexes of tetrathiotungstate
Patricia A. Shapley, Zewdu Gebeyehu, Naijie Zhang, and Scott R. Wilson
pp 5646 - 5651; DOI:
10.1021/ic00077a001
PDF
Synthesis and evaluation of the bonding properties of 2,5-bis(2-(diphenylphosphino)ethyl)thiophene: a new potentially tridentate ligand
Marie Alvarez, Noel Lugan, and Rene Mathieu
pp 5652 - 5657; DOI:
10.1021/ic00077a002
PDF
Octahedral d6 bis(maleimide) and bis(maleic anhydride) complexes of molybdenum
Chen Hsing Lai, Chien Hong Cheng, Fen Ling Liao, and Sue Lein Wang
pp 5658 - 5664; DOI:
10.1021/ic00077a003
PDF
Phosphorus-mediated gold aggregation on a metal cluster: syntheses, structures, dynamic behavior, and ligand addition reactions of the clusters (.mu.-H)nFe3(CO)9P[Au(PR3)]3-n (n = 0, 1, 2)
Deborah L. Sunick, Peter S. White, and Cynthia K. Schauer
pp 5665 - 5675; DOI:
10.1021/ic00077a004
PDF
Heterodifunctional ligands derived from monooxidized bis(phosphino)amines. Synthesis and transition metal (molybdenum(O), tungsten(O), rhodium(I), palladium(II), and platinum(II)) complexes of (diphenylphosphino)(diphenylphosphinothiolyl)- and (diphenylphosphino)(diphenylphosphinoselenoyl)phenylamine, Ph2PN(Ph)P(E)Ph2 (E = S, Se). Crystal and molecular structure of the Pt(II) complex [Cl2Pt(PPh2N(Ph)P(S)Ph2].cntdot.H2O
Maravanji S. Balakrishna, Rita Klein, Stephen Uhlenbrock, A. Alan Pinkerton, and Ronald G. Cavell
pp 5676 - 5681; DOI:
10.1021/ic00077a005
PDF
Preparation and properties of the d0 (.eta.5-C5Me5)Ta(:NR)2 functional group
Theodore C. Baldwin, Susan R. Huber, Michael A. Bruck, and David E. Wigley
pp 5682 - 5686; DOI:
10.1021/ic00077a006
PDF
Crystal structure and metamagnetic behavior of the ferrimagnetic chain compound MnCu(opba)(H2O)2.cntdot.DMSO (opba = o-phenylenebis(oxamato) and DMSO = dimethyl sulfoxide)
Humberto O. Stumpf, Yu Pei, Lahcene Ouahab, Francoise Le Berre, Epiphane Codjovi, and Olivier Kahn
pp 5687 - 5691; DOI:
10.1021/ic00077a007
PDF
Resolution of a planar-chiral platinum(II) complex. Crystal and molecular structure of [SP-4-2-A]-(+)589-[PtCl(achiraphos)(R-PMenPh2)]PF6[achiraphos = (R*,S*)-2,3-bis(diphenylphosphino)butane; R-PMenPh2 = [1(R)-(1.alpha.,2.beta.,5.alpha.)]-diphenylmenthylphosphine]
Paul Gugger, Stephan O. Limmer, Andrew A. Watson, Anthony C. Willis, and S. Bruce Wild
pp 5692 - 5696; DOI:
10.1021/ic00077a008
PDF
A weak antiferromagnetic interaction between manganese(2+) centers through a TCNQ column: crystal structures and magnetic properties of [MnII(tpa)(TCNQ)(CH3OH)](TCNQ)2.cntdot.CH3CN, [MnII(tpa)(.mu.-O2CCH3)]2(TCNQ)2.cntdot.2CH3CN, and [MnII(tpa)(NCS)2].cntdot.CH3CN (tpa = tris(2-pyridylmethyl)amine)
Hiroki Oshio, Etsuo Ino, Iwao Mogi, and Tasuku Ito
pp 5697 - 5703; DOI:
10.1021/ic00077a009
PDF
A dimeric calcium siloxide lightly stabilized by ammonia ligands
Jawwad A. Darr, Simon R. Drake, Michael B. Hursthouse, and K. M. Abdul Malik
pp 5704 - 5708; DOI:
10.1021/ic00077a010
PDF
Stoichiometry of sodium(+)- and carbonate-containing apatites obtained by hydrolysis of monetite
Erna A. P. De Maeyer, Ronald M. H. Verbeeck, and Didier E. Naessens
pp 5709 - 5714; DOI:
10.1021/ic00077a011
PDF
Synthesis, structure, and magnetism of barium vanadium oxide (BaVO2.8): a new perovskite-related vanadate with VIII/VIV ordering
B. H. Chen, B. W. Eichhron, H. L. Ju, and R. L. Greene
pp 5715 - 5719; DOI:
10.1021/ic00077a012
PDF
(Dialkylamino)phosphorus metal carbonyls. 11. Addition of the (iso-Pr2NP)2Fe2(CO)6 unit to C:O, C.tplbond.N, and C:C multiple bonds
Y. W. Li, M. G. Newton, and R. B. King
pp 5720 - 5729; DOI:
10.1021/ic00077a013
PDF
Correlations between optical charge transfer energies and electrochemical data: the iron(III)-catecholato system
Andrea Dei
pp 5730 - 5733; DOI:
10.1021/ic00077a014
PDF
The ClSeNSeCl+ cation. An unusual structurally very flexible ion adopting different solid-state structures as deduced by x-ray and ab initio methods
Matthias Broschag, Thomas M. Klapoetke, Axel Schulz, and Peter S. White
pp 5734 - 5738; DOI:
10.1021/ic00077a015
PDF
Non-metal redox kinetics: hypobromite and hypoiodite reactions with cyanide and the hydrolysis of cyanogen halides
Cynthia M. Gerritsen, Michael Gazda, and Dale W. Margerum
pp 5739 - 5748; DOI:
10.1021/ic00077a016
PDF
Kinetics and mechanism of the hydration of carbon dioxide and dehydration of bicarbonate catalyzed by a zinc (II) complex of 1,5,9-triazacyclododecane as a model for carbonic anhydrase
Xiaoping Zhang, Rudi van Eldik, Tohru Koike, and Eiichi Kimura
pp 5749 - 5755; DOI:
10.1021/ic00077a017
PDF
A new linkage isomer of trichlorotris(dimethyl sulfoxide) rhodium: photochemical synthesis, crystal structure, and reactivity of mer,trans-RhCl3(DMSO-S)2(DMSO)
Enzo Alessio, Paolo Faleschini, Andrea Sessanta o Santi, Giovanni Mestroni, and Mario Calligaris
pp 5756 - 5761; DOI:
10.1021/ic00077a018
PDF
Osmium(II)/ruthenium(II) trimetallics incorporating polyazine bridging ligands: isovalent near-IR absorbers with unique electrochemical behavior
Mark M. Richter and Karen J. Brewer
pp 5762 - 5768; DOI:
10.1021/ic00077a019
PDF
NMR study on the coordination behavior of dissymmetric terdentate trinitrogen ligands on methylpalladium(II) compounds
Richard E. Rulke, Jan M. Ernsting, Anthony L. Spek, Cees J. Elsevier, Piet W. N. M. van Leeuwen, and Kees Vrieze
pp 5769 - 5778; DOI:
10.1021/ic00077a020
PDF
Steric ligand effects of six bidentate bipyridyl ligands
Carol A. Bessel, Joseph A. Margarucci, J. Henry Acquaye, Robert S. Rubino, Janet Crandall, Alan J. Jircitano, and Kenneth J. Takeuchi
pp 5779 - 5784; DOI:
10.1021/ic00077a021
PDF
Divalent metal ion catalyzed hydrolysis of N-methyl-4'-nitro-6-carboxypicolinanilide. The pH-rate profile transitions and buffer inhibition
Wei Tang and Lawrence M. Sayre
pp 5785 - 5791; DOI:
10.1021/ic00077a022
PDF
Kinetics and mechanism of the oxidation of phenols by the oxochromium(IV) ion
Ahmad Al-Ajlouni, Andreja Bakac, and James H. Espenson
pp 5792 - 5796; DOI:
10.1021/ic00077a023
PDF
Correlation between one-electron reduction and oxygen-oxygen bond strength in d0 transition metal peroxo complexes
M. Bonchio, V. Conte, F. Di Furia, G. Modena, S. Moro, T. Carofiglio, F. Magno, and P. Pastore
pp 5797 - 5799; DOI:
10.1021/ic00077a024
PDF
Syntheses and x-ray structural characterizations of three-coordinate gold(I) and silver(I) complexes with the potentially tetradentate ligand tris(2-(diphenylphosphino)ethyl)amine (NP3): [Au2(NP3)2](BPh4)2, Au(NP3)PF6, Au(NP3)NO3, Ag(NP3)NO3, and Ag(NP3)PF6. The Au(I) compounds are luminescent
M. Nazrul I. Khan, Richard J. Staples, Christopher King, John P. Fackler, and Richard E. P. Winpenny
pp 5800 - 5807; DOI:
10.1021/ic00077a025
PDF
(Terpyridine)palladium(II) complexes of phenylcyanamide ligands
Weigang Zhang, Corinne Bensimon, and Robert J. Crutchley
pp 5808 - 5812; DOI:
10.1021/ic00077a026
PDF
Synthesis and characterization of first-row transition metal tellurolates. X-ray crystal structures of Mn[TeSi(SiMe3)3]2(dmpe), Fe[TeSi(SiMe3)3]2(dmpe)2, Fe[TeSi(SiMe3)3](Cl)(dmpe)2, and Co[TeSi(SiMe3)3](PMe3)3
David E. Gindelberger and John Arnold
pp 5813 - 5820; DOI:
10.1021/ic00077a027
PDF
Synthesis and characterization of the polyoxoanion-supported ruthenium(I)-ruthenium(I) tetracarbonyls [(P3O9)2Ru2(CO)4]4- and [(Cp*TiW5O18)2Ru2(CO)4]4-
Walter G. Klemperer and Bianxiao Zhong
pp 5821 - 5826; DOI:
10.1021/ic00077a028
PDF
Spectroscopy, molecular structure, and electrochemistry of rhenium(V) oxo and imido complexes of 1,4,8,11-tetraazacyclotetradecane (cyclam)
Yu Pey Wang, Chi Ming Che, Kowk Yin Wong, and Shie Ming Peng
pp 5827 - 5832; DOI:
10.1021/ic00077a029
PDF
Reactions of trisulfonated triphenylphosphine, TPPTS, with cobalt carbonyls in water
Tamas Bartik, Berit Bartik, Brian E. Hanson, Kenton H. Whitmire, and Ipin Guo
pp 5833 - 5837; DOI:
10.1021/ic00077a030
PDF
Compounds of iron(III) with trans-1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylic acid: structures of trans-(trans-1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylato)iron(III) perchlorate and trans-(trans-1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylato)iron(III) trans-(trans-1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylic acid) dichloroiron(III) trans-1,4,8,11-tetraazoniacyclotetradecane-6,13-dicarboxylic acid dichloride tetraperchlorate tetrahydrate
Neil F. Curtis, Li Xin, and David C. Weatherburn
pp 5838 - 5843; DOI:
10.1021/ic00077a031
PDF
Spectroscopic and electrochemical properties of (.mu.-oxo)diiron(III) complexes related to diiron-oxo proteins. Structure of [Fe2O(TPA)2(MoO4)](ClO4)2
Richard C. Holz, Timothy E. Elgren, Linda L. Pearce, Jian H. Zhang, Charles J. O'Connor, and Lawrence Que
pp 5844 - 5850; DOI:
10.1021/ic00077a032
PDF
Interaction of binuclear transition metal complexes with DNA
Edward A. Kesicki, Mark A. DeRosch, Laurie H. Freeman, Christine L. Walton, Daniel F. Harvey, and William C. Trogler
pp 5851 - 5867; DOI:
10.1021/ic00077a033
PDF
Probing the influence of local coordination environment on ligand binding in nickel hydrogenase model complexes
Mikyung Cha, Christine L. Gatlin, Susan C. Critchlow, and Julie A. Kovacs
pp 5868 - 5877; DOI:
10.1021/ic00077a034
PDF
Synthesis of cis-bis(acetone)tetraammineruthenium(2+): a valuable precursor for cis-tetraammineruthenium(II) chemistry
T. Sugaya and M. Sano
pp 5878 - 5879; DOI:
10.1021/ic00077a035
PDF
Kinetics of iodine hydrolysis
Istvan Lengyel, Irving R. Epstein, and Kenneth Kustin
pp 5880 - 5882; DOI:
10.1021/ic00077a036
PDF
A novel (tricobaltiomethoxy)silatrane: synthesis and structure of [Co3(CO)9{.mu.3-CO[cyclic](Si(OCH2CH2)3N}]
Myong W. Kim, Dong Seon Uh, Sangsoo Kim, and Youngkyu Do
pp 5883 - 5885; DOI:
10.1021/ic00077a037
PDF
Kinetics of the reduction of alkyl halides by a chromium(II) macrocycle
Andreja Bakac, Vjera Butkovic, James H. Espenson, and Matko Orhanovic
pp 5886 - 5888; DOI:
10.1021/ic00077a038
PDF
Synthesis and chemistry of 1,1,4,4-tetramethyl-1-azonia-4-phosphonia-2,5-diboratacyclohexane, a novel multipolar framework heterocycle
Scott W. Dougherty and Norman E. Miller
pp 5889 - 5893; DOI:
10.1021/ic00077a039
PDF
Potassium aluminum alkoxides: characterization of polymeric [(PriOH)2K(.mu.-OPri)2Al(.mu.-OPri)2]n
Juliane A. Meese-Marktscheffel, Roman Weimann, Herbert Schumann, and John W. Gilje
pp 5894 - 5896; DOI:
10.1021/ic00077a040
PDF
Editorial - Manuscript Submission on Disk
M. Frederick Hawthorne
pp 5645 - 5645; DOI:
10.1021/ic00077a600
PDF

Issue 26


Variable oxygenation levels of sulfur in sterically hindered thiolates: molecular structure of [N-(2-mercapto-2-methylpropyl)-N'-(2-sulfeno-2-methylpropyl)-1,5-diazacyclooctanato]nickel(II)
Ivan Font, Rizalia Buonomo, Joseph H. Reibenspies, and Marcetta Y. Darensbourg
pp 5897 - 5898; DOI:
10.1021/ic00078a001
PDF
Site-selective hydrolysis of tRNA by lanthanide metal complexes
Nobuhiro Hayashi, Naoya Takeda, Tetsuro Shiiba, Morio Yashiro, Kimitsuna Watanabe, and Makoto Komiyama
pp 5899 - 5900; DOI:
10.1021/ic00078a002
PDF
Oxidative addition of phenylacetylene to [Ir(CO)(RCN)(PPh3)2]ClO4: preparation, kinetics, and mechanism
Chong Shik Chin, Joogie Yoon, and Joongho Song
pp 5901 - 5904; DOI:
10.1021/ic00078a003
PDF
Kinetics and mechanism of the oxidation of hydroxylamine by aqueous chlorine
John N. Cooper and Dale W. Margerum
pp 5905 - 5910; DOI:
10.1021/ic00078a004
PDF
Electron-transfer kinetics of copper(II/I) macrocyclic tetrathiaether complexes. Influence of ring size upon gated behavior
Gregory H. Leggett, Brian C. Dunn, Ana M. Q. Vande Linde, L. A. Ochrymowycz, and D. B. Rorabacher
pp 5911 - 5918; DOI:
10.1021/ic00078a005
PDF
Functionalized phosphine-phosphinimines as heteroatomic ligands. Synthesis, characterization, and representative x-ray structures of the phosphine-phosphinimines Ph2PCH2PPh2:NAr [Ar = 5-F,2,4-(NO2)2C6H2, 4-(CN)C6F4] and structure of the rhodium(I) complex Cl(CO)RhP(Ph)2CH2PPh2:NC6F4-4-CN
Kattesh V. Katti, B. D. Santarsiero, A. Alan Pinkerton, and Ronald G. Cavell
pp 5919 - 5925; DOI:
10.1021/ic00078a006
PDF
1,1'-Bis(diphenylphosphino)ferrocene (dppf) complexes of gold(I) and gold(III). Crystal structures of [(dppf)AuPPh3]ClO4.cntdot.CHCl3 and [(dppf)Au(.mu.-dppf)Au(dppf)](ClO4)2.cntdot.2CH2Cl2
M. Concepcion Gimeno, Antonio Laguna, Cristina Sarroca, and Peter G. Jones
pp 5926 - 5932; DOI:
10.1021/ic00078a007
PDF
Radical routes to titanium(IV) thiolate complexes: structure and reactivity of (.eta.5-C5H5)TiIII and -TiIV donor and thiolate derivatives
T. Timothy Nadasdi and Douglas W. Stephan
pp 5933 - 5938; DOI:
10.1021/ic00078a008
PDF
Crystal structure, solution chemistry, and antitumor activity of diastereomeric [1,2-bis(2-hydroxyphenyl)ethylenediamine]dichloroplatinum(II) complexes
Ronald Gust, Helmut Schoenenberger, Juergen Kritzenberger, Klaus Juergen Range, Ulrich Klement, and Thomas Burgemeister
pp 5939 - 5950; DOI:
10.1021/ic00078a009
PDF
Reactivity of dioxygen with manganese Schiff-base complexes: a chemical and electrochemical investigation
Colin P. Horwitz, Yangzhen Ciringh, Cuixia Liu, and Samantha Park
pp 5951 - 5956; DOI:
10.1021/ic00078a010
PDF
Comparative studies of mononuclear nickel(II) complexes with N2Sx (x = 2-4) Ligands
Bibhutosh Adhikary, Shuang Liu, and C. Robert Lucas
pp 5957 - 5962; DOI:
10.1021/ic00078a011
PDF
Metallointercalators: syntheses, structures, and photochemical characterizations of phenanthrenequinone diimine complexes of rhodium(III)
Achim H. Krotz, Louis Y. Kuo, and Jacqueline K. Barton
pp 5963 - 5974; DOI:
10.1021/ic00078a012
PDF
Homonuclear copper(II) complexes with multidentate amino alcohol ligands. Synthesis and characterization of a hexanuclear copper compound with a propeller structure: CuII6(bdmap)3Cl6(O)(OH) (bdmap = 1,3-bis(dimethylamino)-2-propanolato)
Suning Wang, Zhen Pang, Jian Chuan Zheng, and Michael J. Wagner
pp 5975 - 5980; DOI:
10.1021/ic00078a013
PDF
Hydrogen-bond-directed assembly of one-dimensional and two-dimensional polymeric copper(II) complexes with trifluoroacetate and hydroxypyridine as ligands: syntheses and structural investigations
Steven R. Breeze and Suning Wang
pp 5981 - 5989; DOI:
10.1021/ic00078a014
PDF
Synthesis and spectroscopic and electrical properties of [W(C3S5)3]2- and [Mo(C3S5)3]2- anion complexes and their oxidized species and x-ray crystal structures of [NBun4]2[W(C3S5)3], [NBun4]2[Mo(C3S5)3], and [Fe(C5Me5)2][W(C3S5)3]
Genetsu Matsubayashi, Katsuji Douki, Hatsue Tamura, Motohiro Nakano, and Wasuke Mori
pp 5990 - 5996; DOI:
10.1021/ic00078a015
PDF
Synthesis, structure, and spectroscopy of encapsulated complexes of cobalt(III) derived from the ligand 5-methyl-5-(4-amino-2-thiabutyl)-3,7-diazanonane-1,9-diamine (N5S)
James I. Bruce, Lawrence R. Gahan, Trevor W. Hambley, and Robert Stranger
pp 5997 - 6002; DOI:
10.1021/ic00078a016
PDF
Synthesis and structure of the novel layered oxide bismuth molybdenum hydroxide oxide dihydrate (BiMo2O7OH.cntdot.2H2O)
Joseph A. Hriljac and Charlie C. Torardi
pp 6003 - 6007; DOI:
10.1021/ic00078a017
PDF
Generalizing the metallacrown analogy: ligand variation and solution stability of the VVO 9-metallacrown-3 structure type
Brian R. Gibney, Ann J. Stemmler, Steffen Pilotek, Jeff W. Kampf, and Vincent L. Pecoraro
pp 6008 - 6015; DOI:
10.1021/ic00078a018
PDF
Crystal structure and magnetic properties of diaqua(L-aspartato)copper(II)
R. Calvo, C. A. Steren, O. E. Piro, T. Rojo, F. J. Zuniga, and E. E. Castellano
pp 6016 - 6022; DOI:
10.1021/ic00078a019
PDF
Synthesis, structure, and spectroscopy of an encapsulated nickel(II) complex of the unsymmetrical macrobicyclic ligand 1-methyl-8-amino-3,13-dithia-6,10,16,19-tetraazabicyclo[6.6.6]icosane (AMN4S2sar)
Therese M. Donlevy, Lawrence R. Gahan, Robert Stranger, Sarah E. Kennedy, Karl A. Byriel, and Colin H. L. Kennard
pp 6023 - 6027; DOI:
10.1021/ic00078a020
PDF
Electrochemical studies of nickel(II) complexes with tri- and bidentate arsine ligands. A stereochemically and electronically accommodating donor set
Alison J. Downard, Lyall R. Hanton, David A. McMorran, and Rowena L. Paul
pp 6028 - 6033; DOI:
10.1021/ic00078a021
PDF
Characterization of large, polyanionic inorganic molecules: fast atom bombardment mass spectrometry of P2W15Nb3O629- and of the supported organometallic catalyst precursor (1,5-COD)Ir.cntdot.P2W15Nb3O628-
Alessandro Trovarelli and Richard G. Finke
pp 6034 - 6039; DOI:
10.1021/ic00078a022
PDF
Polyoxoanions as soluble metal oxide analogs. Synthesis and characterization of the polyoxoanion-supported iridium(I) complex (1,5-COD)Ir.cntdot.SiW9Nb3O406-
Yin Lin, Kenji Nomiya, and Richard G. Finke
pp 6040 - 6045; DOI:
10.1021/ic00078a023
PDF
Multinuclear magnetic resonance study of the dilead trichalcogenide anions Pb2SnCh3-n2- (Ch = Se or Te), Pb2SSeTe2-, and M2Se32- (M = Sn and/or Pb) and the crystal structures of (2,2,2-crypt-K+)2Sn2Te32- and (2,2,2-crypt-K+)2Sn2Se32-
Mar Bjorgvinsson, Helene P. A. Mercier, Kenneth M. Mitchell, Gary J. Schrobilgen, and G. Strohe
pp 6046 - 6055; DOI:
10.1021/ic00078a024
PDF
Studies of mono substituted compounds of formula M2(NMe2)5X (M.tplbond.M), where M = molybdenum and tungsten and X = iodine, alkyl, aryl, and diphenylphosphido, and the bridged-1,1'-ferrocenyl complex W2(NMe2)(.mu.-(C5H4)2Fe)
Hartmut Schulz, Kirsten Folting, John C. Huffman, William E. Streib, and Malcolm H. Chisholm
pp 6056 - 6066; DOI:
10.1021/ic00078a025
PDF
Intramolecular bridge/terminal oxo exchange within oxomolybdenum [MoV2O3]4+ complexes containing linear oxo bridges
Robert L. Thompson, Samkeun Lee, Steven J. Geib, and N. John Cooper
pp 6067 - 6075; DOI:
10.1021/ic00078a026
PDF
Marked wavelength dependence in photolyses of dithiophosphate complexes of the molybdenum-oxygen [MoV2O3]4+ core through a photoactive intermediate accessed by a secondary thermal equilibrium
Robert L. Thompson, Steven J. Geib, and N. John Cooper
pp 6076 - 6083; DOI:
10.1021/ic00078a027
PDF
High-quality mixed-transition-metal dichalcogenides from solid-state exchange reactions
Philippe R. Bonneau and Richard B. Kaner
pp 6084 - 6087; DOI:
10.1021/ic00078a028
PDF
Redox properties of phosphazene polymers with pendant ferrocene groups
A. L. Crumbliss, D. Cooke, J. Castillo, and P. Wisian-Neilson
pp 6088 - 6094; DOI:
10.1021/ic00078a029
PDF
Interaction of metal ions with alloxanthine, a model in xanthine oxidase inhibition by the drug allopurinol: synthesis and characterization of M(alloxanthine)2(NO3)2.cntdot.2H2O (M = copper, cobalt) and bis(alloxanthine)dichlorozinc
Gaby Haenggi, Helmut Schmalle, and Erich Dubler
pp 6095 - 6101; DOI:
10.1021/ic00078a030
PDF
Palladium(II) chloride complexes of bis(pyrazolyl)cyclotriphosphazenes
A. Chandrasekaran, Setharampattu S. Krishnamurthy, and Munirathinam Nethaji
pp 6102 - 6106; DOI:
10.1021/ic00078a031
PDF
Variations in the copper(I)-copper(I) distances in multinuclear clusters with identical coordination geometries. Short metal-metal contacts induced by oligomerization
Santosh P. Abraham, Ashoka G. Samuelson, and Jayaraman Chandrasekhar
pp 6107 - 6111; DOI:
10.1021/ic00078a032
PDF
Proton NMR studies of pyridine binding to cytochrome c
Weiping Shao, Yiming Yao, Gaohua Liu, and Wenxia Tang
pp 6112 - 6114; DOI:
10.1021/ic00078a033
PDF
The synthesis and separation of the isomeric compounds dimeric dimethyl(2-pyridyl)borane and dimethylboronium bis(2-pyridyl)dimethylborate
Thomas G. Hodgkins
pp 6115 - 6116; DOI:
10.1021/ic00078a034
PDF
The first structurally characterized dinuclear nickel(II) selenocyanate compound: (.mu.-SeCN)2[Ni(Medpt)(SeCN)]2. Magnetic behavior
Ramon Vicente, Albert Escuer, Joan Ribas, Xavier Solans, and M. Font-Bardia
pp 6117 - 6118; DOI:
10.1021/ic00078a035
PDF
Steric control of vanadium(V) coordination geometry: a mononuclear structural model for transition-state-analog RNase inhibitors
Ladd M. Mokry and Carl J. Carrano
pp 6119 - 6121; DOI:
10.1021/ic00078a036
PDF
Effects on molecular association, chelate conformation, and reactivity toward substitution in copper Cu(5-X-salen) complexes, salen2- = N,N'-ethylenebis(salicylidenaminato), X = H, CH3O, and Cl: synthesis, x-ray structures, and EPR investigations. [Erratum to document cited in CA119(26):285036b]
Mohan M. Bhadbhade and D. Srinivas
pp 6122 - 6130; DOI:
10.1021/ic00078a037
PDF